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Constructing Fe-MOF-Derived Z-Scheme Photocatalysts with Enhanced Charge Transport: Nanointerface and Carbon Sheath Synergistic Effect

  • Ya Li
    Ya Li
    Institute of Environmental Research at Greater Bay Area; Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education; Guangzhou Key Laboratory for Clean Energy and Materials, Guangzhou University, Guangzhou 510006, China
    More by Ya Li
  • Yu Xia
    Yu Xia
    Department of Gastroenterology and Hepatology, Guangzhou Digestive Disease Center, Guangzhou First People’s Hospital, School of Medicine, South China University of Technology, Guangzhou 510180, China
    More by Yu Xia
  • Kuiliang Liu
    Kuiliang Liu
    Institute of Environmental Research at Greater Bay Area; Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education; Guangzhou Key Laboratory for Clean Energy and Materials, Guangzhou University, Guangzhou 510006, China
    More by Kuiliang Liu
  • Kaihang Ye
    Kaihang Ye
    School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, Guangdong, China
    More by Kaihang Ye
  • Qiushi Wang
    Qiushi Wang
    School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, Guangdong, China
    More by Qiushi Wang
  • Shanqing Zhang*
    Shanqing Zhang
    Country Centre for Clean Environment and Energy, School of Environment and Science, Griffith University, Southport, Queensland 4215, Australia
    *Email: [email protected]
  • Yongchao Huang*
    Yongchao Huang
    Institute of Environmental Research at Greater Bay Area; Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education; Guangzhou Key Laboratory for Clean Energy and Materials, Guangzhou University, Guangzhou 510006, China
    *Email: [email protected]
  • , and 
  • Hong Liu
    Hong Liu
    Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 401122, China
    More by Hong Liu
Cite this: ACS Appl. Mater. Interfaces 2020, 12, 22, 25494–25502
Publication Date (Web):May 13, 2020
https://doi.org/10.1021/acsami.0c06601
Copyright © 2020 American Chemical Society
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Abstract

Creatively constructing Z-scheme composites is a promising and common strategy for designing effective photocatalyst systems. Herein, we synthesized Z-scheme Fe2O3@Ag–[email protected] heterostructures from the Fe-MOFs and applied it to photodegradation of tetracycline and methylene blue pollutants in wastewater. The optimized sample exhibits a remarkable performance as well as stability under visible light irradiation. The calculating and experimental results demonstrate that the Fe2O3@ZnO nanointerface and carbon sheath together boost the transfer efficiency of photogenerated carriers and absorption ability, thereby improving the photocatalytic activity. Furthermore, detailed mechanism investigation reveals the pivotal role of reactive oxygen species (OH and O2) generated, resulting in remarkable performance. In addition, cell biology experiments reveal that the wastewater after photocatalytic treatment has good biological compatibility, which is important for applications. This work provides valuable information for constructing high-performance Z-scheme photocatalysts from MOFs for environmental treatment.

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  • XPS spectra, nitrogen adsorption–desorption isotherm, cycling performance, SEM and XRD for FAZ, UV–vis diffuse reflectance spectra, XRD and SEM images, binding energy spectra, and the cell cycle distribution (PDF)

