Preparation and Evaluation of Copper–Manganese Oxide as a High-Efficiency Catalyst for CO Oxidation and NO Reduction by CO

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Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, P. R. China
Department of Chemistry, College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, P. R. China
Cite this: J. Phys. Chem. C 2017, 121, 23, 12757–12770
Publication Date (Web):May 22, 2017
https://doi.org/10.1021/acs.jpcc.7b02052
Copyright © 2017 American Chemical Society
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Abstract

In this work, highly efficient Cux–Mn composite catalysts (0 ≤ x ≤ 0.20) were synthesized by an improved hydrothermal–citrate complex method and tested in the catalytic total oxidation of CO and the removal of NO by CO. The influence of Cu on manganese oxide materials was characterized by several techniques, including FESEM, HRTEM, XRD, BET analysis, H2 TPR, O2 TPD, XPS, and DRIFTS. Possible reaction mechanisms for the NO + CO model reaction and CO oxidation were also tentatively proposed. The Cu-modified manganese oxide materials showed higher catalytic activity in CO oxidation and the selective catalytic reduction (SCR) of NO with CO than pure MnOx materials. The improved catalytic activity in CO oxidation observed for the copper–manganese oxide catalyst was associated with a greater amount of adsorbed oxygen species and high lattice oxygen mobility due to the formation of a Cu1.5Mn1.5O4 spinel active phase (Cux2+–Mnx3+–[O(yz)z] species). Furthermore, in terms of the CO-SCR model reaction, the surface-dispersed Cux+–O2––Mny+ active species could be reduced to a Cu+–□–Mn(4–x)+ active species, which was considered to be the primary active component in the reduction of NO by CO. The results of the catalytic performance testing indicated that Cu0.075Mn had the highest catalytic activity in CO oxidation, whereas Cu0.15Mn exhibited the best CO-SCR catalytic performance.

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  • Additional in situ DRIFT spectra of NO adsorption (PDF)

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