Molecular Catalysts for Water Oxidation

View Author Information
Department of Chemistry and Energy Sciences Institute, Yale University, P.O. Box 208107, New Haven, Connecticut 06520-8107, United States
Cite this: Chem. Rev. 2015, 115, 23, 12974–13005
Publication Date (Web):July 7, 2015
https://doi.org/10.1021/acs.chemrev.5b00122
Copyright © 2015 American Chemical Society
Article Views
23496
Altmetric
-
Citations
LEARN ABOUT THESE METRICS
Read OnlinePDF (8 MB)

Cited By


This article is cited by 749 publications.

  1. Quyen T. Nguyen, Elodie Rousset, Van T. H. Nguyen, Vincent Colliere, Pierre Lecante, Wantana Klysubun, Karine Philippot, Jérôme Esvan, Marc Respaud, Gilles Lemercier, Phong D. Tran, Catherine Amiens. Covalent Grafting of Ruthenium Complexes on Iron Oxide Nanoparticles: Hybrid Materials for Photocatalytic Water Oxidation. ACS Applied Materials & Interfaces 2021, 13 (45) , 53829-53840. https://doi.org/10.1021/acsami.1c15051
  2. Deepika G. Karmalkar, Mi Sook Seo, Yong-Min Lee, Youngsuk Kim, Eunsung Lee, Ritimukta Sarangi, Shunichi Fukuzumi, Wonwoo Nam. Deeper Understanding of Mononuclear Manganese(IV)–Oxo Binding Brønsted and Lewis Acids and the Manganese(IV)–Hydroxide Complex. Inorganic Chemistry 2021, 60 (22) , 16996-17007. https://doi.org/10.1021/acs.inorgchem.1c02119
  3. Hui Ding, Hongfei Liu, Wangsheng Chu, Changzheng Wu, Yi Xie. Structural Transformation of Heterogeneous Materials for Electrocatalytic Oxygen Evolution Reaction. Chemical Reviews 2021, 121 (21) , 13174-13212. https://doi.org/10.1021/acs.chemrev.1c00234
  4. Mian Guo, Jisheng Zhang, Lina Zhang, Yong-Min Lee, Shunichi Fukuzumi, Wonwoo Nam. Enthalpy–Entropy Compensation Effect in Oxidation Reactions by Manganese(IV)-Oxo Porphyrins and Nonheme Iron(IV)-Oxo Models. Journal of the American Chemical Society 2021, 143 (44) , 18559-18570. https://doi.org/10.1021/jacs.1c08198
  5. Peikun Zhang, Pai Wang, Wei Wang, Qianbao Wu, Mengjun Xiao, Roger Alberto, Yanning Zhang, Chunhua Cui. Efficient Alkaline Water Oxidation with a Regenerable Nickel Pseudo-Complex. ACS Applied Materials & Interfaces 2021, 13 (41) , 48661-48668. https://doi.org/10.1021/acsami.1c13609
  6. Xialiang Li, Xue-Peng Zhang, Mian Guo, Bin Lv, Kai Guo, Xiaotong Jin, Wei Zhang, Yong-Min Lee, Shunichi Fukuzumi, Wonwoo Nam, Rui Cao. Identifying Intermediates in Electrocatalytic Water Oxidation with a Manganese Corrole Complex. Journal of the American Chemical Society 2021, 143 (36) , 14613-14621. https://doi.org/10.1021/jacs.1c05204
  7. Biswanath Das, Ahibur Rahaman, Andrey Shatskiy, Oscar Verho, Markus D. Kärkäs, Björn Åkermark. The Impact of Ligand Carboxylates on Electrocatalyzed Water Oxidation. Accounts of Chemical Research 2021, 54 (17) , 3326-3337. https://doi.org/10.1021/acs.accounts.1c00298
  8. Edward Barry, Raelyn Burns, Wei Chen, Guilhem X. De Hoe, Joan Manuel Montes De Oca, Juan J. de Pablo, James Dombrowski, Jeffrey W. Elam, Alanna M. Felts, Giulia Galli, John Hack, Qiming He, Xiang He, Eli Hoenig, Aysenur Iscen, Benjamin Kash, Harold H. Kung, Nicholas H. C. Lewis, Chong Liu, Xinyou Ma, Anil Mane, Alex B. F. Martinson, Karen L. Mulfort, Julia Murphy, Kristian Mølhave, Paul Nealey, Yijun Qiao, Vepa Rozyyev, George C. Schatz, Steven J. Sibener, Dmitri Talapin, David M. Tiede, Matthew V. Tirrell, Andrei Tokmakoff, Gregory A. Voth, Zhongyang Wang, Zifan Ye, Murat Yesibolati, Nestor J. Zaluzec, Seth B. Darling. Advanced Materials for Energy-Water Systems: The Central Role of Water/Solid Interfaces in Adsorption, Reactivity, and Transport. Chemical Reviews 2021, 121 (15) , 9450-9501. https://doi.org/10.1021/acs.chemrev.1c00069
  9. Marcos Gil-Sepulcre, Joachim O. Lindner, Dorothee Schindler, Lucía Velasco, Dooshaye Moonshiram, Olaf Rüdiger, Serena DeBeer, Vladimir Stepanenko, Eduardo Solano, Frank Würthner, Antoni Llobet. Surface-Promoted Evolution of Ru-bda Coordination Oligomers Boosts the Efficiency of Water Oxidation Molecular Anodes. Journal of the American Chemical Society 2021, 143 (30) , 11651-11661. https://doi.org/10.1021/jacs.1c04738