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  2. Xuzhao Han, Yang Qin, Jiaxin Luo, Fazhi Zhang, Xiaodong Lei. Polygonal CuS Nanoprisms Fabricated by Grinding Reaction for Advanced Quasi-Solid-State Asymmetry Supercapacitors. ACS Applied Energy Materials 2021, 4 (11) , 12631-12640. https://doi.org/10.1021/acsaem.1c02386
  3. Yongfu Tang, Haiwei Li, Ruonan Zhang, Wenfeng Guo, Meiqi Yu. [email protected] Material Derived from ZIF-8 for Lithium-Ion Capacitors. ACS Omega 2021, 6 (43) , 28528-28537. https://doi.org/10.1021/acsomega.1c02271
  4. Fan Wu, Rajesh Pathak, Junhong Liu, Ronghua Jian, Tiansheng Zhang, Quinn Qiao. Photoelectrochemical Application and Charge Transport Dynamics of a Water-Stable Organic–Inorganic Halide (C6H4NH2CuCl2I) Film in Aqueous Solution. ACS Applied Materials & Interfaces 2021, 13 (37) , 44274-44283. https://doi.org/10.1021/acsami.1c11082
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  7. Jin Kyung Park, Madhumita Patel, Zhengyu Piao, So-Jung Park, Byeongmoon Jeong. Size and Shape Control of Ice Crystals by Amphiphilic Block Copolymers and Their Implication in the Cryoprotection of Mesenchymal Stem Cells. ACS Applied Materials & Interfaces 2021, 13 (29) , 33969-33980. https://doi.org/10.1021/acsami.1c09933
  8. Fei Rao, Gangqiang Zhu, Weibin Zhang, Yunhua Xu, Baowei Cao, Xianjin Shi, Jianzhi Gao, Yuhong Huang, Yu Huang, Mirabbos Hojamberdiev. Maximizing the Formation of Reactive Oxygen Species for Deep Oxidation of NO via Manipulating the Oxygen-Vacancy Defect Position on (BiO)2CO3. ACS Catalysis 2021, 11 (13) , 7735-7749. https://doi.org/10.1021/acscatal.1c01251
  9. Jingnan Zhang, Yongchao Huang, Xinyu Lu, Jindong Yang, Yexiang Tong. Enhanced BiVO4 Photoanode Photoelectrochemical Performance via Borate Treatment and a NiFeOx Cocatalyst. ACS Sustainable Chemistry & Engineering 2021, 9 (24) , 8306-8314. https://doi.org/10.1021/acssuschemeng.1c03055
  10. Jayanthan P. Jayaraman, Muhammed Hamdan, Manishankar Velpula, Niket S. Kaisare, Aravind Kumar Chandiran. BiVO4/Cs2PtI6 Vacancy-Ordered Halide Perovskite Heterojunction for Panchromatic Light Harvesting and Enhanced Charge Separation in Photoelectrochemical Water Oxidation. ACS Applied Materials & Interfaces 2021, 13 (14) , 16267-16278. https://doi.org/10.1021/acsami.0c22654
  11. Kirk S. Schanze (Editor-in-Chief). Year 2020: Science and Engineering Research Continues. ACS Applied Materials & Interfaces 2021, 13 (13) , 14799-14801. https://doi.org/10.1021/acsami.1c04978
  12. Kunlin Tang, Zhiqiang Wang, Weixin Zou, Hongyu Guo, Yuchao Wu, Yu Pu, Qing Tong, Haiqin Wan, Xianrui Gu, Lin Dong, Junfeng Rong, Yu-Wen Chen. Advantageous Role of Ir0 Supported on TiO2 Nanosheets in Photocatalytic CO2 Reduction to CH4: Fast Electron Transfer and Rich Surface Hydroxyl Groups. ACS Applied Materials & Interfaces 2021, 13 (5) , 6219-6228. https://doi.org/10.1021/acsami.0c19233
  13. Hao Li, Jianwu Sun. Highly Selective Photocatalytic CO2 Reduction to CH4 by Ball-Milled Cubic Silicon Carbide Nanoparticles under Visible-Light Irradiation. ACS Applied Materials & Interfaces 2021, 13 (4) , 5073-5078. https://doi.org/10.1021/acsami.0c19945
  14. Agne Sulciute, Keita Nishimura, Evgeniia Gilshtein, Federico Cesano, Guido Viscardi, Albert G. Nasibulin, Yutaka Ohno, Simas Rackauskas. ZnO Nanostructures Application in Electrochemistry: Influence of Morphology. The Journal of Physical Chemistry C 2021, 125 (2) , 1472-1482. https://doi.org/10.1021/acs.jpcc.0c08459
  15. Haihong Zheng, Fang Yang, Tuzhi Xiong, David Adekoya, Yongchao Huang, M.-Sadeeq Jie Tang Balogun. Polypyrrole Hollow Microspheres with Boosted Hydrophilic Properties for Enhanced Hydrogen Evolution Water Dissociation Kinetics. ACS Applied Materials & Interfaces 2020, 12 (51) , 57093-57101. https://doi.org/10.1021/acsami.0c16938
