Fundamentals and Catalytic Applications of CeO2-Based Materials

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Department of Chemical and Pharmaceutical Sciences, University of Trieste and ICCOM-CNR and INSTM Trieste Research Units Via L. Giorgieri 1, 34127 Trieste, Italy
Cite this: Chem. Rev. 2016, 116, 10, 5987–6041
Publication Date (Web):April 27, 2016
https://doi.org/10.1021/acs.chemrev.5b00603
Copyright © 2016 American Chemical Society
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Abstract

Cerium dioxide (CeO2, ceria) is becoming an ubiquitous constituent in catalytic systems for a variety of applications. 2016 sees the 40th anniversary since ceria was first employed by Ford Motor Company as an oxygen storage component in car converters, to become in the years since its inception an irreplaceable component in three-way catalysts (TWCs). Apart from this well-established use, ceria is looming as a catalyst component for a wide range of catalytic applications. For some of these, such as fuel cells, CeO2-based materials have almost reached the market stage, while for some other catalytic reactions, such as reforming processes, photocatalysis, water-gas shift reaction, thermochemical water splitting, and organic reactions, ceria is emerging as a unique material, holding great promise for future market breakthroughs. While much knowledge about the fundamental characteristics of CeO2-based materials has already been acquired, new characterization techniques and powerful theoretical methods are deepening our understanding of these materials, helping us to predict their behavior and application potential. This review has a wide view on all those aspects related to ceria which promise to produce an important impact on our life, encompassing fundamental knowledge of CeO2 and its properties, characterization toolbox, emerging features, theoretical studies, and all the catalytic applications, organized by their degree of establishment on the market.

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  1. Palle Ramana Murthy, Sehrish Munsif, Jing-Cai Zhang, Wei-Zhen Li. Influence of CeO2 and ZrO2 on the Thermal Stability and Catalytic Activity of SBA-15-Supported Pd Catalysts for CO Oxidation. Industrial & Engineering Chemistry Research 2021, 60 (40) , 14424-14433. https://doi.org/10.1021/acs.iecr.1c02409
  2. Lidiya S. Kibis, Alexander A. Simanenko, Andrey I. Stadnichenko, Vladimir I. Zaikovskii, Andrei I. Boronin. Probing of Pd4+ Species in a PdOx–CeO2 System by X-Ray Photoelectron Spectroscopy. The Journal of Physical Chemistry C 2021, 125 (38) , 20845-20854. https://doi.org/10.1021/acs.jpcc.1c04646
  3. Ziang Su, Wenzhe Si, Hao Liu, Shangchao Xiong, Xuefeng Chu, Wenhao Yang, Yue Peng, Jianjun Chen, Xingzhong Cao, Junhua Li. Boosting the Catalytic Performance of CeO2 in Toluene Combustion via the Ce–Ce Homogeneous Interface. Environmental Science & Technology 2021, 55 (18) , 12630-12639. https://doi.org/10.1021/acs.est.1c03999
  4. Wei Tan, Shaohua Xie, Yandi Cai, Meiyu Wang, Shuohan Yu, Ke-Bin Low, Yuejin Li, Lu Ma, Steven N. Ehrlich, Fei Gao, Lin Dong, Fudong Liu. Transformation of Highly Stable Pt Single Sites on Defect Engineered Ceria into Robust Pt Clusters for Vehicle Emission Control. Environmental Science & Technology 2021, 55 (18) , 12607-12618. https://doi.org/10.1021/acs.est.1c02853
  5. Wen-Zhu Yu, Mei-Yao Wu, Wei-Wei Wang, Chun-Jiang Jia. In Situ Generation of the Surface Oxygen Vacancies in a Copper–Ceria Catalyst for the Water–Gas Shift Reaction. Langmuir 2021, 37 (35) , 10499-10509. https://doi.org/10.1021/acs.langmuir.1c01428
  6. Jawaher Mosrati, Ali M. Abdel-Mageed, Thanh Huyen Vuong, Reni Grauke, Stephan Bartling, Nils Rockstroh, Hanan Atia, Udo Armbruster, Sebastian Wohlrab, Jabor Rabeah, Angelika Brückner. Tiny Species with Big Impact: High Activity of Cu Single Atoms on CeO2–TiO2 Deciphered by Operando Spectroscopy. ACS Catalysis 2021, 11 (17) , 10933-10949. https://doi.org/10.1021/acscatal.1c02349
  7. Jing Qin, Youyou Feng, Dong Cheng, Biwu Liu, Zheng Wang, Yongxi Zhao, Jing Wei. Construction of a Mesoporous Ceria Hollow Sphere/Enzyme Nanoreactor for Enhanced Cascade Catalytic Antibacterial Therapy. ACS Applied Materials & Interfaces 2021, 13 (34) , 40302-40314. https://doi.org/10.1021/acsami.1c10821