  10. Koteswara Rao Gorantla, Bhabani S. Mallik. Mechanistic Insight into the O2 Evolution Catalyzed by Copper Complexes with Tetra- and Pentadentate Ligands. The Journal of Physical Chemistry A 2021, 125 (29) , 6461-6473. https://doi.org/10.1021/acs.jpca.1c06008
  11. Guilin Ruan, Pritam Ghosh, Natalia Fridman, Galia Maayan. A Di-Copper-Peptoid in a Noninnocent Borate Buffer as a Fast Electrocatalyst for Homogeneous Water Oxidation with Low Overpotential. Journal of the American Chemical Society 2021, 143 (28) , 10614-10623. https://doi.org/10.1021/jacs.1c03225
  12. Shao-Xiong Lennon Luo, Richard Y. Liu, Sungsik Lee, Timothy M. Swager. Electrocatalytic Isoxazoline–Nanocarbon Metal Complexes. Journal of the American Chemical Society 2021, 143 (27) , 10441-10453. https://doi.org/10.1021/jacs.1c05439
  13. Sanchaita Dey, Baghendra Singh, Souradip Dasgupta, Anindya Dutta, Arindam Indra, Goutam Kumar Lahiri. Ruthenium–Benzothiadiazole Building Block Derived Dynamic Heterometallic Ru–Ag Coordination Polymer and Its Enhanced Water-Splitting Feature. Inorganic Chemistry 2021, 60 (13) , 9607-9620. https://doi.org/10.1021/acs.inorgchem.1c00865
  14. Ana M. Geer, Charles Musgrave III, Christopher Webber, Robert J. Nielsen, Bradley A. McKeown, Chang Liu, P. Philipp M. Schleker, Peter Jakes, Xiaofan Jia, Diane A. Dickie, Josef Granwehr, Sen Zhang, Charles W. Machan, William A. Goddard, III, T. Brent Gunnoe. Electrocatalytic Water Oxidation by a Trinuclear Copper(II) Complex. ACS Catalysis 2021, 11 (12) , 7223-7240. https://doi.org/10.1021/acscatal.1c01395
  15. Sandra M. Lang, Nina Zimmermann, Thorsten M. Bernhardt, Robert N. Barnett, Bokwon Yoon, Uzi Landman. Size, Stoichiometry, Dimensionality, and Ca Doping of Manganese Oxide-Based Water Oxidation Clusters: An Oxyl/Hydroxy Mechanism for Oxygen–Oxygen Coupling. The Journal of Physical Chemistry Letters 2021, 12 (22) , 5248-5255. https://doi.org/10.1021/acs.jpclett.1c01299
  16. Jacob A. Spies, John R. Swierk, H. Ray Kelly, Matt D. Capobianco, Kevin P. Regan, Victor S. Batista, Gary W. Brudvig, Charles A. Schmuttenmaer. Tuning the Conduction Band for Interfacial Electron Transfer: Dye-Sensitized SnxTi1–xO2 Photoanodes for Water Splitting. ACS Applied Energy Materials 2021, 4 (5) , 4695-4703. https://doi.org/10.1021/acsaem.1c00305
  17. Afsar Ali, Divyansh Prakash, Piyali Majumder, Soumya Ghosh, Arnab Dutta. Flexible Ligand in a Molecular Cu Electrocatalyst Unfurls Bidirectional O2/H2O Conversion in Water. ACS Catalysis 2021, 11 (10) , 5934-5941. https://doi.org/10.1021/acscatal.1c01542
  18. Mengjun Xiao, Qianbao Wu, Lei Li, Shijia Mu, Mads Nybo Sørensen, Wei Wang, Chunhua Cui. Regenerable Catalyst for Highly Alkaline Water Oxidation. ACS Energy Letters 2021, 6 (5) , 1677-1683. https://doi.org/10.1021/acsenergylett.1c00127
  19. S. Esmael Balaghi, Somayeh Mehrabani, Younes Mousazade, Robabeh Bagheri, Alla S. Sologubenko, Zhenlun Song, Greta R. Patzke, Mohammad Mahdi Najafpour. Mechanistic Understanding of Water Oxidation in the Presence of a Copper Complex by In Situ Electrochemical Liquid Transmission Electron Microscopy. ACS Applied Materials & Interfaces 2021, 13 (17) , 19927-19937. https://doi.org/10.1021/acsami.1c00243
  20. Nader Akbari, Ivan Kondov, Matthias Vandichel, Pavlo Aleshkevych, Mohammad Mahdi Najafpour. Oxygen-Evolution Reaction by a Palladium Foil in the Presence of Iron. Inorganic Chemistry 2021, 60 (8) , 5682-5693. https://doi.org/10.1021/acs.inorgchem.0c03746
  21. Yosra M. Badiei, Christian Traba, Rina Rosales, Anthony Lopez Rojas, Claudio Amaya, Mohammed Shahid, Carolina Vera-Rolong, Javier J. Concepcion. Plasma-Initiated Graft Polymerization of Acrylic Acid onto Fluorine-Doped Tin Oxide as a Platform for Immobilization of Water-Oxidation Catalysts. ACS Applied Materials & Interfaces 2021, 13 (12) , 14077-14090. https://doi.org/10.1021/acsami.0c19730
  22. Sima Heidari, S. Esmael Balaghi, Alla S. Sologubenko, Greta R. Patzke. Economic Manganese-Oxide-Based Anodes for Efficient Water Oxidation: Rapid Synthesis and In Situ Transmission Electron Microscopy Monitoring. ACS Catalysis 2021, 11 (5) , 2511-2523. https://doi.org/10.1021/acscatal.0c03388
