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Successive Interfacial Reaction-Directed Synthesis of CeO2@[email protected]2-MnO2 Environmental Catalyst with Sandwich Hollow Structure

  • Guozhu Chen*
    Guozhu Chen
    Key Laboratory of Interfacial Reaction & Sensing Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, Jinan, Shandong Province 250022, China
    *E-mail: [email protected]
    More by Guozhu Chen
  • Yong Wang
    Yong Wang
    Key Laboratory of Interfacial Reaction & Sensing Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, Jinan, Shandong Province 250022, China
    More by Yong Wang
  • Yunwei Wei
    Yunwei Wei
    Key Laboratory of Interfacial Reaction & Sensing Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, Jinan, Shandong Province 250022, China
    More by Yunwei Wei
  • Wei Zhao
    Wei Zhao
    Shandong Institute and Laboratory of Geological Sciences, Jinan 250013, China
    More by Wei Zhao
  • Daowei Gao
    Daowei Gao
    Key Laboratory of Interfacial Reaction & Sensing Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, Jinan, Shandong Province 250022, China
    More by Daowei Gao
  • Hongxiao Yang
    Hongxiao Yang
    Key Laboratory of Interfacial Reaction & Sensing Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, Jinan, Shandong Province 250022, China
  • , and 
  • Cuncheng Li
    Cuncheng Li
    Key Laboratory of Interfacial Reaction & Sensing Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, Jinan, Shandong Province 250022, China
    More by Cuncheng Li
Cite this: ACS Appl. Mater. Interfaces 2018, 10, 14, 11595–11603
Publication Date (Web):March 20, 2018
https://doi.org/10.1021/acsami.7b18371
Copyright © 2018 American Chemical Society
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Supporting Info (1)»

Abstract

Noble metal nanoparticle-based catalysts are widely used for the removal of hazardous materials. During the catalytic reactions, it is of particular importance for developing novel strategies to avoid the leaching or sintering of noble metal nanoparticles. Here, the 4-nitrophenol (4-NP) and CO, typical hazardous chemicals in industrial water and exhaust gases from vehicles, are studied for their removal using CeO2@[email protected]2-MnO2 catalyst. The sandwich hollow structure is achieved by means of successive interfacial redox reaction without any surfactants and without involving any surface modifications. Because of the synergistic interaction between Au nanoparticles and oxides, the as-prepared environmental catalyst exhibits remarkable activity toward the 4-NP reduction. Moreover, the sandwich structure inhibits the growth of the Au nanoparticles and the as-prepared catalyst still displays high activity toward CO oxidation even when the catalyst is treated at 600 °C.

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The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsami.7b18371.

  • Detailed experimental procedures for the compared catalysts, TEM images of the catalysts with different-sized Au nanoparticles, XRD patterns for the catalysts before and after calcination, and one table for TOF values comparison (PDF)

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