Activation of Persulfates by Graphitized Nanodiamonds for Removal of Organic Compounds

View Author Information
Chemical and Environmental Engineering, Yale University, New Haven, Connecticut 06511, United States
School of Environmental Science and Engineering, Pohang University of Science and Technology (POSTECH), San 31, Hyoja-dong, Pohang 790-784, Republic of Korea
§ Future Environmental Research Center, Korea Institute of Toxicology (KIT), Jinju, 660-844, Republic of Korea
Human and Environmental Toxicology Program, University of Science and Technology (UST), Daejeon, 305-350, Republic of Korea
School of Urban and Environmental Engineering, Ulsan National Institute of Science and Technology (UNIST), 50 UNIST-gil, Ulju-gun, Ulsan 689-798, Republic of Korea
*(C.L.) Phone: +82-52-217-2812; fax: +82-52-217-2809; e-mail: [email protected]
*(J.-H.K.) Phone: +1-203-432-4386; fax: +1-203-432-4387; e-mail: [email protected]
Cite this: Environ. Sci. Technol. 2016, 50, 18, 10134–10142
Publication Date (Web):September 2, 2016
https://doi.org/10.1021/acs.est.6b02079
Copyright © 2016 American Chemical Society
Article Views
6647
Altmetric
-
Citations
LEARN ABOUT THESE METRICS
Read OnlinePDF (4 MB)
Supporting Info (1)»

Abstract

This study introduces graphited nanodiamond (G-ND) as an environmentally friendly, easy-to-regenerate, and cost-effective alternative catalyst to activate persulfate (i.e., peroxymonosulfate (PMS) and peroxydisulfate (PDS)) and oxidize organic compounds in water. The G-ND was found to be superior for persulfate activation to other benchmark carbon materials such as graphite, graphene, fullerene, and carbon nanotubes. The G-ND/persulfate showed selective reactivity toward phenolic compounds and some pharmaceuticals, and the degradation kinetics were not inhibited by the presence of oxidant scavengers and natural organic matter. These results indicate that radical intermediates such as sulfate radical anion and hydroxyl radical are not majorly responsible for this persulfate-driven oxidation of organic compounds. The findings from linear sweep voltammetry, thermogravimetric analysis, Fourier transform infrared spectroscopy, and electron paramagnetic resonance spectroscopy analyses suggest that the both persulfate and phenol effectively bind to G-ND surface and are likely to form charge transfer complex, in which G-ND plays a critical role in mediating facile electron transfer from phenol to persulfate.

Supporting Information

ARTICLE SECTIONS
Jump To

The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.est.6b02079.

  • Detailed experimental setup and procedure information on GC/MS system for phenol oxidation products analysis (Text S1), water quality parameters of field water samples (Table S1), phenol removal by G-NDs/PDS system with and without phosphate buffer solution (Figure S1), phenol removal by G-NDs/PDS system with and without dissolved oxygen (Figure S2), photographs and XPS spectra of G-NDs prepared at different annealing temperatures (Figure S3), HR-TEM images of G-ND (Figure S4), particles size distribution and average particles size for aqueous suspension of G-ND measured by dynamic light scattering (Figure S5), phenol oxidation by surface modification nanodiamonds without persulfate systems (Figure S6), phenol removal and pseudo first order rate constant for the removal of phenol by G-NDs/PDS system as a function of G-NDs loading and phenol concentrations (Figure S7), decomposition of phenol and oxyanions by G-NDs in the presence of oxyanions (Figure S8), BET specific surface area of carbon-materials (Figure S9), FT-IR spectrum of G-NDs/PDS system with and without UV treatment (Figure S10), EPR spectra obtained by spin trapping with DMPO in the Fe(II)/H2O2 and G-NDs/PDS system at acidic pH and neutral pH (Figure S11), the GC/MS spectrum of intermediates for the removal of phenol by G-NDs/PDS system (Figure S12), removal and recovery of phenol by G-NDs with and without persulfate systems (Figure S13), phenol removal by G-NDs/PDS system with different type of tap water (Figure S14) (PDF)

Terms & Conditions

Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

Cited By


This article is cited by 313 publications.