  23. Silvia D’Agostini, Konstantin G. Kottrup, Carla Casadevall, Ilaria Gamba, Valeria Dantignana, Alberto Bucci, Miquel Costas, Julio Lloret-Fillol, Dennis G.H. Hetterscheid. Electrocatalytic Water Oxidation with α-[Fe(mcp)(OTf)2] and Analogues. ACS Catalysis 2021, 11 (5) , 2583-2595. https://doi.org/10.1021/acscatal.0c05439
  24. Brittany L. Huffman, Katherine J. Lee, Ana M. Geer, Bradley A. McKeown, Xiaofan Jia, Diane A. Dickie, T. Brent Gunnoe, Jillian L. Dempsey. Role of Axial Ligation in Gating the Reactivity of Dimethylplatinum(III) Diimine Radical Cations. Organometallics 2021, 40 (3) , 333-345. https://doi.org/10.1021/acs.organomet.0c00663
  25. Xiangyang Guo, Lifang Liu, Yu Xiao, Rashid Mehmood, Yejun Xiao, Yu Qi, Fuxiang Zhang. Water-Stable Cobalt-Based MOF for Water Oxidation in Neutral Aqueous Solution: A Case of Mimicking the Photosystem II. Inorganic Chemistry 2021, 60 (3) , 1790-1796. https://doi.org/10.1021/acs.inorgchem.0c03265
  26. Du Yu, Zhi-Qiang Jiang, Jin Lu, Yu-Feng Li, Wen-Juan Fan, Hai-Yan Yang, Tian Wen. Well-Aligned Ni-Heteroatom (N, S) MOF Arrays Enhanced Electrocatalytic Oxygen Evolution Reaction. Inorganic Chemistry 2021, 60 (3) , 1305-1309. https://doi.org/10.1021/acs.inorgchem.0c03348
  27. Kaiwen Wang, Ronghui Jin, Yuhua Liu, Jing Ai, Zhipeng Liu, Xiaotian Li, Nan Li. Three-Dimensional Ordered Macroporous NiFe2O4 Self-Supporting Electrode with Enhanced Mass Transport for High-Efficiency Oxygen Evolution Reaction. ACS Applied Energy Materials 2021, 4 (1) , 268-274. https://doi.org/10.1021/acsaem.0c02232
  28. Koteswara Rao Gorantla, Bhabani S. Mallik. Mechanism and Electronic Perspective of Oxygen Evolution Reactions Catalyzed by [Fe(OTf)2(bpbp)]. The Journal of Physical Chemistry C 2021, 125 (2) , 1313-1322. https://doi.org/10.1021/acs.jpcc.0c08495
  29. Pradip K. Das, Sarmistha Bhunia, Priyanka Chakraborty, Sudipta Chatterjee, Atanu Rana, Karthik Peramaiah, Merfat M. Alsabban, Indranil Dutta, Abhishek Dey, Kuo-Wei Huang. Electrocatalytic Water Oxidation by a Phosphorus–Nitrogen O═PN3-Pincer Cobalt Complex. Inorganic Chemistry 2021, 60 (2) , 614-622. https://doi.org/10.1021/acs.inorgchem.0c02376
  30. Koteswara Rao Gorantla, Bhabani S. Mallik. Mechanism and Dynamics of Formation of Bisoxo Intermediates and O–O Bond in the Catalytic Water Oxidation Process. The Journal of Physical Chemistry A 2021, 125 (1) , 279-290. https://doi.org/10.1021/acs.jpca.0c09943
  31. Zhiwei Liu, Qing Chang, Weijie Wu, Weiye Yin, Yongle Chu, Wei Wang, Xikui Fang. Bridging Polyoxometalate-Based Mn4 Cubane Clusters with Inorganic Phosphates: Structural Transformation and Magnetic Properties. Inorganic Chemistry 2021, 60 (1) , 219-224. https://doi.org/10.1021/acs.inorgchem.0c02837
  32. Yuki Tanahashi, Sho Nagai, Yuta Tsubonouchi, Masanari Hirahara, Taisei Sato, Eman A. Mohamed, Zaki N. Zahran, Kenji Saito, Tatsuto Yui, Masayuki Yagi. Efficient Electrocatalytic Water Oxidation by a Dinuclear Ruthenium(II) Complex with Vicinal Aquo and Hydroxo Groups Adsorbed on a TiO2 Electrode. ACS Applied Energy Materials 2020, 3 (12) , 12172-12184. https://doi.org/10.1021/acsaem.0c02242
  33. Biswajit Mondal, Samir Chattopadhyay, Subal Dey, Atif Mahammed, Kaustuv Mittra, Atanu Rana, Zeev Gross, Abhishek Dey. Elucidation of Factors That Govern the 2e–/2H+ vs 4e–/4H+ Selectivity of Water Oxidation by a Cobalt Corrole. Journal of the American Chemical Society 2020, 142 (50) , 21040-21049. https://doi.org/10.1021/jacs.0c08654
  34. Yang Zong, Xiaohong Guan, Jun Xu, Yong Feng, Yunfeng Mao, Longqian Xu, Huaqiang Chu, Deli Wu. Unraveling the Overlooked Involvement of High-Valent Cobalt-Oxo Species Generated from the Cobalt(II)-Activated Peroxymonosulfate Process. Environmental Science & Technology 2020, 54 (24) , 16231-16239. https://doi.org/10.1021/acs.est.0c06808
  35. Nicolás I. Neuman, Uta Albold, Eleonora Ferretti, Shubhadeep Chandra, Simon Steinhauer, Paul Rößner, Franc Meyer, Fabio Doctorovich, Santiago E. Vaillard, Biprajit Sarkar. Cobalt Corroles as Electrocatalysts for Water Oxidation: Strong Effect of Substituents on Catalytic Activity. Inorganic Chemistry 2020, 59 (22) , 16622-16634. https://doi.org/10.1021/acs.inorgchem.0c02550