  16. Xiaolin He, Biyun Lin, Liqin Yang, Chaoqun Shang, Shanshan Li, Zhihong Chen, Xin Wang. Novel Fe2O3/PZT Nanorods for Ferroelectric Polarization-Enhanced Photoelectrochemical Water Splitting. Energy & Fuels 2020, 34 (12) , 16927-16935. https://doi.org/10.1021/acs.energyfuels.0c02888
  17. Sanjoy Mondal, Yoshikazu Ninomiya, Masayoshi Higuchi. Durable Supercapattery Film with Dual-Branched Dense Hexagonal Fe(II)-Based Coordination Nanosheets for Flexible Power Sources. ACS Applied Energy Materials 2020, 3 (11) , 10653-10659. https://doi.org/10.1021/acsaem.0c01720
  18. Heejung Kong, Jinhyeong Kwon, Dongwoo Paeng, Won Jun Jung, Santosh Ghimire, Joonghoe Dho, Jae-Hyuck Yoo, Sukjoon Hong, Jinwook Jung, Jaeho Shin, Costas P. Grigoropoulos, Seung Hwan Ko, Junyeob Yeo. Laser-Induced Crystalline-Phase Transformation for Hematite Nanorod Photoelectrochemical Cells. ACS Applied Materials & Interfaces 2020, 12 (43) , 48917-48927. https://doi.org/10.1021/acsami.0c11999
  19. Shubham Yadav, Archa Nair, Kusuma Urs MB, Vinayak B. Kamble. Protonic Titanate Nanotube–Reduced Graphene Oxide Composites for Hydrogen Sensing. ACS Applied Nano Materials 2020, 3 (10) , 10082-10093. https://doi.org/10.1021/acsanm.0c02077
  20. Ya Li, Kuiliang Liu, Jingnan Zhang, Jingdong Yang, Yongchao Huang, Yexiang Tong. Engineering the Band-Edge of Fe2O3/ZnO Nanoplates via Separate Dual Cation Incorporation for Efficient Photocatalytic Performance. Industrial & Engineering Chemistry Research 2020, 59 (42) , 18865-18872. https://doi.org/10.1021/acs.iecr.0c03388
  21. Qiuxia Cheng, Yingying Pan, Yueying Chen, Akif Zeb, Xiaoming Lin, Zhongzhi Yuan, Jincheng Liu. Nanostructured Iron Fluoride Derived from Fe-Based Metal–Organic Framework for Lithium Ion Battery Cathodes. Inorganic Chemistry 2020, 59 (17) , 12700-12710. https://doi.org/10.1021/acs.inorgchem.0c01783
  22. Eunsoo Kim, Sungsoon Kim, Young Moon Choi, Jong Hyeok Park, Hyunjung Shin. Ultrathin Hematite on Mesoporous WO3 from Atomic Layer Deposition for Minimal Charge Recombination. ACS Sustainable Chemistry & Engineering 2020, 8 (30) , 11358-11367. https://doi.org/10.1021/acssuschemeng.0c03579
  23. Shuangyang Zhao, Chengxin Chen, Jie Ding, Shanshan Yang, Yani Zang, Nanqi Ren. One-pot hydrothermal fabrication of BiVO4/Fe3O4/rGO composite photocatalyst for the simulated solar light-driven degradation of Rhodamine B. Frontiers of Environmental Science & Engineering 2022, 16 (3) https://doi.org/10.1007/s11783-021-1470-y
  24. Xinyu Lu, Kai-hang Ye, Siqi Zhang, Jingnan Zhang, Jindong Yang, Yongchao Huang, Hongbing Ji. Amorphous type FeOOH modified defective BiVO4 photoanodes for photoelectrochemical water oxidation. Chemical Engineering Journal 2022, 428 , 131027. https://doi.org/10.1016/j.cej.2021.131027
  25. Jungang Yi, Xianghui Wu, Huadong Wu, Jia Guo, Kun Wu, Linfeng Zhang. Facile synthesis of novel NH 2 -MIL-53(Fe)/AgSCN heterojunction composites as a highly efficient photocatalyst for ciprofloxacin degradation and H 2 production under visible-light irradiation. Reaction Chemistry & Engineering 2022, 250 https://doi.org/10.1039/D1RE00349F
  26. Huanhuan Ji, Chun Hu, Sai Zhang, Lili Zhang, Xiaozhuo Yang. BiO(OH)xI1-x solid solution with rich oxygen vacancies: interlayer guest hydroxyl for improved photocatalytic properties. Journal of Colloid and Interface Science 2022, 605 , 1-12. https://doi.org/10.1016/j.jcis.2021.07.060
  27. Salim Ali, Shatarupa Basak, Suranjan Sikdar, MahendraNath Roy. Synergetic effects of green synthesized CeO2 nanorod-like catalyst for degradation of organic pollutants to reduce water pollution. Environmental Nanotechnology, Monitoring & Management 2021, 16 , 100539. https://doi.org/10.1016/j.enmm.2021.100539