  1. Penghui Shao, Yunpeng Jing, Xiaoguang Duan, Huiyun Lin, Liming Yang, Wei Ren, Fang Deng, Buhong Li, Xubiao Luo, Shaobin Wang. Revisiting the Graphitized Nanodiamond-Mediated Activation of Peroxymonosulfate: Singlet Oxygenation versus Electron Transfer. Environmental Science & Technology 2021, 55 (23) , 16078-16087. https://doi.org/10.1021/acs.est.1c02042
  2. Cong Wang, Shao-Yi Jia, You Han, Yang Li, Yong Liu, Hai-Tao Ren, Song-Hai Wu, Xu Han. Selective Oxidation of Various Phenolic Contaminants by Activated Persulfate via the Hydrogen Abstraction Pathway. ACS ES&T Engineering 2021, 1 (9) , 1275-1286. https://doi.org/10.1021/acsestengg.1c00091
  3. Weixue Wang, Yang Liu, Yifan Yue, Huihui Wang, Gong Cheng, Chunyang Gao, Chunlin Chen, Yuejie Ai, Zhe Chen, Xiangke Wang. The Confined Interlayer Growth of Ultrathin Two-Dimensional Fe3O4 Nanosheets with Enriched Oxygen Vacancies for Peroxymonosulfate Activation. ACS Catalysis 2021, 11 (17) , 11256-11265. https://doi.org/10.1021/acscatal.1c03331
  4. Yongsong Ma, Yuxing Gu, Da Jiang, Xuhui Mao, Dihua Wang. Transforming CO2 into Sulfur-Doped Carbon As a High-Efficiency Persulfate Catalyst for the Degradation of 2,4-Dichlorphenol: Influential Factors, Activation Mechanism, and Regeneration of Catalyst. ACS ES&T Water 2021, 1 (8) , 1796-1806. https://doi.org/10.1021/acsestwater.1c00112
  5. Yufei Zhen, Shishu Zhu, Zhiqiang Sun, Yu Tian, Zeng Li, Chen Yang, Jun Ma. Identifying the Persistent Free Radicals (PFRs) Formed as Crucial Metastable Intermediates during Peroxymonosulfate (PMS) Activation by N-Doped Carbonaceous Materials. Environmental Science & Technology 2021, 55 (13) , 9293-9304. https://doi.org/10.1021/acs.est.1c01974
  6. Yinghao Wen, Mingbao Feng, Peng Zhang, Hong-Chai Zhou, Virender K. Sharma, Xingmao Ma. Metal Organic Frameworks (MOFs) as Photocatalysts for the Degradation of Agricultural Pollutants in Water. ACS ES&T Engineering 2021, 1 (5) , 804-826. https://doi.org/10.1021/acsestengg.1c00051
  7. Mingyue Liu, Zhiyuan Feng, Xinmiao Luan, Wenhai Chu, Hongying Zhao, Guohua Zhao. Accelerated Fe2+ Regeneration in an Effective Electro-Fenton Process by Boosting Internal Electron Transfer to a Nitrogen-Conjugated Fe(III) Complex. Environmental Science & Technology 2021, 55 (9) , 6042-6051. https://doi.org/10.1021/acs.est.0c08018
  8. Junhui Wang, Jiaxing Yu, Qi Fu, Huangsheng Yang, Qing Tong, Zhengping Hao, Gangfeng Ouyang. Unprecedented Nonphotomediated Hole (h+) Oxidation System Constructed from Defective Carbon Nanotubes and Superoxides. ACS Central Science 2021, 7 (2) , 355-364. https://doi.org/10.1021/acscentsci.0c01600
  9. Ming Zhang, Chengming Xiao, Chi Zhang, Junwen Qi, Chaohai Wang, Xiuyun Sun, Lianjun Wang, Qiang Xu, Jiansheng Li. Large-Scale Synthesis of [email protected] Porous Carbon/Cobalt Nanofiber for Environmental Remediation by Advanced Oxidation Processes. ACS ES&T Engineering 2021, 1 (2) , 249-260. https://doi.org/10.1021/acsestengg.0c00090
  10. Hui Song, Xianguang Meng, Shengyao Wang, Wei Zhou, Shuang Song, Tetsuya Kako, Jinhua Ye. Selective Photo-oxidation of Methane to Methanol with Oxygen over Dual-Cocatalyst-Modified Titanium Dioxide. ACS Catalysis 2020, 10 (23) , 14318-14326. https://doi.org/10.1021/acscatal.0c04329
  11. Penghui Shao, Shuiping Yu, Xiaoguang Duan, Liming Yang, Hui Shi, Lin Ding, Jiayu Tian, Lixia Yang, Xubiao Luo, Shaobin Wang. Potential Difference Driving Electron Transfer via Defective Carbon Nanotubes toward Selective Oxidation of Organic Micropollutants. Environmental Science & Technology 2020, 54 (13) , 8464-8472. https://doi.org/10.1021/acs.est.0c02645
  12. Jie Miao, Wei Geng, Pedro J. J. Alvarez, Mingce Long. 2D N-Doped Porous Carbon Derived from Polydopamine-Coated Graphitic Carbon Nitride for Efficient Nonradical Activation of Peroxymonosulfate. Environmental Science & Technology 2020, 54 (13) , 8473-8481. https://doi.org/10.1021/acs.est.0c03207
  13. Sergio Navalón, Amarajothi Dhakshinamoorthy, Mercedes Álvaro, Hermenegildo García. Diamond Nanoparticles in Heterogeneous Catalysis. Chemistry of Materials 2020, 32 (10) , 4116-4143. https://doi.org/10.1021/acs.chemmater.0c00204
  14. Wei Ren, Gang Nie, Peng Zhou, Hui Zhang, Xiaoguang Duan, Shaobin Wang. The Intrinsic Nature of Persulfate Activation and N-Doping in Carbocatalysis. Environmental Science & Technology 2020, 54 (10) , 6438-6447. https://doi.org/10.1021/acs.est.0c01161