  36. Akhilesh Babu Ganganboina, Indra Memdi Khoris, Ankan Dutta Chowdhury, Tian-Cheng Li, Enoch Y. Park. Ultrasensitive Detection of the Hepatitis E Virus by Electrocatalytic Water Oxidation Using Pt-Co3O4 Hollow Cages. ACS Applied Materials & Interfaces 2020, 12 (45) , 50212-50221. https://doi.org/10.1021/acsami.0c13247
  37. Peter L. Dunn, Brian J. Cook, Samantha I. Johnson, Aaron M. Appel, R. Morris Bullock. Oxidation of Ammonia with Molecular Complexes. Journal of the American Chemical Society 2020, 142 (42) , 17845-17858. https://doi.org/10.1021/jacs.0c08269
  38. Mio Kondo, Shigeyuki Masaoka. Pentanuclear Scaffold: A Molecular Platform for Small-Molecule Conversions. Accounts of Chemical Research 2020, 53 (10) , 2140-2151. https://doi.org/10.1021/acs.accounts.0c00186
  39. Pablo Garrido-Barros, Dooshaye Moonshiram, Marcos Gil-Sepulcre, Primavera Pelosin, Carolina Gimbert-Suriñach, Jordi Benet-Buchholz, Antoni Llobet. Redox Metal–Ligand Cooperativity Enables Robust and Efficient Water Oxidation Catalysis at Neutral pH with Macrocyclic Copper Complexes. Journal of the American Chemical Society 2020, 142 (41) , 17434-17446. https://doi.org/10.1021/jacs.0c06515
  40. Han-Yu Liu, Claire C. Cody, Josephine A. Jacob-Dolan, Robert H. Crabtree, Gary W. Brudvig. Surface-Attached Molecular Catalysts on Visible-Light-Absorbing Semiconductors: Opportunities and Challenges for a Stable Hybrid Water-Splitting Photoanode. ACS Energy Letters 2020, 5 (10) , 3195-3202. https://doi.org/10.1021/acsenergylett.0c01719
  41. Keito Sano, Fazalurahman Kuttassery, Tetsuya Shimada, Tamao Ishida, Shinsuke Takagi, Bunsho Ohtani, Akira Yamakata, Tetsuo Honma, Hiroshi Tachibana, Haruo Inoue. Optically Transparent Colloidal Dispersion of Titania Nanoparticles Storable for Longer than One Year Prepared by Sol/Gel Progressive Hydrolysis/Condensation. ACS Applied Materials & Interfaces 2020, 12 (40) , 44743-44753. https://doi.org/10.1021/acsami.0c12951
  42. Ayuk M. Ako, Amal Cherian Kathalikkattil, Rory Elliott, Joaquín Soriano-López, Ian M. McKeogh, Muhammad Zubair, Nianyong Zhu, Max García-Melchor, Paul E. Kruger, Wolfgang Schmitt. Synthetic Approaches to Metallo-Supramolecular CoII Polygons and Potential Use for H2O Oxidation. Inorganic Chemistry 2020, 59 (19) , 14432-14438. https://doi.org/10.1021/acs.inorgchem.0c02182
  43. Sheida Rajabi, Fatemeh Ebrahimi, Gaurav Lole, Jann Odrobina, Sebastian Dechert, Christian Jooss, Franc Meyer. Water Oxidizing Diruthenium Electrocatalysts Immobilized on Carbon Nanotubes: Effects of the Number and Positioning of Pyrene Anchors. ACS Catalysis 2020, 10 (18) , 10614-10626. https://doi.org/10.1021/acscatal.0c01577
  44. Joaquín Soriano-López, Rory Elliott, Amal C. Kathalikkattil, Ayuk M. Ako, Muhamed Mulahmetović, Munuswamy Venkatesan, Wolfgang Schmitt. Bioinspired Water Oxidation Using a Mn-Oxo Cluster Stabilized by Non-Innocent Organic Tyrosine Y161 and Plastoquinone Mimics. ACS Sustainable Chemistry & Engineering 2020, 8 (36) , 13648-13659. https://doi.org/10.1021/acssuschemeng.0c03379
  45. Mohamed Barakat Zakaria, Dehua Zheng, Ulf-peter Apfel, Takahiro Nagata, El-Refaie S. Kenawy, Jianjian Lin. Dual-Heteroatom-Doped Reduced Graphene Oxide Sheets Conjoined CoNi-Based Carbide and Sulfide Nanoparticles for Efficient Oxygen Evolution Reaction. ACS Applied Materials & Interfaces 2020, 12 (36) , 40186-40193. https://doi.org/10.1021/acsami.0c06141
  46. Zahra Mazloomi, Jessica Margalef, Marcos Gil-Sepulcre, Nuria Romero, Martin Albrecht, Antoni Llobet, Xavier Sala, Oscar Pàmies, Montserrat Diéguez. Effect of Ligand Chelation and Sacrificial Oxidant on the Integrity of Triazole-Based Carbene Iridium Water Oxidation Catalysts. Inorganic Chemistry 2020, 59 (17) , 12337-12347. https://doi.org/10.1021/acs.inorgchem.0c01439
  47. Máté J. Bezdek, István Pelczer, Paul J. Chirik. Coordination-Induced N–H Bond Weakening in a Molybdenum Pyrrolidine Complex: Isotopic Labeling Provides Insight into the Pathway for H2 Evolution. Organometallics 2020, 39 (16) , 3050-3059. https://doi.org/10.1021/acs.organomet.0c00471