  8. Yinzhou Guo, Héloïse Thérien-Aubin. Nanofibrous Photocatalytic Membranes Based on Tailored Anisotropic Gold/Ceria Nanoparticles. ACS Applied Materials & Interfaces 2021, 13 (31) , 37578-37588. https://doi.org/10.1021/acsami.1c11954
  9. Xiubing Huang, Kaiyue Zhang, Baoxiang Peng, Ge Wang, Martin Muhler, Feng Wang. Ceria-Based Materials for Thermocatalytic and Photocatalytic Organic Synthesis. ACS Catalysis 2021, 11 (15) , 9618-9678. https://doi.org/10.1021/acscatal.1c02443
  10. Mizuho Yabushita, Motohiro Yoshida, Ryota Osuga, Fumiya Muto, Shoji Iguchi, Shuhei Yasuda, Atsushi Neya, Mami Horie, Sachiko Maki, Kiyoshi Kanie, Ichiro Yamanaka, Toshiyuki Yokoi, Atsushi Muramatsu. Mechanochemical Route for Preparation of MFI-Type Zeolites Containing Highly Dispersed and Small Ce Species and Catalytic Application to Low-Temperature Oxidative Coupling of Methane. Industrial & Engineering Chemistry Research 2021, 60 (28) , 10101-10111. https://doi.org/10.1021/acs.iecr.1c01664
  11. Yubing Lu, Shulan Zhou, Chun-Te Kuo, Deepak Kunwar, Coogan Thompson, Adam S. Hoffman, Alexey Boubnov, Sen Lin, Abhaya K. Datye, Hua Guo, Ayman M. Karim. Unraveling the Intermediate Reaction Complexes and Critical Role of Support-Derived Oxygen Atoms in CO Oxidation on Single-Atom Pt/CeO2. ACS Catalysis 2021, 11 (14) , 8701-8715. https://doi.org/10.1021/acscatal.1c01900
  12. Jennifer M. Empey, Christopher Grieco, Natasha W. Pettinger, Bern Kohler. Ultrafast Electron Injection and Recombination Dynamics of Coumarin 343-Sensitized Cerium Oxide Nanoparticles. The Journal of Physical Chemistry C 2021, 125 (27) , 14827-14835. https://doi.org/10.1021/acs.jpcc.1c03904
  13. Ryland C. Forsythe, Connor P. Cox, Madeleine K. Wilsey, Astrid M. Müller. Pulsed Laser in Liquids Made Nanomaterials for Catalysis. Chemical Reviews 2021, 121 (13) , 7568-7637. https://doi.org/10.1021/acs.chemrev.0c01069
  14. Marc Ziemba, Christian Schilling, M. Verónica Ganduglia-Pirovano, Christian Hess. Toward an Atomic-Level Understanding of Ceria-Based Catalysts: When Experiment and Theory Go Hand in Hand. Accounts of Chemical Research 2021, 54 (13) , 2884-2893. https://doi.org/10.1021/acs.accounts.1c00226
  15. Luca Brugnoli, Maria Cristina Menziani, Shingo Urata, Alfonso Pedone. Development and Application of a ReaxFF Reactive Force Field for Cerium Oxide/Water Interfaces. The Journal of Physical Chemistry A 2021, 125 (25) , 5693-5708. https://doi.org/10.1021/acs.jpca.1c04078
  16. Feng-qiu Chen, Yang Xia, Jia-zheng Lao, Dang-guo Cheng, Xiao-li Zhan. Unraveling the Change in Multiple Cu Species Present in CuO/CeO2 over the Preferential CO Oxidation Reaction. Industrial & Engineering Chemistry Research 2021, 60 (25) , 9068-9079. https://doi.org/10.1021/acs.iecr.1c01289
  17. Beom-Sik Kim, Junemin Bae, Hojin Jeong, Chanyeong Choe, Hyunjoo Lee. Surface Restructuring of Supported Nano-Ceria for Improving Sulfur Resistance. ACS Catalysis 2021, 11 (12) , 7154-7159. https://doi.org/10.1021/acscatal.1c02209
  18. Lukasz Wolski, Oleg I. Lebedev, Colin P. Harmer, Kirill Kovnir, Hanen Abdelli, Tomasz Grzyb, Marco Daturi, Mohamad El-Roz. Unraveling the Origin of Photocatalytic Deactivation in CeO2/Nb2O5 Heterostructure Systems during Methanol Oxidation: Insight into the Role of Cerium Species. The Journal of Physical Chemistry C 2021, 125 (23) , 12650-12662. https://doi.org/10.1021/acs.jpcc.1c02812
  19. Si Luo, Meijun Li, Victor Fung, Bobby G. Sumpter, Jue Liu, Zili Wu, Katharine Page. New Insights into the Bulk and Surface Defect Structures of Ceria Nanocrystals from Neutron Scattering Study. Chemistry of Materials 2021, 33 (11) , 3959-3970. https://doi.org/10.1021/acs.chemmater.1c00156
  20. Yukiko Hosono, Hikaru Saito, Takuma Higo, Kosuke Watanabe, Kazuharu Ito, Hideaki Tsuneki, Shun Maeda, Kunihide Hashimoto, Yasushi Sekine. Co–CeO2 Interaction Induces the Mars–van Krevelen Mechanism in Dehydrogenation of Ethane. The Journal of Physical Chemistry C 2021, 125 (21) , 11411-11418. https://doi.org/10.1021/acs.jpcc.1c02855