  28. Ali Akbari, Hessam Jafari, Gholamreza Gohari, Gader Kheiri, Gholam Reza Mahdavinia. Fulvic acid-embedded poly (vinyl alcohol)–zinc oxide hydrogel nanocomposite: synthesis, characterization, swelling and release kinetic. International Nano Letters 2021, 11 (4) , 347-354. https://doi.org/10.1007/s40089-021-00344-y
  29. Jiacheng Liu, Guangfu Qian, Hao Zhang, Jinli Chen, Yujiao Wang, Huibing He, Lin Luo, Shibin Yin. Amorphous FeOOH coating stabilizes WO2-NaxWO3 for accelerating oxygen evolution reaction. Chemical Engineering Journal 2021, 426 , 131253. https://doi.org/10.1016/j.cej.2021.131253
  30. Borui Du, Ruichi Li, Yanghong Zhang, Xingyu Chen, Rencai Tao, Zihang Qin, ChaoPing Fu, Jingran Xiao. Pluronic-assisted modifications of FeOOH precursor facilitate morphology adjustment and performance enhancement of Fe2O3 photoanodes. International Journal of Hydrogen Energy 2021, 9 https://doi.org/10.1016/j.ijhydene.2021.10.115
  31. Xiaolan Gao, Zhixiao Xu, Ge Li. MOF-driven ultrafine Co9S8 nanocrystals embedded in N, S-Codoped Multilayer-Assembled carbon nanoplates for efficient bifunctional oxygen electrocatalysis. Chemical Engineering Journal 2021, 302 , 133385. https://doi.org/10.1016/j.cej.2021.133385
  32. Shi-Wen Lv, Yanqing Cong, Xiang Chen, Wanxing Wang, Lin Che. Developing fine-tuned metal–organic frameworks for photocatalytic treatment of wastewater: A review. Chemical Engineering Journal 2021, 53 , 133605. https://doi.org/10.1016/j.cej.2021.133605
  33. Ping Li, Jiangna Guo, Xing Ji, Yuli Xiong, Qingxin Lai, Shuangrui Yao, Yan Zhu, Yunhuai Zhang, Peng Xiao. Construction of direct Z-scheme photocatalyst by the interfacial interaction of WO3 and SiC to enhance the redox activity of electrons and holes. Chemosphere 2021, 282 , 130866. https://doi.org/10.1016/j.chemosphere.2021.130866
  34. Shangqing Zhang, Shaohui Guo, Aimin Li, Dongna Liu, Hongfu Sun, Fenghua Zhao. Low-cost bauxite residue-MoS2 possessing adsorption and photocatalysis ability for removing organic pollutants in wastewater. Separation and Purification Technology 2021, 268 , 120144. https://doi.org/10.1016/j.seppur.2021.120144
  35. Tianqi Wang, Bingbing Tian, Bin Han, Dingren Ma, Mingzhe Sun, Aamir Hanif, Dehua Xia, Jin Shang. Recent Advances on Porous Materials for Synergetic Adsorption and Photocatalysis. ENERGY & ENVIRONMENTAL MATERIALS 2021, 63 https://doi.org/10.1002/eem2.12229
  36. Huidong Shen, Feng Fu, Wenwen Xue, Xiaoxia Yang, Saira Ajmal, Yanzhong Zhen, Li Guo, Danjun Wang, Ruan Chi. In situ fabrication of Bi2MoO6/Bi2MoO6-x homojunction photocatalyst for simultaneous photocatalytic phenol degradation and Cr(VI) reduction. Journal of Colloid and Interface Science 2021, 599 , 741-751. https://doi.org/10.1016/j.jcis.2021.04.122
  37. M. Rashid, D. Mowla, F. Esmaeilzadeh, K. Dashtian, M. Bahmani. Boosted Cr(VI) clean up over magnetically recoverable NiS/γ-Fe2O3/C type-II heterostructure derived from bimetal (Fe/Ni)-organic framework under visible light. Journal of Cleaner Production 2021, 317 , 128471. https://doi.org/10.1016/j.jclepro.2021.128471
  38. Bidhan Pandit, Sachin R. Rondiya, Shyamal Shegokar, Lakshmana Kumar Bommineedi, Russell W. Cross, Nelson Y. Dzade, Babasaheb R. Sankapal. Combined electrochemical and DFT investigations of iron selenide: a mechanically bendable solid-state symmetric supercapacitor. Sustainable Energy & Fuels 2021, 5 (19) , 5001-5012. https://doi.org/10.1039/D1SE00074H
