Fabrication of Tubelike Co3O4 with Superior Peroxidase-Like Activity and Activation of PMS by a Facile Electrospinning Technique

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School of Paper-making and Botanical Resources Engineering, Key Lab of Pulp and Paper Science & Technology, Ministry of Education (Shandong Province), and §School of Chemistry and Pharmaceutical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, Shandong 250353, P. R. China
State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090, P. R. China
*Tel.: +86-0531-89631632. Fax: +86-0531-89631632. E-mail: [email protected] (H.L.).
*Tel.: +86-0531-89631632. Fax: +86-0531-89631632. E-mail: [email protected] (H.S.).
Cite this: Ind. Eng. Chem. Res. 2018, 57, 6, 2396–2403
Publication Date (Web):January 29, 2018
https://doi.org/10.1021/acs.iecr.7b04180
Copyright © 2018 American Chemical Society
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Abstract

Tubelike Co3O4 was successfully prepared by a facile electrospinning route combined with a subsequent calcining treatment. The as-prepared tubelike Co3O4 was exploited as peroxidase mimics and to activate peroxymonosulfate (PMS) to produce sulfate radicals. The tubelike Co3O4 exhibited intrinsic peroxidase-like activity and high ability of activating PMS to degrade 2,4-dichlorophenol compared with the powders for the high specific surface area and surface Co2+ and adsorbed oxygen contents. Furthermore, the electronic properties of Co3O4 and the catalytic mechanism on H2O2 and PMS were investigated by electron spin resonance test and density functional theory calculation. This study details the insights into Co3O4 nanomaterials for activation of peroxides and application in sustainable remediation.

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The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.iecr.7b04180.

  • XPS spectra of Co3O4 tubes in the activation of H2O2 and PMS, the effect of reaction conditions on the peroxidase-like activity of Co3O4 tubes, XRD patterns of the control powder sample, the effect of the catalyst concentration on the activation of PMS, TOC removal trend of Co3O4 tubes with the reaction time, the nitrogen adsorption–desorption isotherms of Co3O4 tubes and powders, XPS spectra of Co3O4 powders, the band structure and density of state (DOS) of Co3O4, and the cycling test result of Co3O4 tubes in the activation of PMS (PDF)

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