Deactivation in Homogeneous Transition Metal Catalysis: Causes, Avoidance, and Cure

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Department of Chemistry, Yale University, 225 Prospect Street, New Haven, Connecticut 06520-8107, United States
Cite this: Chem. Rev. 2015, 115, 1, 127–150
Publication Date (Web):December 10, 2014
Copyright © 2014 American Chemical Society
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  19. Pengpeng Zhang, David Huang, Timothy R. Newhouse. Aryl-Nickel-Catalyzed Benzylic Dehydrogenation of Electron-Deficient Heteroarenes. Journal of the American Chemical Society 2020, 142 (4) , 1757-1762.
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  21. Julia J. Jennings, Benjamin W. Wigman, Brittany M. Armstrong, Annaliese K. Franz. NMR Quantification of the Effects of Ligands and Counterions on Lewis Acid Catalysis. The Journal of Organic Chemistry 2019, 84 (24) , 15845-15853.
  22. Stephanie J. Ton, Deryn E. Fogg. The Impact of Oxygen on Leading and Emerging Ru-Carbene Catalysts for Olefin Metathesis: An Unanticipated Correlation Between Robustness and Metathesis Activity. ACS Catalysis 2019, 9 (12) , 11329-11334.
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  24. David Huang, Diego Olivieri, Yang Sun, Pengpeng Zhang, Timothy R. Newhouse. Nickel-Catalyzed Difunctionalization of Unactivated Alkenes Initiated by Unstabilized Enolates. Journal of the American Chemical Society 2019, 141 (41) , 16249-16254.
  25. Robert H. Crabtree. Transfer Hydrogenation with Glycerol as H-Donor: Catalyst Activation, Deactivation and Homogeneity. ACS Sustainable Chemistry & Engineering 2019, 7 (19) , 15845-15853.
  26. Rafal M. Dziedzic, Jonathan C. Axtell, Arnold L. Rheingold, Alexander M. Spokoyny. Off-Cycle Processes in Pd-Catalyzed Cross-Coupling of Carboranes. Organic Process Research & Development 2019, 23 (8) , 1638-1645.
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  28. J. M. Dreimann, E. Kohls, H. F. W. Warmeling, M. Stein, L. F. Guo, M. Garland, T. N. Dinh, A. J. Vorholt. In Situ Infrared Spectroscopy as a Tool for Monitoring Molecular Catalyst for Hydroformylation in Continuous Processes. ACS Catalysis 2019, 9 (5) , 4308-4319.
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  30. Tao Zhang, Hong-Cheng Shen, Jia-Cheng Xu, Tao Fan, Zhi-Yong Han, Liu-Zhu Gong. Pd(II)-Catalyzed Asymmetric Oxidative Annulation of N-Alkoxyheteroaryl Amides and 1,3-Dienes. Organic Letters 2019, 21 (7) , 2048-2051.
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  35. Konstantinos D. Vogiatzis, Mikhail V. Polynski, Justin K. Kirkland, Jacob Townsend, Ali Hashemi, Chong Liu, Evgeny A. Pidko. Computational Approach to Molecular Catalysis by 3d Transition Metals: Challenges and Opportunities. Chemical Reviews 2019, 119 (4) , 2453-2523.
  36. Juan J. Moreno, María F. Espada, Jesús Campos, Joaquín López-Serrano, Stuart A. Macgregor, Ernesto Carmona. Base-Promoted, Remote C–H Activation at a Cationic (η5-C5Me5)Ir(III) Center Involving Reversible C–C Bond Formation of Bound C5Me5. Journal of the American Chemical Society 2019, 141 (6) , 2205-2210.
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  38. Stephanie A. Rufh, Alexandre Y. Goudreault, Marco Foscato, Vidar R. Jensen, Deryn E. Fogg. Rapid Decomposition of Olefin Metathesis Catalysts by a Truncated N-Heterocyclic Carbene: Efficient Catalyst Quenching and N-Heterocyclic Carbene Vinylation. ACS Catalysis 2018, 8 (12) , 11822-11826.