  15. Ming Zhu, Jie Miao, Daqin Guan, Yijun Zhong, Ran Ran, Shaobin Wang, Wei Zhou, Zongping Shao. Efficient Wastewater Remediation Enabled by Self-Assembled Perovskite Oxide Heterostructures with Multiple Reaction Pathways. ACS Sustainable Chemistry & Engineering 2020, 8 (15) , 6033-6042. https://doi.org/10.1021/acssuschemeng.0c00882
  16. Jaesang Lee, Urs von Gunten, Jae-Hong Kim. Persulfate-Based Advanced Oxidation: Critical Assessment of Opportunities and Roadblocks. Environmental Science & Technology 2020, 54 (6) , 3064-3081. https://doi.org/10.1021/acs.est.9b07082
  17. Ali Jawad, Kun Zhan, Haibin Wang, Ajmal Shahzad, Zehua Zeng, Jia Wang, Xinquan Zhou, Habib Ullah, Zhulei Chen, Zhuqi Chen. Tuning of Persulfate Activation from a Free Radical to a Nonradical Pathway through the Incorporation of Non-Redox Magnesium Oxide. Environmental Science & Technology 2020, 54 (4) , 2476-2488. https://doi.org/10.1021/acs.est.9b04696
  18. Hongyu Dong, Guangfeng Wei, Tongcheng Cao, Binbin Shao, Xiaohong Guan, Timothy J. Strathmann. Insights into the Oxidation of Organic Cocontaminants during Cr(VI) Reduction by Sulfite: The Overlooked Significance of Cr(V). Environmental Science & Technology 2020, 54 (2) , 1157-1166. https://doi.org/10.1021/acs.est.9b03356
  19. Wei Ren, Liangliang Xiong, Gang Nie, Hui Zhang, Xiaoguang Duan, Shaobin Wang. Insights into the Electron-Transfer Regime of Peroxydisulfate Activation on Carbon Nanotubes: The Role of Oxygen Functional Groups. Environmental Science & Technology 2020, 54 (2) , 1267-1275. https://doi.org/10.1021/acs.est.9b06208
  20. Wei Ren, Liangliang Xiong, Xuehong Yuan, Ziwei Yu, Hui Zhang, Xiaoguang Duan, Shaobin Wang. Activation of Peroxydisulfate on Carbon Nanotubes: Electron-Transfer Mechanism. Environmental Science & Technology 2019, 53 (24) , 14595-14603. https://doi.org/10.1021/acs.est.9b05475
  21. Liangyu Wang, Jie Di, Jun Nie, Guiping Ma. Multicomponent Doped Sugar-Coated Nanofibers for Peroxymonosulfate Activation. ACS Applied Nano Materials 2019, 2 (11) , 6998-7007. https://doi.org/10.1021/acsanm.9b01505
  22. Kuan Z. Huang, Huichun Zhang. Direct Electron-Transfer-Based Peroxymonosulfate Activation by Iron-Doped Manganese Oxide (δ-MnO2) and the Development of Galvanic Oxidation Processes (GOPs). Environmental Science & Technology 2019, 53 (21) , 12610-12620. https://doi.org/10.1021/acs.est.9b03648
  23. Zijian Wang, Peizhe Sun, Yaxiu Li, Tan Meng, Zhipeng Li, Xu Zhang, Ruochun Zhang, Hanzhong Jia, Hong Yao. Reactive Nitrogen Species Mediated Degradation of Estrogenic Disrupting Chemicals by Biochar/Monochloramine in Buffered Water and Synthetic Hydrolyzed Urine. Environmental Science & Technology 2019, 53 (21) , 12688-12696. https://doi.org/10.1021/acs.est.9b04704
  24. Chiheng Chu, Ji Yang, Dahong Huang, Jianfeng Li, Aiqin Wang, Pedro J. J. Alvarez, Jae-Hong Kim. Cooperative Pollutant Adsorption and Persulfate-Driven Oxidation on Hierarchically Ordered Porous Carbon. Environmental Science & Technology 2019, 53 (17) , 10352-10360. https://doi.org/10.1021/acs.est.9b03067
  25. Bojing Sun, Wenjie Ma, Na Wang, Ping Xu, Leijiang Zhang, Bianna Wang, Honghong Zhao, Kun-Yi Andrew Lin, Yunchen Du. Polyaniline: A New Metal-Free Catalyst for Peroxymonosulfate Activation with Highly Efficient and Durable Removal of Organic Pollutants. Environmental Science & Technology 2019, 53 (16) , 9771-9780. https://doi.org/10.1021/acs.est.9b03374
  26. Chaoting Guan, Jin Jiang, Yongming Shen, Suyan Pang, Congwei Luo, Xi Zhao. Carbon Materials Inhibit Formation of Nitrated Aromatic Products in Treatment of Phenolic Compounds by Thermal Activation of Peroxydisulfate in the Presence of Nitrite. Environmental Science & Technology 2019, 53 (15) , 9054-9062. https://doi.org/10.1021/acs.est.9b01354
  27. Xiaoguang Duan, Wenjie Tian, Huayang Zhang, Hongqi Sun, Zhimin Ao, Zongping Shao, Shaobin Wang. sp2/sp3 Framework from Diamond Nanocrystals: A Key Bridge of Carbonaceous Structure to Carbocatalysis. ACS Catalysis 2019, 9 (8) , 7494-7519. https://doi.org/10.1021/acscatal.9b01565
  28. Jonghun Lim, Yang Yang, Michael R. Hoffmann. Activation of Peroxymonosulfate by Oxygen Vacancies-Enriched Cobalt-Doped Black TiO2 Nanotubes for the Removal of Organic Pollutants. Environmental Science & Technology 2019, 53 (12) , 6972-6980. https://doi.org/10.1021/acs.est.9b01449
  29. Yanming Liu, Xinfei Fan, Xie Quan, Yaofang Fan, Shuo Chen, Xueyang Zhao. Enhanced Perfluorooctanoic Acid Degradation by Electrochemical Activation of Sulfate Solution on B/N Codoped Diamond. Environmental Science & Technology 2019, 53 (9) , 5195-5201. https://doi.org/10.1021/acs.est.8b06130