  21. Hayato Tsurugi, Kazushi Mashima. Renaissance of Homogeneous Cerium Catalysts with Unique     Ce(IV/III) Couple: Redox-Mediated Organic Transformations Involving Homolysis of Ce(IV)–Ligand Covalent Bonds. Journal of the American Chemical Society 2021, 143 (21) , 7879-7890. https://doi.org/10.1021/jacs.1c02889
  22. Shaohua Xie, Zhiwei Wang, Wei Tan, Yatong Zhu, Samantha Collier, Lu Ma, Steven N. Ehrlich, Peng Xu, Yong Yan, Tao Xu, Jiguang Deng, Fudong Liu. Highly Active and Stable Palladium Catalysts on Novel Ceria–Alumina Supports for Efficient Oxidation of Carbon Monoxide and Hydrocarbons. Environmental Science & Technology 2021, 55 (11) , 7624-7633. https://doi.org/10.1021/acs.est.1c00077
  23. Jinqiu Guo, Zongjing Feng, Jun Xu, Jie Zhu, Guanghui Zhang, Yaping Du, Hongbo Zhang, Chunhua Yan. Facile Preparation of Methyl Phenols from Ethanol over Lamellar Ce(OH)SO4·xH2O. ACS Catalysis 2021, 11 (10) , 6162-6174. https://doi.org/10.1021/acscatal.1c01096
  24. C. Brambila, D. C. Sayle, M. Molinari, J. Nutter, J. M. Flitcroft, T. X. T. Sayle, T. Sakthivel, S. Seal, G. Möbus. Tomographic Study of Mesopore Formation in Ceria Nanorods. The Journal of Physical Chemistry C 2021, 125 (18) , 10077-10089. https://doi.org/10.1021/acs.jpcc.1c01221
  25. Zhiyu Zhou, Michael P. Harold, Dan Luss. Dynamic Oxygen Storage Capacity of Ceria-Zirconia and Mn0.5Fe2.5O4 Spinel: Experiments and Modeling. Industrial & Engineering Chemistry Research 2021, 60 (18) , 6465-6482. https://doi.org/10.1021/acs.iecr.0c05187
  26. Manoj Kumar Ghosalya, Xiansheng Li, Arik Beck, Jeroen Anton van Bokhoven, Luca Artiglia. Size of Ceria Particles Influences Surface Hydroxylation and Hydroxyl Stability. The Journal of Physical Chemistry C 2021, 125 (17) , 9303-9309. https://doi.org/10.1021/acs.jpcc.1c01718
  27. Alvin M. H. Lim, Hua Chun Zeng. Antisolvent Route to Ultrathin Hollow Spheres of Cerium Oxide for Enhanced CO Oxidation. ACS Applied Materials & Interfaces 2021, 13 (17) , 20501-20510. https://doi.org/10.1021/acsami.1c01320
  28. Liang Chen, Rui Lin, Xiaoting Yu, Tong Zheng, Mengcheng Dong, Mingyu Lou, Yunyang Ma, Zhixian Hao. Microporous Layer Containing CeO2-Doped 3D Graphene Foam for Proton Exchange Membrane Fuel Cells at Varying Operating Conditions. ACS Applied Materials & Interfaces 2021, 13 (17) , 20201-20212. https://doi.org/10.1021/acsami.1c03699
  29. Zhi Liu, Jia Zheng, Lianfeng Duan, Zhi Zhu. Biomass-Assisted Synthesis of CeO2 Nanorods for CO2 Photoreduction under Visible Light. ACS Applied Nano Materials 2021, 4 (4) , 4226-4237. https://doi.org/10.1021/acsanm.1c00720
  30. Suyeon Hyun, Vasu Kaker, Arumugam Sivanantham, Junhyung Hong, Sangaraju Shanmugam. The Influence of Porous Co/CeO1.88-Nitrogen-Doped Carbon Nanorods on the Specific Capacity of Li-O2 Batteries. ACS Applied Materials & Interfaces 2021, 13 (15) , 17699-17706. https://doi.org/10.1021/acsami.1c03095
  31. Xin-Pu Fu, Wen-Zhu Yu, Meng-Yuan Li, Rui Si, Chao Ma, Chun-Jiang Jia. Facile Fabrication of CeO2-Al2O3 Hollow Sphere with Atomically Dispersed Fe via Spray Pyrolysis. Inorganic Chemistry 2021, 60 (7) , 5183-5189. https://doi.org/10.1021/acs.inorgchem.1c00194
  32. Ruiying Zhao, Haile Liu, Yongming Li, Meili Guo, Xiao-Dong Zhang. Catalytic Nanozyme for Radiation Protection. Bioconjugate Chemistry 2021, 32 (3) , 411-429. https://doi.org/10.1021/acs.bioconjchem.0c00648
  33. Guillaume Gouget, Morgane Pellerin, Rabih Al Rahal Al Orabi, Lauriane Pautrot-D’Alençon, Thierry Le Mercier, Christopher B. Murray. Rare-Earth Sulfide Nanocrystals from Wet Colloidal Synthesis: Tunable Compositions, Size-Dependent Light Absorption, and Sensitized Rare-Earth Luminescence. Journal of the American Chemical Society 2021, 143 (9) , 3300-3305. https://doi.org/10.1021/jacs.0c13433
  34. Florian Jonas, Bénédicte Lebeau, Stéphane Siffert, Laure Michelin, Christophe Poupin, Renaud Cousin, Ludovic Josien, Loïc Vidal, Martine Mallet, Pierrick Gaudin, Jean-Luc Blin. Nanoporous CeO2–ZrO2 Oxides for Oxidation of Volatile Organic Compounds. ACS Applied Nano Materials 2021, 4 (2) , 1786-1797. https://doi.org/10.1021/acsanm.0c03212