  39. Francesco Zaccaria, Cristiano Zuccaccia, Roberta Cipullo, Peter H. M. Budzelaar, Alceo Macchioni, Vincenzo Busico, Christian Ehm. Toluene and α-Olefins as Radical Scavengers: Direct NMR Evidence for Homolytic Chain Transfer Mechanism Leading to Benzyl and “Dormant” Titanium Allyl Complexes. Organometallics 2018, 37 (22) , 4189-4194.
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  42. Tasha Drake, Pengfei Ji, Wenbin Lin. Site Isolation in Metal–Organic Frameworks Enables Novel Transition Metal Catalysis. Accounts of Chemical Research 2018, 51 (9) , 2129-2138.
  43. Olga N. Gorunova, Ivan M. Novitskiy, Yuri K. Grishin, Igor P. Gloriozov, Vitaly A. Roznyatovsky, Victor N. Khrustalev, Konstantin A. Kochetkov, Valery V. Dunina. When Applying the Mercury Poisoning Test to Palladacycle-Catalyzed Reactions, One Should Not Consider the Common Misconception of Mercury(0) Selectivity. Organometallics 2018, 37 (17) , 2842-2858.
  44. Francesco Zaccaria, Christian Ehm, Peter H. M. Budzelaar, Vincenzo Busico, Roberta Cipullo. Catalyst Mileage in Olefin Polymerization: The Peculiar Role of Toluene. Organometallics 2018, 37 (17) , 2872-2879.
  45. Ba L. Tran, John L. Fulton, John C. Linehan, Johannes A. Lercher, R. Morris Bullock. Rh(CAAC)-Catalyzed Arene Hydrogenation: Evidence for Nanocatalysis and Sterically Controlled Site-Selective Hydrogenation. ACS Catalysis 2018, 8 (9) , 8441-8449.
  46. Eric C. Keske, Thomas H. West, Guy C. Lloyd-Jones. Analysis of Autoinduction, Inhibition, and Autoinhibition in a Rh-Catalyzed C–C Cleavage: Mechanism of Decyanative Aryl Silylation. ACS Catalysis 2018, 8 (9) , 8932-8940.
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  48. Ping Wang, Guangchao Liang, M. Ramana Reddy, Melissa Long, Kandria Driskill, Christian Lyons, Bruno Donnadieu, John C. Bollinger, Charles Edwin Webster, Xuan Zhao. Electronic and Steric Tuning of Catalytic H2 Evolution by Cobalt Complexes with Pentadentate Polypyridyl-Amine Ligands. Journal of the American Chemical Society 2018, 140 (29) , 9219-9229.
  49. Lillian V. A. Hale, Nathaniel K. Szymczak. Hydrogen Transfer Catalysis beyond the Primary Coordination Sphere. ACS Catalysis 2018, 8 (7) , 6446-6461.
  50. Mohammad Mehdi Haghdoost, Juliette Guard, Golara Golbaghi, Annie Castonguay. Anticancer Activity and Catalytic Potential of Ruthenium(II)–Arene Complexes with N,O-Donor Ligands. Inorganic Chemistry 2018, 57 (13) , 7558-7567.
  51. Dwaipayan Ghosh, Benny Febriansyah, Disha Gupta, Leonard Kia-Sheun Ng, Shibo Xi, Yonghua Du, Tom Baikie, ZhiLi Dong, Han Sen Soo. Hybrid Nanomaterials with Single-Site Catalysts by Spatially Controllable Immobilization of Nickel Complexes via Photoclick Chemistry for Alkene Epoxidation. ACS Nano 2018, 12 (6) , 5903-5912.
  52. Péter Pál Fehér, Henrietta Horváth, Ferenc Joó, Mihály Purgel. DFT Study on the Mechanism of Hydrogen Storage Based on the Formate-Bicarbonate Equilibrium Catalyzed by an Ir-NHC Complex: An Elusive Intramolecular C–H Activation. Inorganic Chemistry 2018, 57 (10) , 5903-5914.
  53. Hannah Rothfuss, Nicolai D. Knöfel, Peter W. Roesky, Christopher Barner-Kowollik. Single-Chain Nanoparticles as Catalytic Nanoreactors. Journal of the American Chemical Society 2018, 140 (18) , 5875-5881.
  54. Ambikesh D. Dwivedi, Vinod K. Sahu, Shaikh M. Mobin, Sanjay K. Singh. Cyclopentadienyl–Ru(II)–Pyridylamine Complexes: Synthesis, X-ray Structure, and Application in Catalytic Transformation of Bio-Derived Furans to Levulinic Acid and Diketones in Water. Inorganic Chemistry 2018, 57 (8) , 4777-4787.