  30. Wenjie Ma, Na Wang, Yunchen Du, Ping Xu, Bojing Sun, Leijiang Zhang, Kun-Yi Andrew Lin. Human-Hair-Derived N, S-Doped Porous Carbon: An Enrichment and Degradation System for Wastewater Remediation in the Presence of Peroxymonosulfate. ACS Sustainable Chemistry & Engineering 2019, 7 (2) , 2718-2727. https://doi.org/10.1021/acssuschemeng.8b05801
  31. Guodong Fang, Xiru Chen, Wenhui Wu, Cun Liu, Dionysios D. Dionysiou, Tingting Fan, Yujun Wang, Changyin Zhu, Dongmei Zhou. Mechanisms of Interaction between Persulfate and Soil Constituents: Activation, Free Radical Formation, Conversion, and Identification. Environmental Science & Technology 2018, 52 (24) , 14352-14361. https://doi.org/10.1021/acs.est.8b04766
  32. Yaowen Gao, Yue Zhu, Lai Lyu, Qingyi Zeng, Xueci Xing, Chun Hu. Electronic Structure Modulation of Graphitic Carbon Nitride by Oxygen Doping for Enhanced Catalytic Degradation of Organic Pollutants through Peroxymonosulfate Activation. Environmental Science & Technology 2018, 52 (24) , 14371-14380. https://doi.org/10.1021/acs.est.8b05246
  33. Shishu Zhu, Xiaochen Huang, Fang Ma, Li Wang, Xiaoguang Duan, Shaobin Wang. Catalytic Removal of Aqueous Contaminants on N-Doped Graphitic Biochars: Inherent Roles of Adsorption and Nonradical Mechanisms. Environmental Science & Technology 2018, 52 (15) , 8649-8658. https://doi.org/10.1021/acs.est.8b01817
  34. Shichao Tian, Congzhe Dang, Ran Mao, Xu Zhao. Enhancement of Photoelectrocatalytic Oxidation of Cu–Cyanide Complexes and Cathodic Recovery of Cu in a Metal-Free System. ACS Sustainable Chemistry & Engineering 2018, 6 (8) , 10273-10281. https://doi.org/10.1021/acssuschemeng.8b01634
  35. Eun-Tae Yun, Jeong Hoon Lee, Jaesung Kim, Hee-Deung Park, Jaesang Lee. Identifying the Nonradical Mechanism in the Peroxymonosulfate Activation Process: Singlet Oxygenation Versus Mediated Electron Transfer. Environmental Science & Technology 2018, 52 (12) , 7032-7042. https://doi.org/10.1021/acs.est.8b00959
  36. Xiaoguang Duan, Hongqi Sun, Shaobin Wang. Metal-Free Carbocatalysis in Advanced Oxidation Reactions. Accounts of Chemical Research 2018, 51 (3) , 678-687. https://doi.org/10.1021/acs.accounts.7b00535
  37. Jiabin Chen, Cong Fang, Wenjun Xia, Tianyin Huang, and Ching-Hua Huang . Selective Transformation of β-Lactam Antibiotics by Peroxymonosulfate: Reaction Kinetics and Nonradical Mechanism. Environmental Science & Technology 2018, 52 (3) , 1461-1470. https://doi.org/10.1021/acs.est.7b05543
  38. Peidong Hu, Hanrui Su, Zhenyu Chen, Chunyang Yu, Qilin Li, Baoxue Zhou, Pedro J. J. Alvarez, and Mingce Long . Selective Degradation of Organic Pollutants Using an Efficient Metal-Free Catalyst Derived from Carbonized Polypyrrole via Peroxymonosulfate Activation. Environmental Science & Technology 2017, 51 (19) , 11288-11296. https://doi.org/10.1021/acs.est.7b03014
  39. Chaoting Guan, Jin Jiang, Suyan Pang, Congwei Luo, Jun Ma, Yang Zhou, and Yi Yang . Oxidation Kinetics of Bromophenols by Nonradical Activation of Peroxydisulfate in the Presence of Carbon Nanotube and Formation of Brominated Polymeric Products. Environmental Science & Technology 2017, 51 (18) , 10718-10728. https://doi.org/10.1021/acs.est.7b02271
  40. Eun-Tae Yun, Ha-Young Yoo, Hyokwan Bae, Hyoung-Il Kim, and Jaesang Lee . Exploring the Role of Persulfate in the Activation Process: Radical Precursor Versus Electron Acceptor. Environmental Science & Technology 2017, 51 (17) , 10090-10099. https://doi.org/10.1021/acs.est.7b02519
  41. Xiaoguang Duan, Hongqi Sun, and Shaobin Wang . Comment on “Activation of Persulfate by Graphitized Nanodiamonds for Removal of Organic Compounds”. Environmental Science & Technology 2017, 51 (9) , 5351-5352. https://doi.org/10.1021/acs.est.7b00399
  42. Hongshin Lee, Changha Lee, and Jae-Hong Kim . Response to Comment on “Activation of Persulfate by Graphitized Nanodiamonds for Removal of Organic Compounds”. Environmental Science & Technology 2017, 51 (9) , 5353-5354. https://doi.org/10.1021/acs.est.7b01642
  43. Chaoting Guan, Jin Jiang, Congwei Luo, Suyan Pang, Chengchun Jiang, Jun Ma, Yixin Jin, and Juan Li . Transformation of Iodide by Carbon Nanotube Activated Peroxydisulfate and Formation of Iodoorganic Compounds in the Presence of Natural Organic Matter. Environmental Science & Technology 2017, 51 (1) , 479-487. https://doi.org/10.1021/acs.est.6b04158
  44. Liping He, Jianhao Tong, Yuanqiang Yang, Jianxun Wu, Linqian Li, Zhonghua Wei, Wei Long, Jingli Pang, Jiyan Shi. Overestimate of remediation efficiency due to residual sodium persulfate in PAHs contaminated soil and a solution. Journal of Environmental Sciences 2022, 113 , 242-250. https://doi.org/10.1016/j.jes.2021.06.004
