Operando Raman Spectroscopy Reveals Cr-Induced-Phase Reconstruction of NiFe and CoFe Oxyhydroxides for Enhanced Electrocatalytic Water Oxidation

  • Xin Bo
    Xin Bo
    School of Chemistry, Faculty of Science, The University of New South Wales, Sydney, NSW 2052 Australia
    More by Xin Bo
  • Yibing Li
    Yibing Li
    School of Chemistry, Faculty of Science, The University of New South Wales, Sydney, NSW 2052 Australia
    More by Yibing Li
  • Xianjue Chen
    Xianjue Chen
    School of Chemistry, Faculty of Science, The University of New South Wales, Sydney, NSW 2052 Australia
    More by Xianjue Chen
  • , and 
  • Chuan Zhao*
    Chuan Zhao
    School of Chemistry, Faculty of Science, The University of New South Wales, Sydney, NSW 2052 Australia
    *Email: [email protected]
    More by Chuan Zhao
Cite this: Chem. Mater. 2020, 32, 10, 4303–4311
Publication Date (Web):April 24, 2020
https://doi.org/10.1021/acs.chemmater.0c01067
Copyright © 2020 American Chemical Society
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Abstract

Nonprecious NiFe and CoFe oxyhydroxides are among the most active materials for oxygen evolution reaction (OER) in basic media. However, the phase separation in these composites during water oxidation remains a critical issue that often results in degradation of electrochemical performance and debate on the mechanism and the active intermediates. In this study, we show that the introduction of Cr can efficiently transform the crystalline multiphase NiFe and CoFe oxides/hydroxides into homogeneous amorphous nanodots with sharply reduced nanoparticle size from tens of nanometers to merely 2–3 nm. Serving as an OER catalyst, the ternary NiFeCr and CoFeCr catalysts exhibit a smaller onset potential of ∼1.51 V vs reversible hydrogen electrode (RHE) and a stable OER performance during long-term water electrolysis. The impact of Cr on the NiFe and CoFe catalysts for OER kinetics was systematically investigated by operando electrochemical Raman spectroscopy. It is found that, for the NiFeCr compound, Cr can promote the generation of a more active β-NiOOH phase than that of the NiFe composite during water oxidation. For the CoFe and CoFeCr systems, the introduction of Cr only disturbs the lattice crystallization. However, active CoOOH is spontaneously present on the surface of the composites upon making contact with KOH electrolyte, even without applying a potential. Thus, Co-based catalysts can easily achieve the “ready-to-serve” state for high-performance water oxidation without preactivation.

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  • Photos of obtained catalysts, XRD patterns, TEM images, optimization of OER performance, cyclic voltammetries, EIS plots, Raman spectra, LSV, XPS data, HRTEM images, ICP-OES, and simulated parameters of relevant equivalent circuits (PDF)

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