  39. Ruiling Wang, Yaustaka Kuwahara, Kohsuke Mori, Hiromi Yamashita. Semiconductor‐based Photoanodes Modified with Metal‐organic Frameworks and Molecular Catalysts as Cocatalysts for Enhanced Photoelectrochemical Water Oxidation Reaction. ChemCatChem 2021, https://doi.org/10.1002/cctc.202101033
  40. Shuai Zhang, Shuangrun Zhao, Shunjiang Huang, Bin Hu, Minghua Wang, Zhihong Zhang, Linghao He, Miao Du. Photocatalytic degradation of oxytetracycline under visible light by nanohybrids of CoFe alloy nanoparticles and nitrogen-/sulfur-codoped mesoporous carbon. Chemical Engineering Journal 2021, 420 , 130516. https://doi.org/10.1016/j.cej.2021.130516
  41. Junxian Hu, Chaohong Guan, Huangxu Li, Yangyang Xie, Liuyun Zhang, Jingqiang Zheng, Yanqing Lai, Zhian Zhang. Boosting potassium-storage performance via confining highly dispersed molybdenum dioxide nanoparticles within N-doped porous carbon nano-octahedrons. Journal of Colloid and Interface Science 2021, 120 https://doi.org/10.1016/j.jcis.2021.09.068
  42. Yongteng Qian, Fangfang Zhang, Huan Pang. A Review of MOFs and Their Composites‐Based Photocatalysts: Synthesis and Applications. Advanced Functional Materials 2021, 31 (37) , 2104231. https://doi.org/10.1002/adfm.202104231
  43. Yejung Choi, Tianyu Chen, Dongwon Kim, Sang Gu Ji, Hwichan Hong, Lulu Lyu, Myeongseok Jang, Yuanzhe Piao. Transformation of microwave synthesized highly uniform FeMo-MIL-88B nanorod to oxynitride derivate for overall water splitting reaction. Applied Materials Today 2021, 24 , 101093. https://doi.org/10.1016/j.apmt.2021.101093
  44. Xitong Li, Bo Yang, Ke Xiao, Huabo Duan, Jinquan Wan, Huazhang Zhao. Targeted degradation of refractory organic compounds in wastewaters based on molecular imprinting catalysts. Water Research 2021, 203 , 117541. https://doi.org/10.1016/j.watres.2021.117541
  45. Dahai Zhu, Li Cai, Zhuyu Sun, Ai Zhang, Paul Héroux, Hyunjung Kim, Wei Yu, Yanan Liu. Efficient degradation of tetracycline by [email protected] titanium dioxide nanofluid via enhanced catalysis and photothermal conversion. Science of The Total Environment 2021, 787 , 147536. https://doi.org/10.1016/j.scitotenv.2021.147536
  46. Tao Hu, Jingjing Sun, Yifu Zhang, Yanyan Liu, Hanmei Jiang, Xueying Dong, Jiqi Zheng, Changgong Meng, Chi Huang. PVA-assisted hydrated vanadium pentoxide/reduced graphene oxide films for excellent Li+ and Zn2+ storage properties. Journal of Materials Science & Technology 2021, 83 , 7-17. https://doi.org/10.1016/j.jmst.2020.10.087
  47. Hye Ji Jang, So Jeong Park, Ju Hyun Yang, Sung-Min Hong, Choong Kyun Rhee, Youngku Sohn. Photocatalytic and Electrocatalytic Properties of Cu-Loaded ZIF-67-Derivatized Bean Sprout-Like Co-TiO2/Ti Nanostructures. Nanomaterials 2021, 11 (8) , 1904. https://doi.org/10.3390/nano11081904
  48. Amirreza Valizadeh, Rahman Bikas, Pavlo Aleshkevych, Anna Kozakiewicz, Suleyman I. Allakhverdiev, Mohammad Mahdi Najafpour. A dinuclear iron complex as a precatalyst for water oxidation under alkaline conditions. International Journal of Hydrogen Energy 2021, 46 (58) , 29896-29904. https://doi.org/10.1016/j.ijhydene.2021.06.123
  49. Xinxin Jin, Yan Xie, Chaoyue Zhao, Yinghao Xu, Yang Lv, He Wang, Li Chen, Jiahui Huang. FeCo-based mesoporous carbon shells modified N-doped porous carbon spheres for oxygen reduction reaction. Progress in Natural Science: Materials International 2021, 31 (4) , 527-535. https://doi.org/10.1016/j.pnsc.2021.06.002
  50. Reda M. Mohamed, Adel. A. Ismail. Mesoporous α-Fe2O3/ZnO heterojunction with a synergistic effect for rapid and efficient reduction of mercury ions. Separation and Purification Technology 2021, 266 , 118360. https://doi.org/10.1016/j.seppur.2021.118360