  45. Kleopatra Miserli, Dimitra Kogola, Irini Paraschoudi, Ioannis Konstantinou. Activation of persulfate by biochar for the degradation of phenolic compounds in aqueous systems. Chemical Engineering Journal Advances 2022, 9 , 100201. https://doi.org/10.1016/j.ceja.2021.100201
  46. Yang Li, Ruoyun Lin, Fangjie Lv, Xiaoyu Zhao, Tianzhi Yong, Xiaojun Zuo. Tannic acid-Fe complex derivative-modified electrode with pH regulating function for environmental remediation by electro-Fenton process. Environmental Research 2022, 204 , 111994. https://doi.org/10.1016/j.envres.2021.111994
  47. Mengfei He, Peng Zhao, Ran Duan, Shengjun Xu, Gong Cheng, Mengjia Li, Shuanglong Ma. Insights on the electron transfer pathway of phenolic pollutant degradation by endogenous N-doped carbonaceous materials and peroxymonosulfate system. Journal of Hazardous Materials 2022, 424 , 127568. https://doi.org/10.1016/j.jhazmat.2021.127568
  48. Sijin Zuo, Shengcai Zhu, Jiaying Wang, Weiping Liu, Juan Wang. Boosting Fenton-like reaction efficiency by co-construction of the adsorption and reactive sites on N/O co-doped carbon. Applied Catalysis B: Environmental 2022, 301 , 120783. https://doi.org/10.1016/j.apcatb.2021.120783
  49. Yu-Dan Dong, Liang-Qing Zhang, Peng Zhou, Yang Liu, Hao Lin, Gan-Ji Zhong, Gang Yao, Zhong-Ming Li, Bo Lai. Natural cellulose supported carbon nanotubes and Fe3O4 NPs as the efficient peroxydisulfate activator for the removal of bisphenol A: An enhanced non-radical oxidation process. Journal of Hazardous Materials 2022, 423 , 127054. https://doi.org/10.1016/j.jhazmat.2021.127054
  50. Zilong Zhao, Xing Wang, Guocheng Zhu, Feng Wang, Yu Zhou, Wenyi Dong, Hongjie Wang, Feiyun Sun, Haijiao Xie. Enhanced removal of Cu-EDTA in a three-dimensional electrolysis system with highly graphitic activated biochar produced via acidic and K2FeO4 treatment. Chemical Engineering Journal 2022, 430 , 132661. https://doi.org/10.1016/j.cej.2021.132661
  51. Wen Huang, Yaxin Tang, Xueping Zhang, Ze Luo, Jianqiang Zhang. nZVI-biochar derived from Fe3O4-loaded rabbit manure for activation of peroxymonosulfate to degrade sulfamethoxazole. Journal of Water Process Engineering 2022, 45 , 102470. https://doi.org/10.1016/j.jwpe.2021.102470
  52. Mamta Rani, Arunima Bhattacharjee, Pragati Singh, Sanchayita Basu, Kunwali Das, Khyati Goswami, Saurabh Pandey, Deeksha Tripathi, Ashutosh Kumar. Antimicrobial activities of different nanoparticles concerning to wastewater treatment. 2022,,, 501-514. https://doi.org/10.1016/B978-0-323-85583-9.00029-6
  53. Teng-fei Hu, Si Chen, Qian Zhang, Jun-ming Hong. Efficiency and mechanism analysis of bisphenol A degradation by sulfur-doped graphene-catalyzed peroxydisulfate. Applied Surface Science 2022, 572 , 151429. https://doi.org/10.1016/j.apsusc.2021.151429
  54. Chang-Mao Hung, Chiu-Wen Chen, Chin-Pao Huang, Su Shiung Lam, Cheng-Di Dong. Peroxymonosulfate activation by a metal-free biochar for sulfonamide antibiotic removal in water and associated bacterial community composition. Bioresource Technology 2022, 343 , 126082. https://doi.org/10.1016/j.biortech.2021.126082
  55. Jianan Yu, Zhiliang Zhu, Hua Zhang, Yanling Qiu, Daqiang Yin. Fe–nitrogen–doped carbon with dual active sites for efficient degradation of aromatic pollutants via peroxymonosulfate activation. Chemical Engineering Journal 2022, 427 , 130898. https://doi.org/10.1016/j.cej.2021.130898
  56. Ruihao Tang, Wei Hong, C. Srinivasakannan, Xuelin Liu, Xin Wang, Xinhui Duan. A novel mesoporous Fe-silica aerogel composite with phenomenal adsorption capacity for malachite green. Separation and Purification Technology 2022, 281 , 119950. https://doi.org/10.1016/j.seppur.2021.119950
  57. Jia Wang, Jiayi Cai, Siqi Wang, Xinquan Zhou, Xintao Ding, Jawad Ali, Li Zheng, Songlin Wang, Lie Yang, Shuang Xi, Mingju Wang, Zhuqi Chen. Biochar-based activation of peroxide: multivariate-controlled performance, modulatory surface reactive sites and tunable oxidative species. Chemical Engineering Journal 2022, 428 , 131233. https://doi.org/10.1016/j.cej.2021.131233
  58. Zhuofan Huang, Qintie Lin, Nan Cai, Qingsong Weng, Jingwei Xu, Shuchai Gan, Chao Chen, Quanfa Zhong, Hengyi Fu, Yuejie Xia, Pengran Guo. Coexistence of free radical and nonradical mechanisms for triclosan degradation by CuO/HNTs. Separation and Purification Technology 2021, 276 , 119318. https://doi.org/10.1016/j.seppur.2021.119318