  35. Yilin Zhao, Haotian Li, Yaoqiang Wang, Yawen Wang, Zhicheng Huang, Haijia Su, Juewen Liu. CeO2 Nanoparticle Transformation to Nanorods and Nanoflowers in Acids with Boosted Oxidative Catalytic Activity. ACS Applied Nano Materials 2021, 4 (2) , 2098-2107. https://doi.org/10.1021/acsanm.0c03387
  36. Jue Zhou, Rui-tang Guo, Xin-fu Zhang, Yuan-zhen Liu, Chao-peng Duan, Gui-lin Wu, Wei-guo Pan. Cerium Oxide-Based Catalysts for Low-Temperature Selective Catalytic Reduction of NOx with NH3: A Review. Energy & Fuels 2021, 35 (4) , 2981-2998. https://doi.org/10.1021/acs.energyfuels.0c04231
  37. Sinmyung Yoon, Jinwoung Jo, Beomjoon Jeon, Jihyeon Lee, Min Gee Cho, Myoung Hwan Oh, Beomgyun Jeong, Tae Joo Shin, Hu Young Jeong, Jeong Young Park, Taeghwan Hyeon, Kwangjin An. Revealing Charge Transfer at the Interface of Spinel Oxide and Ceria during CO Oxidation. ACS Catalysis 2021, 11 (3) , 1516-1527. https://doi.org/10.1021/acscatal.0c04091
  38. Arun Ramanathan, Johannes E. Leisen, Henry S. La Pierre. In-Plane Cation Ordering and Sodium Displacements in Layered Honeycomb Oxides with Tetravalent Lanthanides: Na2LnO3 (Ln = Ce, Pr, and Tb). Inorganic Chemistry 2021, 60 (3) , 1398-1410. https://doi.org/10.1021/acs.inorgchem.0c02628
  39. Hong-Guang Jin, Mingyu Wang, Jian-Xin Wen, Sheng-Hua Han, Xu-Jia Hong, Yue-Peng Cai, Guangli Li, Jincheng Fan, Zi-Sheng Chao. Oxygen Vacancy-Rich Mixed-Valence Cerium MOF: An Efficient Separator Coating to High-Performance Lithium–Sulfur Batteries. ACS Applied Materials & Interfaces 2021, 13 (3) , 3899-3910. https://doi.org/10.1021/acsami.0c18899
  40. Antony Joseph, Kevin P. John Mathew, Sajith Vandana. Zirconium-Doped Ceria Nanoparticles as Anticorrosion Pigments in Waterborne Epoxy–Polymer Coatings. ACS Applied Nano Materials 2021, 4 (1) , 834-849. https://doi.org/10.1021/acsanm.0c03162
  41. Qin Wu, Xiaoping Chen, Jinxing Mi, Sixiang Cai, Lei Ma, Weitao Zhao, Jianjun Chen, Junhua Li. The Absence of Oxygen in Sulfation Promotes the Performance of the Sulfated CeO2 Catalyst for Low-Temperature Selective Catalytic Reduction of NOx by NH3: Redox Property versus Acidity. ACS Sustainable Chemistry & Engineering 2021, 9 (2) , 967-979. https://doi.org/10.1021/acssuschemeng.0c08427
  42. Xuanyu Yang, Yanyan Li, Junhao Ma, Yidong Zou, Xinran Zhou, Xiaowei Cheng, Fahad A. Alharthi, Abdulaziz A. Alghamdi, Yonghui Deng. General and Efficient Synthesis of Two-Dimensional Monolayer Mesoporous Materials with Diverse Framework Compositions. ACS Applied Materials & Interfaces 2021, 13 (1) , 1222-1233. https://doi.org/10.1021/acsami.0c18027
  43. Meng Wang, Yan Zhang, Yunbo Yu, Wenpo Shan, Hong He. Synergistic Effects of Multicomponents Produce Outstanding Soot Oxidation Activity in a Cs/Co/MnOx Catalyst. Environmental Science & Technology 2021, 55 (1) , 240-248. https://doi.org/10.1021/acs.est.0c06082
  44. Zhixiang Ren, Hongliang Zhang, Guangying Wang, Youchun Pan, Zhengwei Yu, Hongming Long. Effect of Calcination Temperature on the Activation Performance and Reaction Mechanism of Ce–Mn–Ru/TiO2 Catalysts for Selective Catalytic Reduction of NO with NH3. ACS Omega 2020, 5 (51) , 33357-33371. https://doi.org/10.1021/acsomega.0c05194
  45. Antonio Jose Exposito, Patrick J. Barrie, Laura Torrente-Murciano. Fast Synthesis of CeO2 Nanoparticles in a Continuous Microreactor Using Deep Eutectic Reline As Solvent. ACS Sustainable Chemistry & Engineering 2020, 8 (49) , 18297-18302. https://doi.org/10.1021/acssuschemeng.0c06949
  46. Ruixi Gao, Xiang Liu, Tian C. Zhang, Like Ouyang, Ying Liang, Shaojun Yuan. Superhydrophobic Copper Foam Modified with n-Dodecyl Mercaptan-CeO2 Nanosheets for Efficient Oil/Water Separation and Oil Spill Cleanup. Industrial & Engineering Chemistry Research 2020, 59 (49) , 21510-21521. https://doi.org/10.1021/acs.iecr.0c04515
  47. Pascal Cop, Erdogan Celik, Kevin Hess, Yannik Moryson, Philip Klement, Matthias T. Elm, Bernd M. Smarsly. Atomic Layer Deposition of Nanometer-Sized CeO2 Layers in Ordered Mesoporous ZrO2 Films and Their Impact on the Ionic/Electronic Conductivity. ACS Applied Nano Materials 2020, 3 (11) , 10757-10766. https://doi.org/10.1021/acsanm.0c02060
