Hierarchical Iron-Doped Nickel Diselenide Hollow Spheres for Efficient Oxygen Evolution Electrocatalysis

  • Lifeng Lin
    Lifeng Lin
    Department of Materials Science and State Key Laboratory of Molecular Engineering of Polymers, Fudan University, Shanghai 200433, China
    More by Lifeng Lin
  • Min Chen
    Min Chen
    Department of Materials Science and State Key Laboratory of Molecular Engineering of Polymers, Fudan University, Shanghai 200433, China
    More by Min Chen
  • , and 
  • Limin Wu*
    Limin Wu
    Department of Materials Science and State Key Laboratory of Molecular Engineering of Polymers, Fudan University, Shanghai 200433, China
    *(L.W.) E-mail: [email protected]
    More by Limin Wu
Cite this: ACS Appl. Energy Mater. 2019, 2, 7, 4737–4744
Publication Date (Web):June 17, 2019
https://doi.org/10.1021/acsaem.9b00337
Copyright © 2019 American Chemical Society
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Abstract

Explorin gearth-abundant oxygen evolution reaction electrocatalysts is attracting tremendous attention but still remains challenging. In this study, we design and synthesize hierarchical iron-doped nickel selenides with hollow structure and tunable composition. Benefiting from the synergistic effects of high specific surface area and optimal heteroatom doping, 5% Fe doped NiSe2 hollow spheres present excellent performances, exhibiting a 10 mA cm–2 current density at the overpotential as low as 231 mV and long-term stability for 20 h at 15 mA cm–2 in the basic medium.

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The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsaem.9b00337.

  • Characterization data (TEM, SEM, Raman spectra, XRD, XPS, electrochemical measurement tests, and so forth) and comparison of catalytic activity of various OER catalysts (PDF)

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