  51. J. Tang, J.L. Xu, Z.G. Ye, X.B. Li, J.M. Luo. Microwave sintered porous CoCrFeNiMo high entropy alloy as an efficient electrocatalyst for alkaline oxygen evolution reaction. Journal of Materials Science & Technology 2021, 79 , 171-177. https://doi.org/10.1016/j.jmst.2020.10.079
  52. Guanzhou Lin, Husain Almakrami, Huzaifa Emran, Amar Ruthen, Jie Hu, Zi Wei, Fuqiang Liu. Enhanced Conversion Efficiency Enabled by Species Migration in Direct Solar Energy Storage. ChemPhysChem 2021, 22 (12) , 1193-1200. https://doi.org/10.1002/cphc.202100203
  53. M Burhanuz Zaman, Rajaram Poolla, Shakeel Ahmad Khandy, Anchit Modi, Rajendra Kumar Tiwari. Thioglycolic acid assisted hydrothermal growth of SnS 2D nanosheets as catalysts for photodegradation of industrial dyes. Nanotechnology 2021, 32 (24) , 245706. https://doi.org/10.1088/1361-6528/abec09
  54. Haleh Rasouli, Mir Ghasem Hosseini, Pariya Yardani sefidi, Solen Kinayyigit. Superior overall water splitting performance in polypyrrole photoelectrode by coupling NrGO and modifying electropolymerization substrate. Journal of Applied Polymer Science 2021, 138 (21) , 50507. https://doi.org/10.1002/app.50507
  55. Gouri Tudu, Sourav Ghosh, Sagar Ganguli, Heramba V. S. R. M. Koppisetti, Harish Reddy Inta, Venkataramanan Mahalingam. Ethylene glycol-mediated one-pot synthesis of Fe incorporated α-Ni(OH) 2 nanosheets with enhanced intrinsic electrocatalytic activity and long-term stability for alkaline water oxidation. Dalton Transactions 2021, 50 (21) , 7305-7313. https://doi.org/10.1039/D1DT00226K
  56. Shinya Higashimoto, Yushi Sasakura, Ryuki Tokunaga, Masanari Takahashi, Hisayoshi Kobayashi, Junzhe Jiang, Yoshihisa Sakata. Synthesis, Characterization and Photocatalytic Properties of Robust Resorcinol-Formaldehyde Polymer Fine Particles. Applied Catalysis A: General 2021, 82 , 118240. https://doi.org/10.1016/j.apcata.2021.118240
  57. Yu Xia, Guoyi Tang, Yi Chen, Changbing Wang, Min Guo, Tiantian Xu, Mingqi Zhao, Yongjian Zhou. Tumor-targeted delivery of siRNA to silence Sox2 gene expression enhances therapeutic response in hepatocellular carcinoma. Bioactive Materials 2021, 6 (5) , 1330-1340. https://doi.org/10.1016/j.bioactmat.2020.10.019
  58. Shuyi Feng, Lin Ma, Jiawen Lin, Xiangyi Lu, Limei Xu, Jinfei Wu, Xiuli Yan, Xuliang Fan. SnS nanoparticles anchored on nitrogen-doped carbon sheets derived from metal-organic-framework precursors as anodes with enhanced electrochemical sodium ions storage. Electrochimica Acta 2021, 13 , 138535. https://doi.org/10.1016/j.electacta.2021.138535
  59. R. Chenna Krishna Reddy, Xiaoming Lin, Akif Zeb, Cheng-Yong Su. Metal–Organic Frameworks and Their Derivatives as Cathodes for Lithium-Ion Battery Applications: A Review. Electrochemical Energy Reviews 2021, 3 https://doi.org/10.1007/s41918-021-00101-x
  60. Jianhua Han, Haiyang Xing, Qinggong Song, Huiyu Yan, Jianhai Kang, Yanrui Guo, Zhifeng Liu. A [email protected]CuO core–shell heterojunction photoanode modified with ZnFe-LDH for efficient and stable photoelectrochemical performance. Dalton Transactions 2021, 50 (13) , 4593-4603. https://doi.org/10.1039/D1DT00336D
  61. Jayasmita Jana, Jin Suk Chung, Seung Hyun Hur. Carbon dot supported bimetallic nanocomposite for the hydrogen evolution reaction. Journal of Alloys and Compounds 2021, 859 , 157895. https://doi.org/10.1016/j.jallcom.2020.157895
  62. Qi Qin, Yi-Ran Cui, Meng Song, Ji-Yuan Li, Yan-Jie Wang, Jing Wang, Dian-Bo Zhang. Study on Electrochemical Stripping Method of Graphene Electrode and Its Capacitive Properties. Science of Advanced Materials 2021, 13 (4) , 608-614. https://doi.org/10.1166/sam.2021.3958
