TiO2@UiO-68-CIL: A Metal–Organic-Framework-Based Bifunctional Composite Catalyst for a One-Pot Sequential Asymmetric Morita–Baylis–Hillman Reaction

  • Yu-Hong Hu
    Yu-Hong Hu
    College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Centre of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University, Jinan 250014, P. R. China
    More by Yu-Hong Hu
  • Cong-Xue Liu
    Cong-Xue Liu
    College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Centre of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University, Jinan 250014, P. R. China
    More by Cong-Xue Liu
  • Jian-Cheng Wang*
    Jian-Cheng Wang
    College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Centre of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University, Jinan 250014, P. R. China
    *E-mail: [email protected]
  • Xiu-Hui Ren
    Xiu-Hui Ren
    College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Centre of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University, Jinan 250014, P. R. China
    More by Xiu-Hui Ren
  • Xuan Kan
    Xuan Kan
    College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Centre of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University, Jinan 250014, P. R. China
    More by Xuan Kan
  • , and 
  • Yu-Bin Dong*
    Yu-Bin Dong
    College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Centre of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University, Jinan 250014, P. R. China
    *E-mail: [email protected]
    More by Yu-Bin Dong
Cite this: Inorg. Chem. 2019, 58, 8, 4722–4730
Publication Date (Web):October 9, 2018
https://doi.org/10.1021/acs.inorgchem.8b02132
Copyright © 2018 American Chemical Society
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Abstract

A chiral ionic liquid (CIL) moiety of a l-pyrrolidin-2-ylimidazole-decorated homochiral UiO-68-type metal–organic framework, UiO-68-CIL (1), was successfully prepared by the combination of a new premodified chiral CIL ligand (H2L-CIL) and ZrCl4 via a solvothermal method. The TiO2-loaded TiO2@UiO-68-CIL (2) was prepared by impregnating 1 in a toluene solution of Ti(OPri)4 and sequential in situ hydrolysis. The obtained 2 can be a bifunctional asymmetric heterogeneous catalyst to successfully promote the one-pot Morita–Baylis–Hillman reaction starting from aromatic alcohols in a tandem way.

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  • Synthesis and characterization of H2L-CIL, additional characterization of 2, and MBH product characterization (PDF)

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  2. Seongwoo Kim, Ha-Eun Lee, Jong-Min Suh, Mi Hee Lim, Min Kim. Sequential Connection of Mutually Exclusive Catalytic Reactions by a Method Controlling the Presence of an MOF Catalyst: One-Pot Oxidation of Alcohols to Carboxylic Acids. Inorganic Chemistry 2020, 59 (23) , 17573-17582. https://doi.org/10.1021/acs.inorgchem.0c02809
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