  48. Kei Ikeda, Muhammad Haris Mahyuddin, Yoshihito Shiota, Kazunari Yoshizawa. Active Catalyst for Methane Hydroxylation by an Iridium–Oxo Complex. ACS Catalysis 2020, 10 (15) , 8254-8262. https://doi.org/10.1021/acscatal.0c01610
  49. Caitlin M. Hanna, Ryan T. Pekarek, Elisa M. Miller, Jenny Y. Yang, Nathan R. Neale. Decoupling Kinetics and Thermodynamics of Interfacial Catalysis at a Chemically Modified Black Silicon Semiconductor Photoelectrode. ACS Energy Letters 2020, 5 (6) , 1848-1855. https://doi.org/10.1021/acsenergylett.0c00714
  50. Kerstin Oppelt, Mathias Mosberger, Jeannette Ruf, Ricardo Fernández-Terán, Benjamin Probst, Roger Alberto, Peter Hamm. Shedding Light on the Molecular Surface Assembly at the Nanoscale Level: Dynamics of a Re(I) Carbonyl Photosensitizer with a Coadsorbed Cobalt Tetrapyridyl Water Reduction Catalyst on ZrO2. The Journal of Physical Chemistry C 2020, 124 (23) , 12502-12511. https://doi.org/10.1021/acs.jpcc.0c02556
  51. Alba Iglesias-Mayor, Olaya Amor-Gutiérrez, Antonello Novelli, María-Teresa Fernández-Sánchez, Agustín Costa-García, Alfredo de la Escosura-Muñiz. Bifunctional [email protected]/Au [email protected] Nanoparticles As Novel Electrocatalytic Tags in Immunosensing: Application for Alzheimer’s Disease Biomarker Detection. Analytical Chemistry 2020, 92 (10) , 7209-7217. https://doi.org/10.1021/acs.analchem.0c00760
  52. Sergio Gonell, Eric A. Assaf, Kyle D. Duffee, Cynthia K. Schauer, Alexander J. M. Miller. Kinetics of the Trans Effect in Ruthenium Complexes Provide Insight into the Factors That Control Activity and Stability in CO2 Electroreduction. Journal of the American Chemical Society 2020, 142 (19) , 8980-8999. https://doi.org/10.1021/jacs.0c02912
  53. M. Victoria Bobo, Avishek Paul, Alex J. Robb, Ashley M. Arcidiacono, Mark D. Smith, Kenneth Hanson, Aaron K. Vannucci. Bis-Cyclometalated Iridium Complexes Containing 4,4′-Bis(phosphonomethyl)-2,2′-bipyridine Ligands: Photophysics, Electrochemistry, and High-Voltage Dye-Sensitized Solar Cells. Inorganic Chemistry 2020, 59 (9) , 6351-6358. https://doi.org/10.1021/acs.inorgchem.0c00456
  54. Mehmed Z. Ertem, Javier J. Concepcion. Oxygen Atom Transfer as an Alternative Pathway for Oxygen–Oxygen Bond Formation. Inorganic Chemistry 2020, 59 (9) , 5966-5974. https://doi.org/10.1021/acs.inorgchem.9b03751
  55. Roman Ezhov, Alireza Karbakhsh Ravari, Allison Page, Yulia Pushkar. Water Oxidation Catalyst cis-[Ru(bpy)(5,5′-dcbpy)(H2O)2]2+ and Its Stabilization in Metal–Organic Framework. ACS Catalysis 2020, 10 (9) , 5299-5308. https://doi.org/10.1021/acscatal.0c00488
  56. Xiongfei Zhang, Ying-Ying Li, Jian Jiang, Rong Zhang, Rong-Zhen Liao, Mei Wang. A Dinuclear Copper Complex Featuring a Flexible Linker as Water Oxidation Catalyst with an Activity Far Superior to Its Mononuclear Counterpart. Inorganic Chemistry 2020, 59 (8) , 5424-5432. https://doi.org/10.1021/acs.inorgchem.9b03783
  57. Bas van Dijk, Gabriel Menendez Rodriguez, Longfei Wu, Jan P. Hofmann, Alceo Macchioni, Dennis G. H. Hetterscheid. The Influence of the Ligand in the Iridium Mediated Electrocatalyic Water Oxidation. ACS Catalysis 2020, 10 (7) , 4398-4410. https://doi.org/10.1021/acscatal.0c00531
  58. Woormileela Sinha, Atif Mahammed, Natalia Fridman, Zeev Gross. Water Oxidation Catalysis by Mono- and Binuclear Iron Corroles. ACS Catalysis 2020, 10 (6) , 3764-3772. https://doi.org/10.1021/acscatal.9b05382
  59. Qing Han, Yinjuan Dong, Chunjiang Xu, Qiyu Hu, Congzhao Dong, Xiangming Liang, Yong Ding. Immobilization of Metal–Organic Framework MIL-100(Fe) on the Surface of BiVO4: A New Platform for Enhanced Visible-Light-Driven Water Oxidation. ACS Applied Materials & Interfaces 2020, 12 (9) , 10410-10419. https://doi.org/10.1021/acsami.9b21507
  60. Dominick Filonowich, Miguel Luna, Thalia Quinn, Pabitra Choudhury. Electronic Descriptor of Single Metal-Oxo Species on Phthalocyanine- and Porphyrin-Functionalized Graphene toward Methane Activation Process. The Journal of Physical Chemistry C 2020, 124 (8) , 4502-4510. https://doi.org/10.1021/acs.jpcc.9b08697