  48. Tohru Shiga, Yumi Masuoka, Yuichi Kato. Competition between Conversion Reaction with Cerium Dioxide and Lithium Plating in Superconcentrated Electrolyte. Langmuir 2020, 36 (46) , 14039-14045. https://doi.org/10.1021/acs.langmuir.0c02622
  49. Adam R. Symington, Robert M. Harker, Mark T. Storr, Marco Molinari, Stephen C. Parker. Thermodynamic Evolution of Cerium Oxide Nanoparticle Morphology Using Carbon Dioxide. The Journal of Physical Chemistry C 2020, 124 (42) , 23210-23220. https://doi.org/10.1021/acs.jpcc.0c07437
  50. Nan Yang, Daniel Knez, Giovanni Vinai, Piero Torelli, Regina Ciancio, Pasquale Orgiani, Carmela Aruta. Improved Structural Properties in Homogeneously Doped Sm0.4Ce0.6O2−δ Epitaxial Thin Films: High Doping Effect on the Electronic Bands. ACS Applied Materials & Interfaces 2020, 12 (42) , 47556-47563. https://doi.org/10.1021/acsami.0c13495
  51. Richa Bhargava, Jyoti Shah, Shakeel Khan, R. K. Kotnala. Hydroelectric Cell Based on a Cerium Oxide-Decorated Reduced Graphene Oxide (CeO2–rG) Nanocomposite Generates Green Electricity by Room-Temperature Water Splitting. Energy & Fuels 2020, 34 (10) , 13067-13078. https://doi.org/10.1021/acs.energyfuels.0c02192
  52. Megan C. Wasson, Xuan Zhang, Ken-ichi Otake, Andrew S. Rosen, Selim Alayoglu, Matthew D. Krzyaniak, Zhijie Chen, Louis R. Redfern, Lee Robison, Florencia A. Son, Yongwei Chen, Timur Islamoglu, Justin M. Notestein, Randall Q. Snurr, Michael R. Wasielewski, Omar K. Farha. Supramolecular Porous Assemblies of Atomically Precise Catalytically Active Cerium-Based Clusters. Chemistry of Materials 2020, 32 (19) , 8522-8529. https://doi.org/10.1021/acs.chemmater.0c02740
  53. Ziang Su, Wenhao Yang, Chizhong Wang, Shangchao Xiong, Xingzhong Cao, Yue Peng, Wenzhe Si, Yibin Weng, Ming Xue, Junhua Li. Roles of Oxygen Vacancies in the Bulk and Surface of CeO2 for Toluene Catalytic Combustion. Environmental Science & Technology 2020, 54 (19) , 12684-12692. https://doi.org/10.1021/acs.est.0c03981
  54. Yimeng Lyu, Jennifer Jocz, Rui Xu, Eli Stavitski, Carsten Sievers. Nickel Speciation and Methane Dry Reforming Performance of Ni/CexZr1–xO2 Prepared by Different Synthesis Methods. ACS Catalysis 2020, 10 (19) , 11235-11252. https://doi.org/10.1021/acscatal.0c02426
  55. Dong Jiang, Gang Wan, Carlos E. García-Vargas, Linze Li, Xavier Isidro Pereira-Hernández, Chongmin Wang, Yong Wang. Elucidation of the Active Sites in Single-Atom Pd1/CeO2 Catalysts for Low-Temperature CO Oxidation. ACS Catalysis 2020, 10 (19) , 11356-11364. https://doi.org/10.1021/acscatal.0c02480
  56. Giovanni Valenti, Michele Melchionna, Tiziano Montini, Alessandro Boni, Lucia Nasi, Emiliano Fonda, Alejandro Criado, Andrea Zitolo, Silvia Voci, Giovanni Bertoni, Marcella Bonchio, Paolo Fornasiero, Francesco Paolucci, Maurizio Prato. Water-Mediated ElectroHydrogenation of CO2 at Near-Equilibrium Potential by Carbon Nanotubes/Cerium Dioxide Nanohybrids. ACS Applied Energy Materials 2020, 3 (9) , 8509-8518. https://doi.org/10.1021/acsaem.0c01145
  57. Andreas M. Gänzler, Benjamin Betz, Sina Baier-Stegmaier, Stéphanie Belin, Valérie Briois, Martin Votsmeier, Maria Casapu. Operando X-ray Absorption Spectroscopy Study During Conditioning of Pt-Based Catalysts and Its Implications for CO Oxidation. The Journal of Physical Chemistry C 2020, 124 (37) , 20090-20100. https://doi.org/10.1021/acs.jpcc.0c04740
  58. Chengwu Yang, Marçal Capdevila-Cortada, Chunyan Dong, Yan Zhou, Junjun Wang, Xiaojuan Yu, Alexei Nefedov, Stefan Heißler, Núria López, Wenjie Shen, Christof Wöll, Yuemin Wang. Surface Refaceting Mechanism on Cubic Ceria. The Journal of Physical Chemistry Letters 2020, 11 (18) , 7925-7931. https://doi.org/10.1021/acs.jpclett.0c02409
  59. Shuai Zhang, Haozhe Wang, Huayan Si, Xiaoqian Jia, Ziyan Wang, Qiang Li, Jing Kong, Jianbin Zhang. Novel Core–Shell (ε-MnO2/CeO2)@CeO2 Composite Catalyst with a Synergistic Effect for Efficient Formaldehyde Oxidation. ACS Applied Materials & Interfaces 2020, 12 (36) , 40285-40295. https://doi.org/10.1021/acsami.0c09263
  60. Zhongqi Liu, Yang Lu, Matthew P. Confer, Hao Cui, Junhao Li, Yudong Li, Yifan Wang, Shane C. Street, Evan K. Wujcik, Ruigang Wang. Thermally Stable RuOx–CeO2 Nanofiber Catalysts for Low-Temperature CO Oxidation. ACS Applied Nano Materials 2020, 3 (8) , 8403-8413. https://doi.org/10.1021/acsanm.0c01815