  59. Liang Liang, Xiuyan Yue, Yihan Wang, Yuhan Wu, Shuying Dong, Jinglan Feng, Yuwei Pan, Jianhui Sun. Sucrose-derived N-doped carbon xerogels as efficient peroxydisulfate activators for non-radical degradation of organic pollutants. Journal of Colloid and Interface Science 2021, 604 , 660-669. https://doi.org/10.1016/j.jcis.2021.07.019
  60. Pijun Duan, Xinning Liu, Binhua Liu, Muhammad Akram, Yanwei Li, Jingwen Pan, Qinyan Yue, Baoyu Gao, Xing Xu. Effect of phosphate on peroxymonosulfate activation: Accelerating generation of sulfate radical and underlying mechanism. Applied Catalysis B: Environmental 2021, 298 , 120532. https://doi.org/10.1016/j.apcatb.2021.120532
  61. Si Chen, Teng-fei Hu, Qian Zhang, Jun-ming Hong. UV–annealing synthesis of sulfur-doped graphene for bisphenol A electrocatalytic degradation. Applied Surface Science 2021, 569 , 151042. https://doi.org/10.1016/j.apsusc.2021.151042
  62. Xiaona Dong, Xiaoxue Yang, Sheng Hua, Ziqian Wang, Tianming Cai, Canlan Jiang. Unraveling the mechanisms for persulfate-based remediation of triphenyl phosphate-contaminated soils: Complicated soil constituent effects on the formation and propagation of reactive oxygen species. Chemical Engineering Journal 2021, 426 , 130662. https://doi.org/10.1016/j.cej.2021.130662
  63. Hyeonseok Kang, Donghyun Lee, Ki-Myeong Lee, Hak-Hyeon Kim, Hongshin Lee, Min Sik Kim, Changha Lee. Nonradical activation of peroxymonosulfate by hematite for oxidation of organic compounds: A novel mechanism involving high-valent iron species. Chemical Engineering Journal 2021, 426 , 130743. https://doi.org/10.1016/j.cej.2021.130743
  64. Jawad Ali, Wang Jiang, Ajmal Shahzad, Jerosha Ifthikar, Xiuru Yang, Beibei Wu, Daniel T. Oyekunle, Wang Jia, Zhulei Chen, Li Zheng, Zhuqi Chen. Isolated copper ions and surface hydroxyl groups as a function of non-redox metals to modulate the reactivity and persulfate activation mechanism of spinel oxides. Chemical Engineering Journal 2021, 425 , 130679. https://doi.org/10.1016/j.cej.2021.130679
  65. Chen Sun, Tong Chen, Qunxing Huang, Xiaoguang Duan, Mingxiu Zhan, Longjie Ji, Xiaodong Li, Jianhua Yan. Selective production of singlet oxygen from zinc-etching hierarchically porous biochar for sulfamethoxazole degradation. Environmental Pollution 2021, 290 , 117991. https://doi.org/10.1016/j.envpol.2021.117991
  66. Conghao Yi, Zuyun He, Yizhang Hu, Dengmin Liang, Yongqing Zhang, Yan Chen. [email protected] as a highly effective and stable activator of peroxymonosulfate-based advanced oxidation processes for pollutant degradation. Surfaces and Interfaces 2021, 27 , 101465. https://doi.org/10.1016/j.surfin.2021.101465
  67. Hongbo Liu, Mengting Ye, Xinyi Dong, Zhenxing Ren, Shiping Long, Eric Lichtfouse. Removal of humic substances by the synergistic effect of biochar adsorption and activation of persulfate. Journal of Water Process Engineering 2021, 44 , 102428. https://doi.org/10.1016/j.jwpe.2021.102428
  68. Mengdi Tang, Yonggang Zhang. Enhancing the activation of persulfate using nitrogen-doped carbon materials in the electric field for the effective removal of p -nitrophenol. RSC Advances 2021, 11 (60) , 38003-38015. https://doi.org/10.1039/D1RA06691A
  69. Shujing Ye, Weiping Xiong, Jie Liang, Hailan Yang, Haipeng Wu, Chengyun Zhou, Li Du, Jiayin Guo, Wenjun Wang, Ling Xiang, Guangming Zeng, Xiaofei Tan. Refined regulation and nitrogen doping of biochar derived from ramie fiber by deep eutectic solvents (DESs) for catalytic persulfate activation toward non-radical organics degradation and disinfection. Journal of Colloid and Interface Science 2021, 601 , 544-555. https://doi.org/10.1016/j.jcis.2021.05.080
  70. Zhi-Ling Li, Di Cao, Hao Cheng, Fan Chen, Jun Nan, Bin Liang, Kai Sun, Cong Huang, Ai-Jie Wang. Ordered mesoporous carbon as an efficient heterogeneous catalyst to activate peroxydisulfate for degradation of sulfadiazine. Chinese Chemical Letters 2021, 184 https://doi.org/10.1016/j.cclet.2021.10.086
  71. Zhanmeng Liu, Zhimin Gao, Qin Wu. Activation of persulfate by magnetic zirconium-doped manganese ferrite for efficient degradation of tetracycline. Chemical Engineering Journal 2021, 423 , 130283. https://doi.org/10.1016/j.cej.2021.130283
  72. Meng Li, Zilong Li, Xiaolong Yu, Yinlong Wu, Cehui Mo, Mi Luo, Ligui Li, Shaoqi Zhou, Qiming Liu, Nan Wang, King Lun Yeung, Shaowei Chen. FeN4-doped carbon nanotubes derived from metal organic frameworks for effective degradation of organic dyes by peroxymonosulfate: Impacts of FeN4 spin states. Chemical Engineering Journal 2021, 51 , 133339. https://doi.org/10.1016/j.cej.2021.133339