  61. Sourav Bhowmick, Ankit Dhankhar, Tushar Kanta Sahu, Rohan Jena, Devipriya Gogoi, Nageswara R. Peela, Shane Ardo, Mohammad Qureshi. Low Overpotential and Stable Electrocatalytic Oxygen Evolution Reaction Utilizing Doped Perovskite Oxide, La0.7Sr0.3MnO3, Modified by Cobalt Phosphate. ACS Applied Energy Materials 2020, 3 (2) , 1279-1285. https://doi.org/10.1021/acsaem.9b02167
  62. S. Esmael Balaghi, C. A. Triana, Greta R. Patzke. Molybdenum-Doped Manganese Oxide as a Highly Efficient and Economical Water Oxidation Catalyst. ACS Catalysis 2020, 10 (3) , 2074-2087. https://doi.org/10.1021/acscatal.9b02718
  63. Alireza Karbakhsh Ravari, Guibo Zhu, Roman Ezhov, Yuliana Pineda-Galvan, Allison Page, Whitney Weinschenk, Lifen Yan, Yulia Pushkar. Unraveling the Mechanism of Catalytic Water Oxidation via de Novo Synthesis of Reactive Intermediate. Journal of the American Chemical Society 2020, 142 (2) , 884-893. https://doi.org/10.1021/jacs.9b10265
  64. Koteswara Rao Gorantla, Bhabani S. Mallik. Iron Complex as a Water-Oxidizing Catalyst: Free-Energy Barriers, Proton-Coupled Electron Transfer, Spin Dynamics, and Role of Water Molecules in the Reaction Mechanism. The Journal of Physical Chemistry C 2020, 124 (1) , 205-218. https://doi.org/10.1021/acs.jpcc.9b10378
  65. Kei Ikeda, Muhammad Haris Mahyuddin, Yoshihito Shiota, Aleksandar Staykov, Takahiro Matsumoto, Seiji Ogo, Kazunari Yoshizawa. Computational Study on the Light-Induced Oxidation of Iridium–Aqua Complex to Iridium–Oxo Complex over WO3(001) Surface. Inorganic Chemistry 2020, 59 (1) , 415-422. https://doi.org/10.1021/acs.inorgchem.9b02704
  66. Subhabrata Mukhopadhyay, Olivia Basu, Aranya Kar, Samar K. Das. Efficient Electrocatalytic Water Oxidation by Fe(salen)–MOF Composite: Effect of Modified Microenvironment. Inorganic Chemistry 2020, 59 (1) , 472-483. https://doi.org/10.1021/acs.inorgchem.9b02745
  67. Tuan Le, Thibaut Courant, Jérémy Merad, Clémence Allain, Pierre Audebert, Géraldine Masson. s-Tetrazine Dyes: A Facile Generation of Photoredox Organocatalysts for Routine Oxidations. The Journal of Organic Chemistry 2019, 84 (24) , 16139-16146. https://doi.org/10.1021/acs.joc.9b02454
  68. Jaruwan Amtawong, David Balcells, Jarett Wilcoxen, Rex C. Handford, Naomi Biggins, Andy I. Nguyen, R. David Britt, T. Don Tilley. Isolation and Study of Ruthenium–Cobalt Oxo Cubanes Bearing a High-Valent, Terminal RuV–Oxo with Significant Oxyl Radical Character. Journal of the American Chemical Society 2019, 141 (50) , 19859-19869. https://doi.org/10.1021/jacs.9b10320
  69. Andrea Volpe, Cristina Tubaro, Mirco Natali, Andrea Sartorel, Gary W. Brudvig, Marcella Bonchio. Light-Driven Water Oxidation with the Ir-blue Catalyst and the Ru(bpy)32+/S2O82– Cycle: Photogeneration of Active Dimers, Electron-Transfer Kinetics, and Light Synchronization for Oxygen Evolution with High Quantum Efficiency. Inorganic Chemistry 2019, 58 (24) , 16537-16545. https://doi.org/10.1021/acs.inorgchem.9b02531
  70. Jia Guo, Liugen Zhang, Wenlan Ma, Tinxiang Chen, Guangyao Wang, Naeem Akram, Yi Zhang, Jide Wang. Co(OH)2-Modified CuO Nanoparticles Enabling High-Efficiency Photoinduced Charge Transfer toward the Water Oxidation Reaction. Industrial & Engineering Chemistry Research 2019, 58 (49) , 22236-22243. https://doi.org/10.1021/acs.iecr.9b05346
  71. Qianbao Wu, Mengjun Xiao, Wei Wang, Chunhua Cui. In Situ Coordination Environment Tuning of Cobalt Sites for Efficient Water Oxidation. ACS Catalysis 2019, 9 (12) , 11734-11742. https://doi.org/10.1021/acscatal.9b03762
  72. Xiao-Fang Su, Li-Kai Yan, Zhong-Min Su. Theoretical Insight into the Performance of MnII/III-Monosubstituted Heteropolytungstates as Water Oxidation Catalysts. Inorganic Chemistry 2019, 58 (23) , 15751-15757. https://doi.org/10.1021/acs.inorgchem.9b01806
  73. Xiao-Xi Li, Mian Guo, Bin Qiu, Kyung-Bin Cho, Wei Sun, Wonwoo Nam. High-Spin Mn(V)-Oxo Intermediate in Nonheme Manganese Complex-Catalyzed Alkane Hydroxylation Reaction: Experimental and Theoretical Approach. Inorganic Chemistry 2019, 58 (21) , 14842-14852. https://doi.org/10.1021/acs.inorgchem.9b02543
  74. David Balcells, Eric Clot, Stuart A. Macgregor, Feliu Maseras, Lionel Perrin. A Career in Catalysis: Odile Eisenstein. ACS Catalysis 2019, 9 (11) , 10375-10388. https://doi.org/10.1021/acscatal.9b02498
