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Oxygen Evolution Activity on NiOOH Catalysts: Four-Coordinated Ni Cation as the Active Site and the Hydroperoxide Mechanism

  • Li-Fen Li
    Li-Fen Li
    Collaborative Innovation Center of Chemistry for Energy Material, Key Laboratory of Computational Physical Science (Ministry of Education), Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433, China
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  • Ye-Fei Li*
    Ye-Fei Li
    Collaborative Innovation Center of Chemistry for Energy Material, Key Laboratory of Computational Physical Science (Ministry of Education), Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433, China
    *E-mail: [email protected] (Y.-F.L.).
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  • , and 
  • Zhi-Pan Liu*
    Zhi-Pan Liu
    Collaborative Innovation Center of Chemistry for Energy Material, Key Laboratory of Computational Physical Science (Ministry of Education), Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433, China
    *E-mail: [email protected] (Z.-P.L.).
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Cite this: ACS Catal. 2020, 10, 4, 2581–2590
Publication Date (Web):January 24, 2020
https://doi.org/10.1021/acscatal.9b04975
Copyright © 2020 American Chemical Society
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Abstract

The NiOOH catalyst as obtained dynamically from electrodeposition of Ni2+(aq) in the borate-containing electrolyte was observed to exhibit much higher oxygen evolution activity at a near-neutral pH range (7–9) compared to other NiOx-based materials. Here, we demonstrate that this intriguing high activity is owing to the high concentration of Ni cationic vacancy on the nascent ultra-small NiOOH particles (<3 nm). By using first-principles calculations, we compute the thermodynamics of Ni dissolution and clarify the mechanism of oxygen evolution reaction (OER) on the γ-NiOOH surface. We show that (i) ∼4% Ni cations on the surface of γ-NiOOH dissolve at pH = 7 and 1.73 V versus reversible hydrogen electrode; (ii) on the pristine γ-NiOOH surface, OER proceeds via the “lattice peroxide” mechanism (*H2O → *OH → *O–OlattH* → O–Olatt → O2) with an overpotential of 0.70 V; (iii) in the presence of Ni cationic vacancies, OER proceeds via the “hydroperoxide” mechanism (*OH + *H2O → *2OH → *OOH → O2) with an overpotential of 0.40 V. Our electronic structure and geometrical structure analyses demonstrate that the structural flexibility at the four-coordinated Ni site nearby Ni vacancy, featuring the ability to bind two terminal oxo species, is key to boost the activity. Considering the presence of the active OOH intermediate, our theory thus implies that the ultra-small oxide nanoclusters with ample cation vacancies could be a paradigm in catalyst design for oxidation reactions.

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  • Calculation details for the CHE approach; calculation details for the formation free energy of Ni vacancy; crystal structures for γ-NiOOH; surface energies of γ-NiOOH; and OER profiles on β-NiOOH (PDF)

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