  63. You Zhang, Ning Xie, Lu Zhang, Fenghuang Wu, Zifei Xie, Qibin Fu, Yuxiang Wang, Jiaxiu Liu, Wenjie Fan. Synthesis of Bi 2 MoO 6 /BiOI Composites for Visible Light Driven Photocatalytic Degradation of Methylene Blue. Science of Advanced Materials 2021, 13 (4) , 545-549. https://doi.org/10.1166/sam.2021.3862
  64. Xue Huang, Xu-Ming Yan, Wen-Jie Chen, Chun-Yuan Tan, Guo-Qiang Yin, Guang-Zhu Feng. C 36 Dimer Fatty Acid-Based Flexible Unsaturated Polyester Resin: Improvement of Properties by Adjusting the Intermolecular Crosslinking Structure. Science of Advanced Materials 2021, 13 (4) , 597-607. https://doi.org/10.1166/sam.2021.3933
  65. Xian-Feng Li, Gui-Qiang Diao, Fang Xie, Wen-Hua Liao, Luigi Agostini, Ding-Shu Xiao, Guo-Cong Liu, Wei-Xin Wu, Hong-Bing Zhan, Shuang-Wu Huang. Influence on Electrochemical Properties of Different Types of Manganese Oxides. Science of Advanced Materials 2021, 13 (4) , 569-573. https://doi.org/10.1166/sam.2021.3913
  66. Linsen Huang, Deyu Bao, Xiaoqing Jiang, Junhua Li, Liangxing Zhang, Xiaosong Sun. Fabrication of stable high-performance urchin-like CeO2/[email protected] hierarchical heterojunction photocatalyst for water remediation. Journal of Colloid and Interface Science 2021, 588 , 713-724. https://doi.org/10.1016/j.jcis.2020.11.099
  67. Hong-Qing Qu, Hong Yin, Ya-Long Wang, Cheng Fan, Kwun Nam Hui, Chong Li, Ming-Qiang Zhu. Vapor selenization produced Bi 2 Se 3 nanoparticles in carbon fiber 3D network as binder-free anode for flexible lithium-ion batteries. Materials Chemistry Frontiers 2021, 5 (6) , 2832-2841. https://doi.org/10.1039/D0QM00884B
  68. Lili Feng, Ninghan Li, Siyao Tang, Yanru Guo, Jie Zheng, Xingguo Li. Photoelectrochemical performance of titanium dioxide/Prussian blue analogue synthesized by impregnation conversion method as photoanode. Inorganic Chemistry Communications 2021, 125 , 108349. https://doi.org/10.1016/j.inoche.2020.108349
  69. Mengjie Hao, Muqing Qiu, Hui Yang, Baowei Hu, Xiangxue Wang. Recent advances on preparation and environmental applications of MOF-derived carbons in catalysis. Science of The Total Environment 2021, 760 , 143333. https://doi.org/10.1016/j.scitotenv.2020.143333
  70. Sivakumar Vigneshwaran, Palliyalil Sirajudheen, Perumal Karthikeyan, Manuvelraja Nikitha, Krishnapillai Ramkumar, Sankaran Meenakshi. Immobilization of MIL-88(Fe) anchored TiO2-chitosan(2D/2D) hybrid nanocomposite for the degradation of organophosphate pesticide: Characterization, mechanism and degradation intermediates. Journal of Hazardous Materials 2021, 406 , 124728. https://doi.org/10.1016/j.jhazmat.2020.124728
  71. Kangzhe Cao, Shaodan Wang, Yongheng Jia, Dongli Xu, Huiqiao Liu, Ke-Jing Huang, Qiang-Shan Jing, Lifang Jiao. Promoting K ion storage property of SnS2 anode by structure engineering. Chemical Engineering Journal 2021, 406 , 126902. https://doi.org/10.1016/j.cej.2020.126902
  72. Hui Chang, Wenjuan Fan, Jiashuai Liu, Zhiqiang Jiang, Yufeng Li, Yun Zhang, Jian Zhang. Polyoxo-titanium clusters promoted photocatalytic H2 evolution activity in a NiS modified CdS/MIL-101 system. International Journal of Hydrogen Energy 2021, 46 (9) , 6369-6379. https://doi.org/10.1016/j.ijhydene.2020.11.120
  73. Aya M. Mohamed, Mohamed Ramadan, Nageh K. Allam. Recent advances on zeolitic imidazolate -67 metal-organic framework-derived electrode materials for electrochemical supercapacitors. Journal of Energy Storage 2021, 34 , 102195. https://doi.org/10.1016/j.est.2020.102195
