High Infrared Blocking Cellulose Film Based on Amorphous to Anatase Transition of TiO2 via Atomic Layer Deposition

  • Wenbin Li
    Wenbin Li
    State Key Laboratory of New Textile Materials & Advanced Processing Technologies, Wuhan Textile University, Wuhan, Hubei 430200, China
    More by Wenbin Li
  • Linfeng Li
    Linfeng Li
    State Key Laboratory of New Textile Materials & Advanced Processing Technologies, Wuhan Textile University, Wuhan, Hubei 430200, China
    More by Linfeng Li
  • Xi Wu
    Xi Wu
    State Key Laboratory of New Textile Materials & Advanced Processing Technologies, Wuhan Textile University, Wuhan, Hubei 430200, China
    More by Xi Wu
  • Junyu Li
    Junyu Li
    State Key Laboratory of New Textile Materials & Advanced Processing Technologies, Wuhan Textile University, Wuhan, Hubei 430200, China
    More by Junyu Li
  • Lang Jiang
    Lang Jiang
    State Key Laboratory of New Textile Materials & Advanced Processing Technologies,  School of Material Science and Engineering, Wuhan Textile University, Wuhan, Hubei 430200, China
    More by Lang Jiang
  • Hongjun Yang
    Hongjun Yang
    State Key Laboratory of New Textile Materials & Advanced Processing Technologies,  School of Material Science and Engineering, Wuhan Textile University, Wuhan, Hubei 430200, China
    More by Hongjun Yang
  • Guizhen Ke
    Guizhen Ke
    State Key Laboratory of New Textile Materials & Advanced Processing Technologies, Wuhan Textile University, Wuhan, Hubei 430200, China
    More by Guizhen Ke
  • Genyang Cao
    Genyang Cao
    State Key Laboratory of New Textile Materials & Advanced Processing Technologies, Wuhan Textile University, Wuhan, Hubei 430200, China
    More by Genyang Cao
  • Bo Deng*
    Bo Deng
    State Key Laboratory of New Textile Materials & Advanced Processing Technologies, Wuhan Textile University, Wuhan, Hubei 430200, China
    *E-mail: [email protected] (B.D.).
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  • , and 
  • Weilin Xu*
    Weilin Xu
    State Key Laboratory of New Textile Materials & Advanced Processing Technologies, Wuhan Textile University, Wuhan, Hubei 430200, China
    *E-mail: [email protected] (W.X.).
    More by Weilin Xu
Cite this: ACS Appl. Mater. Interfaces 2018, 10, 25, 21056–21060
Publication Date (Web):May 9, 2018
https://doi.org/10.1021/acsami.8b03641
Copyright © 2018 American Chemical Society
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Abstract

A high IR-blocking cellulose film was designed based on an amorphous to anatase transition of TiO2 using atomic layer deposition (ALD). This transition was realized at 250 °C, at which the cellulose is thermal stable. Optimized ALD condition of 250 °C and 1200 cycles give us an excellent heat insulator, which could significantly reduce the enclosed space temperature from 59.2 to 51.9 °C after exposure to IR lamp for 5 min.

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The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsami.8b03641.

  • Thermogravimetric analysis of TiO2-coated cellulose films treated at different ALD cycles, denotation of samples treated by ALD TiO2 at different cycles and temperatures, representative ATR-FTIR spectra of cellulose films before and after ALD including the attributions of different FTIR peaks, XPS survey spectra of the cellulose films treated by ALD TiO2 at different cycles and temperatures, XPS spectra of the Ti2p peaks of the cellulose films treated by ALD TiO2 at different cycles and temperatures, SEM surface morphology of cellulose films, and device used to evaluate the heat insulating properties of TiO2-coated cellulose films (PDF)

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