Electrochemical Sensing of Bisphenol A on Facet-Tailored TiO2 Single Crystals Engineered by Inorganic-Framework Molecular Imprinting Sites

  • Dan-Ni Pei
    Dan-Ni Pei
    CAS Key Laboratory of Urban Pollutant Conversion, Department of Chemistry, University of Science & Technology of China, Hefei, 230026, China
    More by Dan-Ni Pei
  • Ai-Yong Zhang*
    Ai-Yong Zhang
    CAS Key Laboratory of Urban Pollutant Conversion, Department of Chemistry, University of Science & Technology of China, Hefei, 230026, China
    Department of Municipal Engineering, Hefei University of Technology, Hefei, 230009, China
    *Fax: +86-551-63602449. E-mail: [email protected]
  • Xiao-Qiang Pan
    Xiao-Qiang Pan
    CAS Key Laboratory of Urban Pollutant Conversion, Department of Chemistry, University of Science & Technology of China, Hefei, 230026, China
  • Yang Si
    Yang Si
    CAS Key Laboratory of Urban Pollutant Conversion, Department of Chemistry, University of Science & Technology of China, Hefei, 230026, China
    More by Yang Si
  • , and 
  • Han-Qing Yu*
    Han-Qing Yu
    CAS Key Laboratory of Urban Pollutant Conversion, Department of Chemistry, University of Science & Technology of China, Hefei, 230026, China
    *Fax: +86-551-63601592. E-mail: [email protected]
    More by Han-Qing Yu
Cite this: Anal. Chem. 2018, 90, 5, 3165–3173
Publication Date (Web):February 20, 2018
https://doi.org/10.1021/acs.analchem.7b04466
Copyright © 2018 American Chemical Society
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Abstract

Noble metals, nanostructured carbon, and their hybrids are widely used for electrochemical detection of persistent organic pollutants. However, despite of the rapid detection process and high accuracy, these materials generally suffer from high costs, metallic impurity, heterogeneity, irreversible adsorption and poor sensitivity. Herein, the high-energy {001}-exposed TiO2 single crystals with specific inorganic-framework molecular recognition ability was prepared as the electrode material to detect bisphenol A (BPA), a typical and widely present organic pollutant in the environment. The oxidation peak current was linearly correlated to the BPA concentration from 10.0 nM to 20.0 μM (R2 = 0.9987), with a low detection limit of 3.0 nM (S/N = 3). Furthermore, it exhibited excellent discriminating ability, high anti-interference capacity, and good long-term stability. Its good performance for BPA detection in real environmental samples, including tap water, lake and river waters, domestic wastewater, and municipal sludge, was also demonstrated. This work extends the applications of TiO2 semiconductor and suggests that this material could be used as a highly active, stable, low-cost, and environmentally benign electrode material for electrochemical sensing.

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The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.analchem.7b04466.

  • Morphology and structure of P25, calculation for electrochemical surface area, anodic peak potential, initial surface concentration and diffusion coefficient (text), structural parameters of TiO2 (Table S1), initial surface concentration and signal retention efficiency (Table S2), analysis of industrial samples (Table S3), XRD of P25 (Figure S1), SEM of MI-TiO2 (Figure S2), XPS, VB, and BET of TiO2 (Figure S3), electrochemical properties of different electrodes (Figure S4), interfacial diffusion coefficient and initial surface concentration of BPA (Figure S5), it and calculated diffusion coefficients (Figure S6), LSV and relationships between peak current with scanning rate (Figures S7 and S8), DPV of MI-TiO2 (Figures S9–S11), and BPA determination with interferences (Figures S12–S19) (PDF)

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