Low-Voltage Electrolytic Hydrogen Production Derived from Efficient Water and Ethanol Oxidation on Fluorine-Modified FeOOH Anode

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School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China
*E-mail for L.X.D.: [email protected]
*E-mail for H.H.W.: [email protected]
Cite this: ACS Catal. 2018, 8, 1, 526–530
Publication Date (Web):December 8, 2017
https://doi.org/10.1021/acscatal.7b03319
Copyright © 2017 American Chemical Society
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Abstract

Highly active, earth-abundant anode catalysts are urgently required for the development of electrolytic devices for hydrogen generation. However, the reaction efficiencies of most developed electrocatalysts have been intrinsically limited due to their insufficient adsorption of reactants leading to high energy intermediates. Here, we establish that electronegative fluorine can moderate the binding energy between the Fe sites (FeOOH) and reactants (OH or C2H5O), resulting in more optimized adsorption, and can enhance the positive charge densities on the Fe sites to facilitate oxygen evolution reaction (OER) and ethanol oxidation. Consequently, a low electrolytic voltage (1.43 V to achieve 10 mA cm–2) for H2 production was obtained by integrating the efficiently anodic behaviors of OER and ethanol oxidation. The results reported herein point to fluorine moderation as a promising pathway for developing optimal electrocatalysts and contribute to ongoing efforts of mimicking water splitting.

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  • Detailed experimental procedures; supported physical characterizations by SEM, XRD, TEM, XPS, and ICP-MS; electrochemical characterizations by CV, LSV, current–potential curves, and EIS; additional DFT calculations results; gas chromatography and NMR results (PDF)

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