  73. Peixun Zhai, Haibo Liu, Fuwei Sun, Tianhu Chen, Xuehua Zou, Hanlin Wang, Ziyang Chu, Can Wang, Meng Liu, Dong Chen. Carbonization of methylene blue adsorbed on palygorskite for activating peroxydisulfate to degrade bisphenol A: An electron transfer mechanism. Applied Clay Science 2021, 172 , 106327. https://doi.org/10.1016/j.clay.2021.106327
  74. Jun Wang, Bin Li, Yang Li, Xiaobin Fan, Fengbao Zhang, Guoliang Zhang, Wenchao Peng. Facile Synthesis of Atomic Fe‐N‐C Materials and Dual Roles Investigation of Fe‐N 4 Sites in Fenton‐Like Reactions. Advanced Science 2021, 8 (22) , 2101824. https://doi.org/10.1002/advs.202101824
  75. Lin-Qian Yu, Yi-Heng Zhao, Hao Wang, Feng Jin, Shu-La Chen, Te-Er Wen, Chuan-Shu He, Bao-Cheng Huang, Ren-Cun Jin. Surface oxygen vacancies formation on Zn2SnO4 for bisphenol-A degradation under visible light: The tuning effect by peroxymonosulfate. Journal of Hazardous Materials 2021, 11 , 127828. https://doi.org/10.1016/j.jhazmat.2021.127828
  76. Lin Ge, Binbin Shao, Qinghua Liang, Danlian Huang, Zhifeng Liu, Qingyun He, Ting Wu, Songhao Luo, Yuan Pan, Chenhui Zhao, Jinhui Huang, Yumeng Hu. Layered double hydroxide based materials applied in persulfate based advanced oxidation processes: property, mechanism, application and perspectives. Journal of Hazardous Materials 2021, 47 , 127612. https://doi.org/10.1016/j.jhazmat.2021.127612
  77. Zhilin Zhang, Heng Ding, Yan Li, Jian Yu, Lei Ding, Yanli Kong, Jiangya Ma. Nitrogen-doped biochar encapsulated Fe/Mn nanoparticles as cost-effective catalysts for heterogeneous activation of peroxymonosulfate towards the degradation of bisphenol-A: Mechanism insight and performance assessment. Separation and Purification Technology 2021, 75 , 120136. https://doi.org/10.1016/j.seppur.2021.120136
  78. Xiang Liu, Wenxin Hou, Yu Huang, Haiyu Zhao, Zan Song, Yingping Huang. Facile and green synthesis of carbon nanopinnacles for the removal of chlortetracycline: Performance, mechanism and biotoxicity. Chemical Engineering Journal 2021, 50 , 133822. https://doi.org/10.1016/j.cej.2021.133822
  79. Yue Zhao, Xiaohui Zhan, He Wang, Jie Yu, Yanping Sun, Lei Chen, Mingyue He, Junyan Liu, Huixiang Shi. MOFs-derived [email protected] nanosheets for peroxymonosulfate activation: Synergistic effect and mechanism. Chemical Engineering Journal 2021, 374 , 133806. https://doi.org/10.1016/j.cej.2021.133806
  80. Ai-Yong Zhang, Shuo Xu, Jing-Wei Feng, Pin-Cheng Zhao, Heng Liang. Superior degradation of phenolic contaminants in different water matrices via non-radical Fenton-like mechanism mediated by surface-disordered WO3. Environmental Science and Pollution Research 2021, 50 https://doi.org/10.1007/s11356-021-17088-z
  81. Wenya Peng, Yongxia Dong, Yu Fu, Lingli Wang, Qingchao Li, Yunjiao Liu, Qingya Fan, Zhaohui Wang. Non-radical reactions in persulfate-based homogeneous degradation processes: A review. Chemical Engineering Journal 2021, 421 , 127818. https://doi.org/10.1016/j.cej.2020.127818
  82. Xiaohui Fan, Heng Lin, Jinjin Zhao, Yican Mao, Jiaxing Zhang, Hui Zhang. Activation of peroxymonosulfate by sewage sludge biochar-based catalyst for efficient removal of bisphenol A: Performance and mechanism. Separation and Purification Technology 2021, 272 , 118909. https://doi.org/10.1016/j.seppur.2021.118909
  83. Liang Liang, Xiuyan Yue, Shuying Dong, Jinglan Feng, Jianhui Sun, Yuwei Pan, Minghua Zhou. New insights into the effect of adsorption on catalysis in the metal-free persulfate activation process for removing organic pollutants. Separation and Purification Technology 2021, 272 , 118923. https://doi.org/10.1016/j.seppur.2021.118923
  84. Jie Dong, Weihua Xu, Shaobo Liu, Li Du, Qiang Chen, Ting Yang, Youzi Gong, Meifang Li, Xiaofei Tan, Yunguo Liu. Recent advances in applications of nonradical oxidation in water treatment: Mechanisms, catalysts and environmental effects. Journal of Cleaner Production 2021, 321 , 128781. https://doi.org/10.1016/j.jclepro.2021.128781
  85. Lu-Lu Zhou, Peng-Xi Liu, Ying Ding, Jia-Rui Xi, Li-Juan Liu, Wei-Kang Wang, Juan Xu. Hierarchically porous structure of two-dimensional nano-flakes assembled flower-like NiO promotes the formation of surface-activated complex during persulfate activation. Chemical Engineering Journal 2021, 403 , 133134. https://doi.org/10.1016/j.cej.2021.133134