  75. Namita Sharma, Yong-Min Lee, Xiao-Xi Li, Wonwoo Nam, Shunichi Fukuzumi. Singly Unified Driving Force Dependence of Outer-Sphere Electron-Transfer Pathways of Nonheme Manganese(IV)−Oxo Complexes in the Absence and Presence of Lewis Acids. Inorganic Chemistry 2019, 58 (20) , 13761-13765. https://doi.org/10.1021/acs.inorgchem.9b02403
  76. Shunsuke Watabe, Yuki Tanahashi, Masanari Hirahara, Hirosato Yamazaki, Kosuke Takahashi, Eman A. Mohamed, Yuta Tsubonouchi, Zaki N. Zahran, Kenji Saito, Tatsuto Yui, Masayuki Yagi. Critical Hammett Electron-Donating Ability of Substituent Groups for Efficient Water Oxidation Catalysis by Mononuclear Ruthenium Aquo Complexes. Inorganic Chemistry 2019, 58 (19) , 12716-12723. https://doi.org/10.1021/acs.inorgchem.9b01623
  77. Jennifer M. Le, Kara L. Bren. Engineered Enzymes and Bioinspired Catalysts for Energy Conversion. ACS Energy Letters 2019, 4 (9) , 2168-2180. https://doi.org/10.1021/acsenergylett.9b01308
  78. Qiu-Yun Mao, Yun-Jie Pang, Xi-Chen Li, Guang-Ju Chen, Hong-Wei Tan. Theoretical Study of the Mechanisms of Two Copper Water Oxidation Electrocatalysts with Bipyridine Ligands. ACS Catalysis 2019, 9 (9) , 8798-8809. https://doi.org/10.1021/acscatal.9b01022
  79. S. Gopalakrishnan, G. M. Bhalerao, K. Jeganathan. SrTiO3 NPs/g-C3N4 NSs Coupled Si NWs based Hybrid Photocathode for Visible Light Driven Photoelectrochemical Water Reduction. ACS Sustainable Chemistry & Engineering 2019, 7 (16) , 13911-13919. https://doi.org/10.1021/acssuschemeng.9b02093
  80. Jingguo Li, Wenchao Wan, C. A. Triana, Zbynek Novotny, Jürg Osterwalder, Rolf Erni, Greta R. Patzke. Dynamic Role of Cluster Cocatalysts on Molecular Photoanodes for Water Oxidation. Journal of the American Chemical Society 2019, 141 (32) , 12839-12848. https://doi.org/10.1021/jacs.9b06100
  81. Yoshihiro Shimoyama, Takahiko Kojima. Metal–Oxyl Species and Their Possible Roles in Chemical Oxidations. Inorganic Chemistry 2019, 58 (15) , 9517-9542. https://doi.org/10.1021/acs.inorgchem.8b03459
  82. Sachidulal Biswas, Amritaa Mitra, Sridhar Banerjee, Reena Singh, Abhishek Das, Tapan Kanti Paine, Pinaki Bandyopadhyay, Satadal Paul, Achintesh N. Biswas. A High Spin Mn(IV)-Oxo Complex Generated via Stepwise Proton and Electron Transfer from Mn(III)–Hydroxo Precursor: Characterization and C–H Bond Cleavage Reactivity. Inorganic Chemistry 2019, 58 (15) , 9713-9722. https://doi.org/10.1021/acs.inorgchem.9b00579
  83. Christopher J. Reed, Theodor Agapie. A Terminal FeIII–Oxo in a Tetranuclear Cluster: Effects of Distal Metal Centers on Structure and Reactivity. Journal of the American Chemical Society 2019, 141 (24) , 9479-9484. https://doi.org/10.1021/jacs.9b03157
  84. Seihwan Ahn, Mannkyu Hong, Mahesh Sundararajan, Daniel H. Ess, Mu-Hyun Baik. Design and Optimization of Catalysts Based on Mechanistic Insights Derived from Quantum Chemical Reaction Modeling. Chemical Reviews 2019, 119 (11) , 6509-6560. https://doi.org/10.1021/acs.chemrev.9b00073
  85. Young Hyun Hong, Ji Won Han, Jieun Jung, Tatsuo Nakagawa, Yong-Min Lee, Wonwoo Nam, Shunichi Fukuzumi. Photocatalytic Oxygenation Reactions with a Cobalt Porphyrin Complex Using Water as an Oxygen Source and Dioxygen as an Oxidant. Journal of the American Chemical Society 2019, 141 (23) , 9155-9159. https://doi.org/10.1021/jacs.9b02864
  86. Kei Ikeda, Yuta Hori, Muhammad Haris Mahyuddin, Yoshihito Shiota, Aleksandar Staykov, Takahiro Matsumoto, Kazunari Yoshizawa, Seiji Ogo. Dual Catalytic Cycle of H2 and H2O Oxidations by a Half-Sandwich Iridium Complex: A Theoretical Study. Inorganic Chemistry 2019, 58 (11) , 7274-7284. https://doi.org/10.1021/acs.inorgchem.9b00307
  87. Jorge Nieto, M. Victoria Jiménez, Patricia Álvarez, Ana M. Pérez-Mas, Zoraida González, Rafael Pereira, Beatriz Sánchez-Page, Jesús J. Pérez-Torrente, Javier Blasco, Gloria Subias, Matı́as Blanco, Rosa Menéndez. Enhanced Chemical and Electrochemical Water Oxidation Catalytic Activity by Hybrid Carbon Nanotube-Based Iridium Catalysts Having Sulfonate-Functionalized NHC ligands. ACS Applied Energy Materials 2019, 2 (5) , 3283-3296. https://doi.org/10.1021/acsaem.9b00137