  61. Antonia Infantes-Molina, Andrea Villanova, Aldo Talon, Mojtaba Gilzad Kohan, Alessandro Gradone, Raffaello Mazzaro, Vittorio Morandi, Alberto Vomiero, Elisa Moretti. Au-Decorated Ce–Ti Mixed Oxides for Efficient CO Preferential Photooxidation. ACS Applied Materials & Interfaces 2020, 12 (34) , 38019-38030. https://doi.org/10.1021/acsami.0c08258
  62. Vesna Lazić, Ljiljana S. Živković, Dušan Sredojević, Margarida M. Fernandes, Senentxu Lanceros-Mendez, S. Phillip Ahrenkiel, Jovan M. Nedeljković. Tuning Properties of Cerium Dioxide Nanoparticles by Surface Modification with Catecholate-type of Ligands. Langmuir 2020, 36 (33) , 9738-9746. https://doi.org/10.1021/acs.langmuir.0c01163
  63. Shiwei Ma, Shiyi Chen, Huijun Ge, Tao Song, Ping Lu, Wenguo Xiang. Synergistic Effects of the Zr and Sm Co-doped Fe2O3/CeO2 Oxygen Carrier for Chemical Looping Hydrogen Generation. Energy & Fuels 2020, 34 (8) , 10256-10267. https://doi.org/10.1021/acs.energyfuels.0c01027
  64. Haoming Yan, Zhongqi Liu, Shize Yang, Xiaozhou Yu, Tao Liu, Qianying Guo, Junhao Li, Ruigang Wang, Qing Peng. Stable and Catalytically Active Shape-Engineered Cerium Oxide Nanorods by Controlled Doping of Aluminum Cations. ACS Applied Materials & Interfaces 2020, 12 (33) , 37774-37783. https://doi.org/10.1021/acsami.0c11049
  65. Giulia Righi, Rita Magri, Annabella Selloni. Methane Activation on Metal-Doped (111) and (100) Ceria Surfaces with Charge-Compensating Oxygen Vacancies. The Journal of Physical Chemistry C 2020, 124 (32) , 17578-17585. https://doi.org/10.1021/acs.jpcc.0c03320
  66. Gianluca Pauletto, Angelo Vaccari, Gianpiero Groppi, Lauriane Bricaud, Patricia Benito, Daria C. Boffito, Johannes A. Lercher, Gregory S. Patience. FeCrAl as a Catalyst Support. Chemical Reviews 2020, 120 (15) , 7516-7550. https://doi.org/10.1021/acs.chemrev.0c00149
  67. Lijun Lei, Yehong Wang, Zhixin Zhang, Jinghua An, Feng Wang. Transformations of Biomass, Its Derivatives, and Downstream Chemicals over Ceria Catalysts. ACS Catalysis 2020, 10 (15) , 8788-8814. https://doi.org/10.1021/acscatal.0c01900
  68. Weiwei Xia, Jing Mao, Feng Xu, Mingxing Gong, Xiaodong Tan, Yuting Shen, Litao Sun, Huolin L. Xin. Atomic Modulation Engineering of Hexagon-Shaped CeO2 Nanocrystals by In Situ Sculpturing of an Electron Beam. The Journal of Physical Chemistry C 2020, 124 (31) , 17006-17014. https://doi.org/10.1021/acs.jpcc.0c04106
  69. Xin He, Benjamin G. Looker, Kimberly T. Dinh, Amanda W. Stubbs, Tianyang Chen, Randall J. Meyer, Pedro Serna, Yuriy Román-Leshkov, Kyle M. Lancaster, Mircea Dincă. Cerium(IV) Enhances the Catalytic Oxidation Activity of Single-Site Cu Active Sites in MOFs. ACS Catalysis 2020, 10 (14) , 7820-7825. https://doi.org/10.1021/acscatal.0c02493
  70. Anita Haeussler, Stéphane Abanades, Fernando A. Costa Oliveira, M. Alexandra Barreiros, A. P. F. Caetano, Rui M. Novais, Robert C. Pullar. Solar Redox Cycling of Ceria Structures Based on Fiber Boards, Foams, and Biomimetic Cork-Derived Ecoceramics for Two-Step Thermochemical H2O and CO2 Splitting. Energy & Fuels 2020, 34 (7) , 9037-9049. https://doi.org/10.1021/acs.energyfuels.0c01240
  71. Zicong Tan, Jieru Zhang, Yu-Cheng Chen, Jyh-Pin Chou, Yung-Kang Peng. Unravelling the Role of Structural Geometry and Chemical State of Well-Defined Oxygen Vacancies on Pristine CeO2 for H2O2 Activation. The Journal of Physical Chemistry Letters 2020, 11 (14) , 5390-5396. https://doi.org/10.1021/acs.jpclett.0c01557
  72. Catherine Dejoie, Yi Yu, Fabiano Bernardi, Nobumichi Tamura, Martin Kunz, Matthew A. Marcus, Yi-Lin Huang, Chunjuan Zhang, Bryan W. Eichhorn, Zhi Liu. Potential Control of Oxygen Non-Stoichiometry in Cerium Oxide and Phase Transition Away from Equilibrium. ACS Applied Materials & Interfaces 2020, 12 (28) , 31514-31521. https://doi.org/10.1021/acsami.0c08284
  73. Sayak Das Gupta, Robert L. Stewart, Dian-Teng Chen, Khalil A. Abboud, Hai-Ping Cheng, Stephen Hill, George Christou. Long-Range Ferromagnetic Exchange Interactions Mediated by Mn–CeIV–Mn Superexchange Involving Empty 4f Orbitals. Inorganic Chemistry 2020, 59 (13) , 8716-8726. https://doi.org/10.1021/acs.inorgchem.0c00332