  86. Guangfei Liu, Huali Yu, Tian'ao Zhou, Ruofei Jin, Jiti Zhou. Activation of peroxydisulfate by biogenic nanocomposites of reduced graphene oxide and goethite for non-radical selective oxidation of organic contaminants: Production of singlet oxygen and direct electron transfer. Chemical Engineering Journal 2021, 26 , 133177. https://doi.org/10.1016/j.cej.2021.133177
  87. Zhentao Li, Changjun Hu, Zhuang Hu, Yuanyuan Fu, Zilin Chen. Facile synthesis of novel multifunctional β-cyclodextrin microporous organic network and application in efficient removal of bisphenol A from water. Carbohydrate Polymers 2021, 335 , 118786. https://doi.org/10.1016/j.carbpol.2021.118786
  88. Ya Liu, Chunmao Chen, Xiaoguang Duan, Shaobin Wang, Yuxian Wang. Carbocatalytic ozonation toward advanced water purification. Journal of Materials Chemistry A 2021, 9 (35) , 18994-19024. https://doi.org/10.1039/D1TA02953C
  89. Mufan Xi, Kangping Cui, Minshu Cui, Yan Ding, Zhi Guo, Yihan Chen, Chenxuan Li, Xiaoyang Li. Enhanced norfloxacin degradation by iron and nitrogen co-doped biochar: Revealing the radical and nonradical co-dominant mechanism of persulfate activation. Chemical Engineering Journal 2021, 420 , 129902. https://doi.org/10.1016/j.cej.2021.129902
  90. Chaofan Zhang, Xi Chen, Shih-Hsin Ho. Wastewater treatment nexus: Carbon nanomaterials towards potential aquatic ecotoxicity. Journal of Hazardous Materials 2021, 417 , 125959. https://doi.org/10.1016/j.jhazmat.2021.125959
  91. Shiyu Zuo, Zeyu Guan, Dongsheng Xia, Fan Yang, Haiming Xu, Mingzhi Huang, Dongya Li. Polarized heterogeneous CuO-CN for peroxymonosulfate nonradical activation: An enhancement mechanism of mediated electron transfer. Chemical Engineering Journal 2021, 420 , 127619. https://doi.org/10.1016/j.cej.2020.127619
  92. Qi Wang, Dongmei Zhou, Kuangfei Lin, Xiurong Chen. Carbon nitride–based cuprous catalysts induced nonradical-led oxidation by peroxydisulfate: Role of cuprous and dissolved oxygen. Chemical Engineering Journal 2021, 419 , 129667. https://doi.org/10.1016/j.cej.2021.129667
  93. Bowen Yang, Haisu Kang, Young-Jin Ko, Heesoo Woo, Geondu Gim, Jaemin Choi, Jaesung Kim, Kangwoo Cho, Eun-Ju Kim, Seung-Geol Lee, Hongshin Lee, Jaesang Lee. Persulfate activation by nanodiamond-derived carbon onions: Effect of phase transformation of the inner diamond core on reaction kinetics and mechanisms. Applied Catalysis B: Environmental 2021, 293 , 120205. https://doi.org/10.1016/j.apcatb.2021.120205
  94. Shangyi Li, Xueqi Fan, Mengbin Gu, Giovanni Cagnetta, Jun Huang, Gang Yu. Confined-space strategy for anchoring catalytic nanoparticles on Si-OH by ball milling for enhanced O3/PMS oxidation of ciprofloxacin. Chemical Engineering Journal 2021, 368 , 132318. https://doi.org/10.1016/j.cej.2021.132318
  95. Ying Zhang, Haitong Zhao, Jiaxin Wen, Shihu Ding, Wei Wang. Insights into the nonradical degradation mechanisms of antibiotics in persulfate activation by tourmaline. Separation and Purification Technology 2021, 270 , 118772. https://doi.org/10.1016/j.seppur.2021.118772
  96. Ping Sun, Hui Liu, Mingbao Feng, Xuesheng Zhang, Yingsen Fang, Zhicai Zhai, Virender K. Sharma. Dual nonradical degradation of acetaminophen by peroxymonosulfate activation with highly reusable and efficient N/S co-doped ordered mesoporous carbon. Separation and Purification Technology 2021, 268 , 118697. https://doi.org/10.1016/j.seppur.2021.118697
  97. Shiyu Zuo, Dongsheng Xia, Zeyu Guan, Fan Yang, Binyang Zhang, Haiming Xu, Mingzhi Huang, Xuetao Guo, Dongya Li. The polarized electric field on Fe2O3/g-C3N4 for efficient peroxymonosulfate activation: A synergy of 1O2, electron transfer and pollutant oxidation. Separation and Purification Technology 2021, 269 , 118717. https://doi.org/10.1016/j.seppur.2021.118717
  98. Hui Song, Zeyu Guan, Luyi Chen, Haiming Xu, Dongsheng Xia, Mingzhi Huang, Dongya Li. Role of curvature in a carbon electronic structure under spatial confinement: Conversion of nonradicals to radicals. Carbon 2021, 180 , 22-30. https://doi.org/10.1016/j.carbon.2021.04.088
  99. Wuqi Huang, Sa Xiao, Hua Zhong, Ming Yan, Xin Yang. Activation of persulfates by carbonaceous materials: A review. Chemical Engineering Journal 2021, 418 , 129297. https://doi.org/10.1016/j.cej.2021.129297
  100. Yuyan Liu, Yuqing Sun, Zhonghao Wan, Fanqi Jing, Zhixiong Li, Jiawei Chen, Daniel C.W. Tsang. Tailored design of food waste hydrochar for efficient adsorption and catalytic degradation of refractory organic contaminant. Journal of Cleaner Production 2021, 310 , 127482. https://doi.org/10.1016/j.jclepro.2021.127482
Load more citations