  55. David Balcells, Ainara Nova. Designing Pd and Ni Catalysts for Cross-Coupling Reactions by Minimizing Off-Cycle Species. ACS Catalysis 2018, 8 (4) , 3499-3515.
  56. Gwendolyn A. Bailey, Justin A. M. Lummiss, Marco Foscato, Giovanni Occhipinti, Robert McDonald, Vidar R. Jensen, and Deryn E. Fogg . Decomposition of Olefin Metathesis Catalysts by Brønsted Base: Metallacyclobutane Deprotonation as a Primary Deactivating Event. Journal of the American Chemical Society 2017, 139 (46) , 16446-16449.
  57. Matthew R. Mills, Longzhu Q. Shen, David Z. Zhang, Alexander D. Ryabov, and Terrence J. Collins . Iron(III) Ejection from a “Beheaded” TAML Activator: Catalytically Relevant Mechanistic Insight into the Deceleration of Electrophilic Processes by Electron Donors. Inorganic Chemistry 2017, 56 (17) , 10226-10234.
  58. Alan J. Reay, L. Anders Hammarback, Joshua T. W. Bray, Thomas Sheridan, David Turnbull, Adrian C. Whitwood, and Ian J. S. Fairlamb . Mild and Regioselective Pd(OAc)2-Catalyzed C–H Arylation of Tryptophans by [ArN2]X, Promoted by Tosic Acid. ACS Catalysis 2017, 7 (8) , 5174-5179.
  59. Lili Zhao, Yi Wang, Ziling Ma, and Yuanhua Wang . Dirhodium(II)-Catalyzed Carbonylation Peroxidation of α,β-Unsaturated Esters: Mechanistic Insight into the Role of Aryl Aldehydes. Inorganic Chemistry 2017, 56 (14) , 8166-8174.
  60. Robert H. Crabtree . Homogeneous Transition Metal Catalysis of Acceptorless Dehydrogenative Alcohol Oxidation: Applications in Hydrogen Storage and to Heterocycle Synthesis. Chemical Reviews 2017, 117 (13) , 9228-9246.
  61. Qi Sun, Zhifeng Dai, Xiangju Meng, and Feng-Shou Xiao . Homochiral Porous Framework as a Platform for Durability Enhancement of Molecular Catalysts. Chemistry of Materials 2017, 29 (13) , 5720-5726.
  62. Thoe K. Michaelos, Dimitar Y. Shopov, Shashi Bhushan Sinha, Liam S. Sharninghausen, Katherine J. Fisher, Hannah M. C. Lant, Robert H. Crabtree, and Gary W. Brudvig . A Pyridine Alkoxide Chelate Ligand That Promotes Both Unusually High Oxidation States and Water-Oxidation Catalysis. Accounts of Chemical Research 2017, 50 (4) , 952-959.
  63. Gellért Sipos, Pengchao Gao, Daven Foster, Brian W. Skelton, Alexandre N. Sobolev, and Reto Dorta . In-Depth Study on Chloride Abstractions from (NHC)Ir(COD)Cl Complexes. Organometallics 2017, 36 (4) , 801-817.
  64. Francesco Zaccaria, Christian Ehm, Peter H. M. Budzelaar, and Vincenzo Busico . Accurate Prediction of Copolymerization Statistics in Molecular Olefin Polymerization Catalysis: The Role of Entropic, Electronic, and Steric Effects in Catalyst Comonomer Affinity. ACS Catalysis 2017, 7 (2) , 1512-1519.
  65. Liang L. Tang, Matthew A. DeNardo, Christopher J. Schuler, Matthew R. Mills, Chakicherla Gayathri, Roberto R. Gil, Rakesh Kanda, and Terrence J. Collins . Homogeneous Catalysis Under Ultradilute Conditions: TAML/NaClO Oxidation of Persistent Metaldehyde. Journal of the American Chemical Society 2017, 139 (2) , 879-887.
  66. Augustin A. S. W. Tchawou, Mihai Raducan, and Peter Chen . Mechanism-Based Design and Optimization of a Catalytic Electrophilic Cyclopropanation without Diazomethane. Organometallics 2017, 36 (1) , 180-191.