  74. Stefania Benedetti, Giulia Righi, Paola Luches, Sergio D’Addato, Rita Magri, Annabella Selloni. Surface Reactivity of Ag-Modified Ceria to Hydrogen: A Combined Experimental and Theoretical Investigation. ACS Applied Materials & Interfaces 2020, 12 (24) , 27682-27690. https://doi.org/10.1021/acsami.0c03968
  75. Yongcheng Tong, Xie Meng, Ting Luo, Changsong Cui, Yue Wang, Shiwei Wang, Ranran Peng, B. Xie, Chusheng Chen, Zhongliang Zhan. Protonic Ceramic Electrochemical Cell for Efficient Separation of Hydrogen. ACS Applied Materials & Interfaces 2020, 12 (23) , 25809-25817. https://doi.org/10.1021/acsami.0c04024
  76. Zequan Hu, Si Wang, Xin Zhang, Guoli Fan, Yingdi Lv, Xiaodong Zheng, Lan Yang, Feng Li. Simultaneous Enhancements of Ultraviolet-Shielding Properties and Thermal Stability/Photostability of Poly(vinyl chloride) via Incorporation of Defect-Rich CeO2 Nanoparticles. Industrial & Engineering Chemistry Research 2020, 59 (21) , 9959-9968. https://doi.org/10.1021/acs.iecr.0c00196
  77. Sriram Mansingh, Debasmita Kandi, Kundan Kumar Das, Kulamani Parida. A Mechanistic Approach on Oxygen Vacancy-Engineered CeO2 Nanosheets Concocts over an Oyster Shell Manifesting Robust Photocatalytic Activity toward Water Oxidation. ACS Omega 2020, 5 (17) , 9789-9805. https://doi.org/10.1021/acsomega.9b04420
  78. Mohamed H. Hassan, Daniel Andreescu, Silvana Andreescu. Cerium Oxide Nanoparticles Stabilized within Metal–Organic Frameworks for the Degradation of Nerve Agents. ACS Applied Nano Materials 2020, 3 (4) , 3288-3294. https://doi.org/10.1021/acsanm.0c00015
  79. Meenakshisundaram Sankar, Qian He, Rebecca V. Engel, Mala A. Sainna, Andrew J. Logsdail, Alberto Roldan, David J. Willock, Nishtha Agarwal, Christopher J. Kiely, Graham J. Hutchings. Role of the Support in Gold-Containing Nanoparticles as Heterogeneous Catalysts. Chemical Reviews 2020, 120 (8) , 3890-3938. https://doi.org/10.1021/acs.chemrev.9b00662
  80. Damien Prieur, Walter Bonani, Karin Popa, Olaf Walter, Kyle W. Kriegsman, Mark H. Engelhard, Xiaofeng Guo, Rachel Eloirdi, Thomas Gouder, Aaron Beck, Tonya Vitova, Andreas C. Scheinost, Kristina Kvashnina, Philippe Martin. Size Dependence of Lattice Parameter and Electronic Structure in CeO2 Nanoparticles. Inorganic Chemistry 2020, 59 (8) , 5760-5767. https://doi.org/10.1021/acs.inorgchem.0c00506
  81. Yang Song, Yunhong Pi, Xuanyu Feng, Kaiyuan Ni, Ziwan Xu, Justin S. Chen, Zhong Li, Wenbin Lin. Cerium-Based Metal–Organic Layers Catalyze Hydrogen Evolution Reaction through Dual Photoexcitation. Journal of the American Chemical Society 2020, 142 (15) , 6866-6871. https://doi.org/10.1021/jacs.0c00679
  82. Shuaihu Jiang, Ruya Zhang, Hongxian Liu, Yuan Rao, Yanan Yu, Shan Chen, Qin Yue, Yanning Zhang, Yijin Kang. Promoting Formation of Oxygen Vacancies in Two-Dimensional Cobalt-Doped Ceria Nanosheets for Efficient Hydrogen Evolution. Journal of the American Chemical Society 2020, 142 (14) , 6461-6466. https://doi.org/10.1021/jacs.9b13915
  83. Baile Wu, Irene M.C. Lo. Surface Functional Group Engineering of CeO2 Particles for Enhanced Phosphate Adsorption. Environmental Science & Technology 2020, 54 (7) , 4601-4608. https://doi.org/10.1021/acs.est.9b06812
  84. Zicong Tan, Guangchao Li, Hung-Lung Chou, Yiyang Li, Xianfeng Yi, Abdul Hanif Mahadi, Anmin Zheng, Shik Chi Edman Tsang, Yung-Kang Peng. Differentiating Surface Ce Species among CeO2 Facets by Solid-State NMR for Catalytic Correlation. ACS Catalysis 2020, 10 (7) , 4003-4011. https://doi.org/10.1021/acscatal.0c00014
  85. Behnam Safavinia, Yuming Wang, Changyi Jiang, Cameron Roman, Pragathi Darapaneni, Jarod Larriviere, David A. Cullen, Kerry M. Dooley, James A. Dorman. Enhancing CexZr1–xO2 Activity for Methane Dry Reforming Using Subsurface Ni Dopants. ACS Catalysis 2020, 10 (7) , 4070-4079. https://doi.org/10.1021/acscatal.0c00203
  86. Xiaohai Zheng, Yanli Li, Yong Zheng, Lijuan Shen, Yihong Xiao, Yanning Cao, Yongfan Zhang, Chaktong Au, Lilong Jiang. Highly Efficient Porous FexCe1–xO2−δ with Three-Dimensional Hierarchical Nanoflower Morphology for H2S-Selective Oxidation. ACS Catalysis 2020, 10 (7) , 3968-3983. https://doi.org/10.1021/acscatal.9b05486