  74. Hui Zhang, Liang Zhou, Jing Li, Sijia Rong, Jianping Jiang, Shengquan Liu. Photocatalytic Degradation of Tetracycline by a Novel (CMC)/MIL-101(Fe)/β-CDP Composite Hydrogel. Frontiers in Chemistry 2021, 8 https://doi.org/10.3389/fchem.2020.593730
  75. K. Iyakutti, V.J. Surya, I. Lakshmi, R. Rajeswarapalanichamy, Y. Kawazoe. 18 and 12 – Member carbon rings (cyclo[n]carbons) – A density functional study. Materials Science and Engineering: B 2021, 263 , 114895. https://doi.org/10.1016/j.mseb.2020.114895
  76. Xiaozhen Ren, Xunshuang Zhang, Ruichen Guo, Shulan Zhang, Lezhi Wang, Xipeng Pu. Bi and oxygen defects improved visible light photocatalysis with BiOBr nanosheets. Nanotechnology 2020, 31 (49) , 495405. https://doi.org/10.1088/1361-6528/abb338
  77. S. Sun, H. Qin, H. Wang, R. Ning, Y. Zhao, J. Zhu, Z. Gao, D. Cong, Y. Wang, W. Cai. Colossal magnetocaloric effect in Ni–Co–Mn–In alloys induced by electron irradiation. Materials Today Energy 2020, 18 , 100533. https://doi.org/10.1016/j.mtener.2020.100533
  78. Bilel Chouchene, Thomas Gries, Lavinia Balan, Ghouti Medjahdi, Raphaël Schneider. Graphitic carbon nitride/SmFeO 3 composite Z-scheme photocatalyst with high visible light activity. Nanotechnology 2020, 31 (46) , 465704. https://doi.org/10.1088/1361-6528/abadc7
  79. Shikang Jiang, Meijuan Xiang, Jingyuan Zhang, Shengqi Chu, Augusto Marcelli, Wangsheng Chu, Dajun Wu, Bin Qian, Shi Tao, Li Song. Rational design of hierarchical FeSe 2 encapsulated with bifunctional carbon cuboids as an advanced anode for sodium-ion batteries. Nanoscale 2020, 12 (43) , 22210-22216. https://doi.org/10.1039/D0NR06359B
  80. Mei-Ling Xu, Ling-Wang Liu, Kai Wang, Yi-Chuan Dou, Kui Li, Xin Cheng, Feng-Ming Zhang. Hierarchical-metal–organic framework-templated Cu 0.5 Zn 0.5 In 2 S 4 -rGO-g-C 3 N 4 : flexible synthesis and enhanced photocatalytic activity. Journal of Materials Chemistry A 2020, 8 (42) , 22124-22133. https://doi.org/10.1039/D0TA07449G
  81. Byung Hyun Park, Junhee Lee, Hyerim Park, Jeong Yeon Do, Youngsoo Kim, Rama Krishna Chava, Misook Kang. Effective charge separation through the sulfur vacancy interfacial in n-CdO/p-CdS bulk heterojunction particle and its solar-induced hydrogen production. Journal of Industrial and Engineering Chemistry 2020, 91 , 149-166. https://doi.org/10.1016/j.jiec.2020.07.049
  82. Jindong Yang, Ning Xie, Jingnan Zhang, Wenjie Fan, Yongchao Huang, Yexiang Tong. Defect Engineering Enhances the Charge Separation of CeO2 Nanorods toward Photocatalytic Methyl Blue Oxidation. Nanomaterials 2020, 10 (11) , 2307. https://doi.org/10.3390/nano10112307
  83. Mingchen Shi, Qiang Wang, Junwei Hao, Huihua Min, Hairui You, Xiaomin Liu, Hui Yang. MOF-derived hollow Co 4 S 3 /C nanosheet arrays grown on carbon cloth as the anode for high-performance Li-ion batteries. Dalton Transactions 2020, 49 (40) , 14115-14122. https://doi.org/10.1039/D0DT03070H
  84. Umer Rafiq, Malik Wahid, Kowsar Majid. Optimized h‐BN/Sb 2 WO 6 Interface Mediates an Efficient Charge Separation towards Enhanced Photocatalysis. ChemistrySelect 2020, 5 (37) , 11637-11647. https://doi.org/10.1002/slct.202002981
  85. Jia-nan Cheng, Li-zhu Zhao, Guo-bao Li, Fang Li, Ming-ming Yao. B/Co/Fe tridoped TiO2/SiO2 composite films for improved photocatalytic degradation of organic pollutants under visible light. Inorganic Chemistry Communications 2020, 119 , 108089. https://doi.org/10.1016/j.inoche.2020.108089
  86. Changbing Wang, Yu Xia, Shaochuan Huo, Diwen Shou, Qing Mei, Wenjuan Tang, Yinghua Li, Hongsheng Liu, Yongjian Zhou, Bing Zhu. <p>Silencing of MEF2D by siRNA Loaded Selenium Nanoparticles for Ovarian Cancer Therapy</p>. International Journal of Nanomedicine 2020, Volume 15 , 9759-9770. https://doi.org/10.2147/IJN.S270441