  67. Matthew R. Mills, Andrew C. Weitz, David Z. Zhang, Michael P. Hendrich, Alexander D. Ryabov, and Terrence J. Collins . A “Beheaded” TAML Activator: A Compromised Catalyst that Emphasizes the Linearity between Catalytic Activity and pKa. Inorganic Chemistry 2016, 55 (23) , 12263-12269.
  68. Devi Prasan Ojha, Karthik Gadde, and Kandikere Ramaiah Prabhu . Generation of Hydrogen from Water: A Pd-Catalyzed Reduction of Water Using Diboron Reagent at Ambient Conditions. Organic Letters 2016, 18 (19) , 5062-5065.
  69. Artur Chołuj, Adam Zieliński, Karol Grela, and Michał J. Chmielewski . [email protected]: Simple and Robust Immobilization of Olefin Metathesis Catalysts inside (Al)MIL-101-NH2. ACS Catalysis 2016, 6 (10) , 6343-6349.
  70. Jose Ángel Pino-Chamorro, Yuliya A. Laricheva, Eva Guillamón, M. Jesús Fernández-Trujillo, Andrés G. Algarra, Artem L. Gushchin, Pavel A. Abramov, Emilio Bustelo, Rosa Llusar, Maxim N. Sokolov, and Manuel G. Basallote . Kinetics Aspects of the Reversible Assembly of Copper in Heterometallic Mo3CuS4 Clusters with 4,4′-Di-tert-butyl-2,2′-bipyridine. Inorganic Chemistry 2016, 55 (19) , 9912-9922.
  71. Timothy P. Brewster, Jonathan M. Goldberg, Jeremy C. Tran, D. Michael Heinekey, and Karen I. Goldberg . High Catalytic Efficiency Combined with High Selectivity for the Aldehyde–Water Shift Reaction using (para-cymene)Ruthenium Precatalysts. ACS Catalysis 2016, 6 (9) , 6302-6305.
  72. David Balcells, Eric Clot, Odile Eisenstein, Ainara Nova, and Lionel Perrin . Deciphering Selectivity in Organic Reactions: A Multifaceted Problem. Accounts of Chemical Research 2016, 49 (5) , 1070-1078.
  73. Matthew A. DeNardo, Matthew R. Mills, Alexander D. Ryabov, and Terrence J. Collins . Unifying Evaluation of the Technical Performances of Iron-Tetra-amido Macrocyclic Ligand Oxidation Catalysts. Journal of the American Chemical Society 2016, 138 (9) , 2933-2936.
  74. Iva Stibingerova, Svatava Voltrova, Sarka Kocova, Matthew Lindale, and Jiri Srogl . Modular Approach to Heterogenous Catalysis. Manipulation of Cross-Coupling Catalyst Activity. Organic Letters 2016, 18 (2) , 312-315.
  75. James D. Blakemore, Robert H. Crabtree, and Gary W. Brudvig . Molecular Catalysts for Water Oxidation. Chemical Reviews 2015, 115 (23) , 12974-13005.
  76. Franz Ölscher, Inigo Göttker-Schnetmann, Vincent Monteil, and Stefan Mecking . Role of Radical Species in Salicylaldiminato Ni(II) Mediated Polymer Chain Growth: A Case Study for the Migratory Insertion Polymerization of Ethylene in the Presence of Methyl Methacrylate. Journal of the American Chemical Society 2015, 137 (46) , 14819-14828.
  77. Travis A. White, Suzanne E. Witt, Zhanyong Li, Kim R. Dunbar, and Claudia Turro . New Rh2(II,II) Architecture for the Catalytic Reduction of H+. Inorganic Chemistry 2015, 54 (20) , 10042-10048.
  78. Olivier René, Iain A. Stepek, Alberto Gobbi, Benjamin P. Fauber, and Simon Gaines . Palladium-Catalyzed Ring Expansion of Spirocyclopropanes to Form Caprolactams and Azepanes. The Journal of Organic Chemistry 2015, 80 (20) , 10218-10225.
  79. Simone A. Hauser, Ralf Tonner, and Adrian B. Chaplin . Iridium Complexes of the Conformationally Rigid IBioxMe4 Ligand: Hydride Complexes and Dehydrogenation of Cyclooctene. Organometallics 2015, 34 (17) , 4419-4427.