  87. Aditya W. Sakti, Chien-Pin Chou, Hiromi Nakai. Density-Functional Tight-Binding Study of Carbonaceous Species Diffusion on the (100)-γ-Al2O3 Surface. ACS Omega 2020, 5 (12) , 6862-6871. https://doi.org/10.1021/acsomega.0c00203
  88. Aurélien R. Willauer, Chad T. Palumbo, Farzaneh Fadaei-Tirani, Ivica Zivkovic, Iskander Douair, Laurent Maron, Marinella Mazzanti. Accessing the +IV Oxidation State in Molecular Complexes of Praseodymium. Journal of the American Chemical Society 2020, 142 (12) , 5538-5542. https://doi.org/10.1021/jacs.0c01204
  89. Yi-Chun Huang, Shi-Hong Wu, Chien-Hsuan Hsiao, An-Ting Lee, Michael H. Huang. Mild Synthesis of Size-Tunable CeO2 Octahedra for Band Gap Variation. Chemistry of Materials 2020, 32 (6) , 2631-2638. https://doi.org/10.1021/acs.chemmater.0c00318
  90. Xueqiong Zhang, Dan Zhou, Xiaojing Wang, Jian Zhou, Jiefei Li, Mingkai Zhang, Yihong Shen, Haibin Chu, Yongquan Qu. Overcoming the Deactivation of Pt/CNT by Introducing CeO2 for Selective Base-Free Glycerol-to-Glyceric Acid Oxidation. ACS Catalysis 2020, 10 (6) , 3832-3837. https://doi.org/10.1021/acscatal.9b05559
  91. Hua-Min Zhang, Qi-Yuan Fan, Qing-Hong Zhang, Jin-Can Kang, Ye Wang, Jun Cheng. Understanding Catalytic Mechanisms of Alkane Oxychlorination from the Perspective of Energy Levels. The Journal of Physical Chemistry C 2020, 124 (11) , 6070-6077. https://doi.org/10.1021/acs.jpcc.9b10464
  92. Muhammad A. Naeem, Paula M. Abdala, Andac Armutlulu, Sung Min Kim, Alexey Fedorov, Christoph R. Müller. Exsolution of Metallic Ru Nanoparticles from Defective, Fluorite-Type Solid Solutions Sm2RuxCe2–xO7 To Impart Stability on Dry Reforming Catalysts. ACS Catalysis 2020, 10 (3) , 1923-1937. https://doi.org/10.1021/acscatal.9b04555
  93. Sen Wang, Pengfei Wang, Dezhi Shi, Shipei He, Li Zhang, Wenjun Yan, Zhangfeng Qin, Junfen Li, Mei Dong, Jianguo Wang, Unni Olsbye, Weibin Fan. Direct Conversion of Syngas into Light Olefins with Low CO2 Emission. ACS Catalysis 2020, 10 (3) , 2046-2059. https://doi.org/10.1021/acscatal.9b04629
  94. Alexander J. Hill, Chang Yup Seo, Xiaoyin Chen, Adarsh Bhat, Galen B. Fisher, Andrej Lenert, Johannes W. Schwank. Thermally Induced Restructuring of [email protected] and [email protected] Nanoparticles as a Strategy for Enhancing Low-Temperature Catalytic Activity. ACS Catalysis 2020, 10 (3) , 1731-1741. https://doi.org/10.1021/acscatal.9b05224
  95. Yawen Wang, Tongtong Liu, Juewen Liu. Synergistically Boosted Degradation of Organic Dyes by CeO2 Nanoparticles with Fluoride at Low pH. ACS Applied Nano Materials 2020, 3 (1) , 842-849. https://doi.org/10.1021/acsanm.9b02356
  96. Liu Pi, Rui Jiang, Wanxin Cai, Lei Wang, Yangyang Wang, Jianhua Cai, Xuhui Mao. Bionic Preparation of CeO2-Encapsulated Nitrogen Self-Doped Biochars for Highly Efficient Oxygen Reduction. ACS Applied Materials & Interfaces 2020, 12 (3) , 3642-3653. https://doi.org/10.1021/acsami.9b19614
  97. G. S. Otero, P. G. Lustemberg, F. Prado, M. V. Ganduglia-Pirovano. Relative Stability of Near-Surface Oxygen Vacancies at the CeO2(111) Surface upon Zirconium Doping. The Journal of Physical Chemistry C 2020, 124 (1) , 625-638. https://doi.org/10.1021/acs.jpcc.9b09433
  98. Devin B. O’Neill, Daniel Prezgot, Anatoli Ianoul, Cees Otto, Guido Mul, Annemarie Huijser. Silver Nanocubes Coated in Ceria: Core/Shell Size Effects on Light-Induced Charge Transfer. ACS Applied Materials & Interfaces 2020, 12 (1) , 1905-1912. https://doi.org/10.1021/acsami.9b18393
  99. Kuan Chang, Haochen Zhang, Mu-jeng Cheng, Qi Lu. Application of Ceria in CO2 Conversion Catalysis. ACS Catalysis 2020, 10 (1) , 613-631. https://doi.org/10.1021/acscatal.9b03935
  100. Vinod K. Paidi, Kimber L. Stamm Masias, Michael Shepit, Ryan D. Desautels, Charles A. Roberts, Johan van Lierop. Synergy between Fe and Promoter Ions Supported on Nanoceria Influences NOx Reduction Catalysis. ACS Applied Nano Materials 2019, 2 (12) , 7593-7603. https://doi.org/10.1021/acsanm.9b01691
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