Size-Tailored Porous Spheres of Manganese Oxides for Catalytic Oxidation via Peroxymonosulfate Activation

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Department of Chemical Engineering, Curtin University, GPO Box U1987, Bentley, WA 6845, Australia
School of Engineering, Edith Cowan University, 270 Joondalup Drive, Joondalup, WA 6027, Australia
§ State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing, 18 Fuxue Road, Beijing 102249, P. R. China
*Phone +61 8 6304-5067; e-mail [email protected] (H.S.).
*Phone +61 8 9266-3776; e-mail [email protected] (S.W.).
Cite this: J. Phys. Chem. C 2016, 120, 30, 16871–16878
Publication Date (Web):July 6, 2016
https://doi.org/10.1021/acs.jpcc.6b05934
Copyright © 2016 American Chemical Society
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Abstract

Highly porous and monodisperse manganese oxides with different particle sizes were synthesized via a one-pot hydration and annealing process. Their catalytic performances were evaluated by the activation of peroxymonosulfate (PMS) to degrade phenol in aqueous solutions. The effects of sphere size (200–500 nm), calcination temperature (200–1000 °C), catalytic stability (leaching problem and reusability), reaction kinetics, and reaction temperature (25–45 °C) on the degradation efficiencies as well as the degradation mechanism were comprehensively studied. The small sized catalyst displayed the best efficiency in decomposition of phenol, and the annealing treatments would significantly improve the catalytic stability.

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The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.jpcc.6b05934.

  • XRD patterns, kinetics of catalytic phenol degradation, stability and estimation of activation energies of different samples (PDF)

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