  88. Xin Li, Jiaguo Yu, Mietek Jaroniec, Xiaobo Chen. Cocatalysts for Selective Photoreduction of CO2 into Solar Fuels. Chemical Reviews 2019, 119 (6) , 3962-4179. https://doi.org/10.1021/acs.chemrev.8b00400
  89. Roc Matheu, Mehmed Z. Ertem, Carolina Gimbert-Suriñach, Xavier Sala, Antoni Llobet. Seven Coordinated Molecular Ruthenium–Water Oxidation Catalysts: A Coordination Chemistry Journey. Chemical Reviews 2019, 119 (6) , 3453-3471. https://doi.org/10.1021/acs.chemrev.8b00537
  90. Ying Zhang, Malkanthi K. Karunananda, Hsien-Cheng Yu, Kyle J. Clark, Wendy Williams, Neal P. Mankad, Daniel H. Ess. Dynamically Bifurcating Hydride Transfer Mechanism and Origin of Inverse Isotope Effect for Heterodinuclear AgRu-Catalyzed Alkyne Semihydrogenation. ACS Catalysis 2019, 9 (3) , 2657-2663. https://doi.org/10.1021/acscatal.8b04130
  91. Konstantinos D. Vogiatzis, Mikhail V. Polynski, Justin K. Kirkland, Jacob Townsend, Ali Hashemi, Chong Liu, Evgeny A. Pidko. Computational Approach to Molecular Catalysis by 3d Transition Metals: Challenges and Opportunities. Chemical Reviews 2019, 119 (4) , 2453-2523. https://doi.org/10.1021/acs.chemrev.8b00361
  92. Muniyandi Sankaralingam, Yong-Min Lee, Yuliana Pineda-Galvan, Deepika G. Karmalkar, Mi Sook Seo, So Hyun Jeon, Yulia Pushkar, Shunichi Fukuzumi, Wonwoo Nam. Redox Reactivity of a Mononuclear Manganese-Oxo Complex Binding Calcium Ion and Other Redox-Inactive Metal Ions. Journal of the American Chemical Society 2019, 141 (3) , 1324-1336. https://doi.org/10.1021/jacs.8b11492
  93. Noah D. McMillion, Amanda W. Wilson, McKenna K. Goetz, Mu-Chieh Chang, Chia-Cheng Lin, Wei-Jie Feng, Charles C. L. McCrory, John S. Anderson. Imidazole for Pyridine Substitution Leads to Enhanced Activity Under Milder Conditions in Cobalt Water Oxidation Electrocatalysis. Inorganic Chemistry 2019, 58 (2) , 1391-1397. https://doi.org/10.1021/acs.inorgchem.8b02942
  94. Zoel Codolà, Ilaria Gamba, Ferran Acuña-Parés, Carla Casadevall, Martin Clémancey, Jean-Marc Latour, Josep M. Luis, Julio Lloret-Fillol, Miquel Costas. Design of Iron Coordination Complexes as Highly Active Homogenous Water Oxidation Catalysts by Deuteration of Oxidation-Sensitive Sites. Journal of the American Chemical Society 2019, 141 (1) , 323-333. https://doi.org/10.1021/jacs.8b10211
  95. Lizhou Fan, Peili Zhang, Biaobiao Zhang, Quentin Daniel, Brian J.J. Timmer, Fuguo Zhang, Licheng Sun. 3D Core–Shell NiFeCr Catalyst on a Cu Nanoarray for Water Oxidation: Synergy between Structural and Electronic Modulation. ACS Energy Letters 2018, 3 (12) , 2865-2874. https://doi.org/10.1021/acsenergylett.8b01897
  96. Jimmy Coombs, Dalton Perry, Doo-Hyun Kwon, Christine M. Thomas, Daniel H. Ess. Why Two Metals Are Better Than One for Heterodinuclear Cobalt–Zirconium-Catalyzed Kumada Coupling. Organometallics 2018, 37 (22) , 4195-4203. https://doi.org/10.1021/acs.organomet.8b00449
  97. Nitish Govindarajan, Ambuj Tiwari, Bernd Ensing, Evert Jan Meijer. Impact of the Ligand Flexibility and Solvent on the O–O Bond Formation Step in a Highly Active Ruthenium Water Oxidation Catalyst. Inorganic Chemistry 2018, 57 (21) , 13063-13066. https://doi.org/10.1021/acs.inorgchem.8b00619
  98. Yulia Pushkar, Yuliana Pineda-Galvan, Alireza K. Ravari, Tatiana Otroshchenko, Daniel A. Hartzler. Mechanism for O–O Bond Formation via Radical Coupling of Metal and Ligand Based Radicals: A New Pathway. Journal of the American Chemical Society 2018, 140 (42) , 13538-13541. https://doi.org/10.1021/jacs.8b06836
  99. Máté J. Bezdek, Paul J. Chirik. Proton-Coupled Electron Transfer to a Molybdenum Ethylene Complex Yields a β-Agostic Ethyl: Structure, Dynamics and Mechanism. Journal of the American Chemical Society 2018, 140 (42) , 13817-13826. https://doi.org/10.1021/jacs.8b08460
  100. Ayasha Nadeema, Priyanka S. Walko, R. Nandini Devi, Sreekumar Kurungot. Alkaline Water Electrolysis by NiZn-Double Hydroxide-Derived Porous Nickel Selenide-Nitrogen-Doped Graphene Composite. ACS Applied Energy Materials 2018, 1 (10) , 5500-5510. https://doi.org/10.1021/acsaem.8b01081
Load more citations