  80. Benjamin J. Ireland, Bernadette T. Dobigny, and Deryn E. Fogg . Decomposition of a Phosphine-Free Metathesis Catalyst by Amines and Other Bronsted Bases: Metallacyclobutane Deprotonation as a Major Deactivation Pathway. ACS Catalysis 2015, 5 (8) , 4690-4698.
  81. Pablo Garrido-Barros, Ignacio Funes-Ardoiz, Samuel Drouet, Jordi Benet-Buchholz, Feliu Maseras, and Antoni Llobet . Redox Non-innocent Ligand Controls Water Oxidation Overpotential in a New Family of Mononuclear Cu-Based Efficient Catalysts. Journal of the American Chemical Society 2015, 137 (21) , 6758-6761.
  82. Daniel Weiliang Tay, Howard Jong, Yee Hwee Lim, Wenqin Wu, Xinying Chew, Edward G. Robins, and Charles W. Johannes . Palladium-meta-Terarylphosphine Catalyst for the Mizoroki–Heck Reaction of (Hetero)Aryl Bromides and Functional Olefins. The Journal of Organic Chemistry 2015, 80 (8) , 4054-4063.
  83. Hannah Mallalieu Rogers, Travis A. White, Brittany N. Stone, Shamindri M. Arachchige, and Karen J. Brewer . Nonchromophoric Halide Ligand Variation in Polyazine-Bridged Ru(II),Rh(III) Bimetallic Supramolecules Offering New Insight into Photocatalytic Hydrogen Production from Water. Inorganic Chemistry 2015, 54 (7) , 3545-3551.
  84. Grant J. Sherborne, Michael R. Chapman, A. John Blacker, Richard A. Bourne, Thomas W. Chamberlain, Benjamin D. Crossley, Stephanie J. Lucas, Patrick C. McGowan, Mark A. Newton, Thomas E. O Screen, Paul Thompson, Charlotte E. Willans, and Bao N. Nguyen . Activation and Deactivation of a Robust Immobilized Cp*Ir-Transfer Hydrogenation Catalyst: A Multielement in Situ X-ray Absorption Spectroscopy Study. Journal of the American Chemical Society 2015, 137 (12) , 4151-4157.
  85. Imtiyaz Yousuf, Masrat Bashir, Farukh Arjmand, Sartaj Tabassum. Advancement of metal compounds as therapeutic and diagnostic metallodrugs: Current frontiers and future perspectives. Coordination Chemistry Reviews 2021, 445 , 214104.
  86. Juan José Moreno, María F. Espada, Celia Maya, Jesús Campos, Joaquín López-Serrano, Stuart A. Macgregor, Ernesto Carmona. Isomerization of a cationic (η5-C5Me5)Ir(III) complex involving remote C–C and C–H bond formation. Polyhedron 2021, 207 , 115363.
  87. Rana Deeba, Sylvie Chardon‐Noblat, Cyrille Costentin. Molecular Catalysis of Electrochemical Reactions: Competition between Reduction of the Substrate and Deactivation of the Catalyst by a Cosubstrate Application to N 2 O Reduction. ChemElectroChem 2021, 8 (19) , 3740-3744.
  88. Gina Noh, Michele L. Sarazen. Transport in heterogeneous catalysis – Beyond reactant diffusion limitations. Journal of Catalysis 2021, 18
  89. Gongfang Hu, Robert H. Crabtree, Gary W. Brudvig. Organometallic complexes as preferred precursors to form molecular Ir(pyalk) coordination complexes for catalysis of oxygen evolution. Inorganica Chimica Acta 2021, 526 , 120507.
  90. Hannes Westphal, Rico Warias, Holger Becker, Matthias Spanka, Daniele Ragno, Roger Gläser, Christoph Schneider, Alessandro Massi, Detlev Belder. Unveiling Organocatalysts Action – Investigating Immobilized Catalysts at Steady‐State Operation via Lab‐on‐a‐Chip Technology. ChemCatChem 2021, 376
  91. Andrey Yu. Chernenko, Alexander V. Astakhov, Vadim V. Kutyrev, Evgeniy G. Gordeev, Julia V. Burykina, Mikhail E. Minyaev, Victor N. Khrustalev, Victor M. Chernyshev, Valentine P. Ananikov. Stabilization of the Pd–NHC framework with 1,2,4-triazol-5-ylidene ligands toward decomposition in alkaline media. Inorganic Chemistry Frontiers 2021, 8 (13) , 3382-3401.
