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Ordered Mesoporous Cobalt Containing Perovskite as a High-Performance Heterogeneous Catalyst in Activation of Peroxymonosulfate

  • Xinsheng Luo
    Xinsheng Luo
    State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, China
    More by Xinsheng Luo
  • Langming Bai
    Langming Bai
    State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, China
    More by Langming Bai
  • Jiajian Xing
    Jiajian Xing
    State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, China
    More by Jiajian Xing
  • Xuewu Zhu
    Xuewu Zhu
    State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, China
    More by Xuewu Zhu
  • Daliang Xu
    Daliang Xu
    State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, China
    More by Daliang Xu
  • Binghan Xie
    Binghan Xie
    State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, China
    More by Binghan Xie
  • Zhendong Gan
    Zhendong Gan
    State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, China
    More by Zhendong Gan
  • Guibai Li
    Guibai Li
    State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, China
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  • , and 
  • Heng Liang*
    Heng Liang
    State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, China
    *E-mail: [email protected]. Phone: +86 451 86282252. Fax: +86 451 86282252.
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Cite this: ACS Appl. Mater. Interfaces 2019, 11, 39, 35720–35728
Publication Date (Web):September 5, 2019
https://doi.org/10.1021/acsami.9b11322
Copyright © 2019 American Chemical Society
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Abstract

An ordered mesoporous perovskite, La2CoMnO6−δ (MLCMO), was synthesized for the first time using a facile method of evaporation-induced self-assembly. The N2-sorption, scanning electron microscopy, and transmission electron microscopy measurements indicated that the optimized MLCMO possessed a high specific surface area (58.7 m2/g) and was uniformly mesoporous (11.6 nm). The MLCMO exhibited superior catalytic performance in peroxymonosulfate (PMS) activation for atrazine (ATZ) degradation. From a comparison view, the catalytic activity of the mesoporous MLCMO outperformed that of the bulk La2CoMnO6−δ (LCMO) and other common PMS activators, including α-MnO2, Co3O4, and CoFe2O4. The mechanisms of PMS activation by the MLCMO were investigated by X-ray photoelectron spectroscopy, electron spin resonance, and quenching tests. SO4•–, OH, 1O2, and O2•– were identified as main reactive oxygen species generated from PMS activation. The Co and Mn in MLCMO were the active sites responsible for active radical generation. The lattice oxygen reversible redox sites (OL/OL2–), which were involved in the electron transfer of the MnIII/MnIV cycle, were demonstrated as redox partners to the cation active sites. In addition, the SO4•–/OH radical conversion was promoted at pH 11, which accelerated the consumption of PMS and seriously inhibited the degradation of ATZ.

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The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsami.9b11322.

  • Crystallographic data (CIF)

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  • Information on preparation and characterization of catalysts; detailed information of the PEO-b-PS characterization; optimization of MLCMO preparation condition; micropollutant removal efficiency of MLCMO; the influences of reaction conditions on ATZ removal; the influences of external water conditions on ATZ removal; and reusability investigation of MLCMO (PDF)

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