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Strong Oxide–Support Interactions Accelerate Selective Dehydrogenation of Propane by Modulating the Surface Oxygen

  • Hai Wang
    Hai Wang
    Key Lab of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
    More by Hai Wang
  • Hang Zhou
    Hang Zhou
    Key Lab of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
    More by Hang Zhou
  • Shuqiang Li
    Shuqiang Li
    Key Laboratory of Cluster Science of Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China
    More by Shuqiang Li
  • Xin Ge
    Xin Ge
    Key Laboratory of Automobile Materials MOE, School of Materials Science & Engineering, Electron Microscopy Center, and International Center of Future Science, Jilin University, Changchun 130012, China
    More by Xin Ge
  • Liang Wang*
    Liang Wang
    Key Lab of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
    *Email: [email protected]
    More by Liang Wang
  • Zhu Jin
    Zhu Jin
    Key Lab of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University, Hangzhou 310028, China
    More by Zhu Jin
  • Chengtao Wang
    Chengtao Wang
    Key Lab of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University, Hangzhou 310028, China
  • Jiabi Ma*
    Jiabi Ma
    Key Laboratory of Cluster Science of Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China
    *Email: [email protected]
    More by Jiabi Ma
  • Xuefeng Chu
    Xuefeng Chu
    Key Laboratory of Architectural Cold Climate Energy Management, Ministry of Education, Jilin Jianzhu University, Changchun 130118, China
    More by Xuefeng Chu
  • Xiangju Meng
    Xiangju Meng
    Key Lab of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University, Hangzhou 310028, China
    More by Xiangju Meng
  • Wei Zhang*
    Wei Zhang
    Key Laboratory of Automobile Materials MOE, School of Materials Science & Engineering, Electron Microscopy Center, and International Center of Future Science, Jilin University, Changchun 130012, China
    Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, China
    IKERBASQUE, Basque Foundation for Science, Bilbao 48013, Spain
    *Email: [email protected]
    More by Wei Zhang
  • , and 
  • Feng-Shou Xiao*
    Feng-Shou Xiao
    Key Lab of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
    Key Lab of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University, Hangzhou 310028, China
    *Email: [email protected]
Cite this: ACS Catal. 2020, 10, 18, 10559–10569
Publication Date (Web):August 21, 2020
https://doi.org/10.1021/acscatal.0c02782
Copyright © 2020 American Chemical Society
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Abstract

The catalytic selectivity of supported catalysts can be tuned by the appropriate design of synthesis strategies and catalyst structures. We provide a persuasive strategy to turn manganese oxide from a combustion catalyst into a selective catalyst for oxidative dehydrogenation of propane (ODHP). This success is achieved by anchoring amorphous manganese oxide with thin-layer morphology on a ceria support via constructing strong oxide–support interactions (SOSIs). Multiple structure and mechanism investigations demonstrate that the SOSI forms active interfacial oxygen sites for propane activation and oxygen-deficient manganese oxide to stabilize propene and hinder overoxidation under the ODHP conditions. These features boost the ODHP to exhibit simultaneously high activity and propene selectivity, outperforming the general manganese oxide catalysts and even the practically promising vanadium catalysts. This research work deepens remarkably the structure–performance relationship understanding of metal oxide catalysts in ODHP.

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  • Additional characterization data, XRD patterns; TEM images; XPS; catalytic data; TPR; IR; Raman; and MS data (PDF)

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Cited By


This article is cited by 6 publications.

  1. Beibei Sheng, Dengfeng Cao, Chongjing Liu, Shuangming Chen, Li Song. Support Effects in Electrocatalysis and Their Synchrotron Radiation-Based Characterizations. The Journal of Physical Chemistry Letters 2021, 12 (47) , 11543-11554. https://doi.org/10.1021/acs.jpclett.1c02805
  2. Hai Wang, Qingsong Luo, Liang Wang, Yu Hui, Yucai Qin, Lijuan Song, Feng-Shou Xiao. Product selectivity controlled by manganese oxide crystals in catalytic ammoxidation. Chinese Journal of Catalysis 2021, 42 (12) , 2164-2172. https://doi.org/10.1016/S1872-2067(21)63803-2
  3. Daniyal Kiani, Sagar Sourav, Israel E. Wachs, Jonas Baltrusaitis. A combined computational and experimental study of methane activation during oxidative coupling of methane (OCM) by surface metal oxide catalysts. Chemical Science 2021, 12 (42) , 14143-14158. https://doi.org/10.1039/D1SC02174E
  4. Zhi Hu, Zidan Zou, Aidi Xie, Chun Chen, Xiaoguang Zhu, Yunxia Zhang, Haimin Zhang, Huijun Zhao, Guozhong Wang. Crystal plane effect of ceria on supported copper catalyst for liquid-phase hydrogenation of unsaturated aldehyde. Journal of Colloid and Interface Science 2021, 596 , 34-43. https://doi.org/10.1016/j.jcis.2021.03.137
  5. Xinquan Shen, Dan Wu, Xian-Zhu Fu, Jing-Li Luo. Highly selective conversion of methane to ethanol over CuFe2O4-carbon nanotube catalysts at low temperature. Chinese Chemical Letters 2021, 2 https://doi.org/10.1016/j.cclet.2021.07.019
  6. Jiaxin Wen, Haiwei Guo, Xu He, Xi Tong, Peng Gao, Qixuan Dong, Gengbo Ren, Xiaodong Ma. Morphology-engineering enhanced catalytic performance improvement of Fe-Ca-O /TiO2 for 1,2-dichlorobenzene oxidation. Applied Catalysis A: General 2021, 613 , 118030. https://doi.org/10.1016/j.apcata.2021.118030