  92. Victor M. Chernyshev, Oleg V. Khazipov, Dmitry B. Eremin, Ekaterina A. Denisova, Valentine P. Ananikov. Formation and stabilization of nanosized Pd particles in catalytic systems: Ionic nitrogen compounds as catalytic promoters and stabilizers of nanoparticles. Coordination Chemistry Reviews 2021, 437 , 213860.
  93. Le Thi Hoa, Le Thi Thanh Nhi, Le Van Thanh Sơn, Nguyen Le My Linh, Ho Van Minh Hai, Dinh Quang Khieu, . Single-Atom Ni Heterogeneous Catalysts Supported UiO-66 Structure: Synthesis and Catalytic Activities. Journal of Nanomaterials 2021, 2021 , 1-16.
  94. Jongho So, Seji Kim, Kyung-Bin Cho, Yunho Lee. Metal–ligand cooperative transformation of alkyl azide to isocyanate occurring at a Co–Si moiety. Chemical Communications 2021, 57 (26) , 3219-3222.
  95. Patrick Wilde, Peter B. O'Mara, João R. C. Junqueira, Tsvetan Tarnev, Tania M. Benedetti, Corina Andronescu, Yen-Ting Chen, Richard D. Tilley, Wolfgang Schuhmann, J. Justin Gooding. Is Cu instability during the CO 2 reduction reaction governed by the applied potential or the local CO concentration?. Chemical Science 2021, 12 (11) , 4028-4033.
  96. Xiao‐Jing Zhao, Zi‐Hao Li, Tong‐Mei Ding, Jin‐Miao Tian, Yong‐Qiang Tu, Ai‐Fang Wang, Yu‐Yang Xie. Enantioselective Synthesis of 3,3′‐Disubstituted 2‐Amino‐2′‐hydroxy‐1,1′‐binaphthyls by Copper‐Catalyzed Aerobic Oxidative Cross‐Coupling. Angewandte Chemie International Edition 2021, 60 (13) , 7061-7065.
  97. Xiao‐Jing Zhao, Zi‐Hao Li, Tong‐Mei Ding, Jin‐Miao Tian, Yong‐Qiang Tu, Ai‐Fang Wang, Yu‐Yang Xie. Enantioselective Synthesis of 3,3′‐Disubstituted 2‐Amino‐2′‐hydroxy‐1,1′‐binaphthyls by Copper‐Catalyzed Aerobic Oxidative Cross‐Coupling. Angewandte Chemie 2021, 133 (13) , 7137-7141.
  98. Guozhu Zhang, Takuro Hosomi, Wataru Mizukami, Jiangyang Liu, Kazuki Nagashima, Tsunaki Takahashi, Masaki Kanai, Takeharu Sugiyama, Takao Yasui, Yuriko Aoki, Yoshinobu Baba, Johnny C. Ho, Takeshi Yanagida. A thermally robust and strongly oxidizing surface of WO 3 hydrate nanowires for electrical aldehyde sensing with long-term stability. Journal of Materials Chemistry A 2021, 9 (9) , 5815-5824.
  99. Mohammad Usman, Rais Ahmad Khan, Mohammad Rashid Khan, Mohammad Abul Farah, Ibtisam I. BinSharfan, Walaa Alharbi, Jilani. P. Shaik, Narasimha Reddy Parine, Ali Alsalme, Sartaj Tabassum. A novel biocompatible formate bridged 1D-Cu( ii ) coordination polymer induces apoptosis selectively in human lung adenocarcinoma (A549) cells. Dalton Transactions 2021, 50 (6) , 2253-2267.
  100. Arne Merschel, Timo Glodde, Beate Neumann, Hans‐Georg Stammler, Rajendra S. Ghadwal. Nickel‐katalysierte intramolekulare 1,2‐Aryl‐Wanderung von mesoionischen Carbenen (iMICs). Angewandte Chemie 2021, 133 (6) , 3006-3010.
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