Oxidation of Chlorinated Ethenes by Heat-Activated Persulfate:  Kinetics and Products

View Author Information
Department of Environmental and Biomolecular Systems, Oregon Health & Science University, 20000 NW Walker Road, Portland, Oregon 97006
Cite this: Environ. Sci. Technol. 2007, 41, 3, 1010–1015
Publication Date (Web):December 15, 2006
https://doi.org/10.1021/es062237m
Copyright © 2007 American Chemical Society
Article Views
4745
Altmetric
-
Citations
LEARN ABOUT THESE METRICS
Read OnlinePDF (191 KB)
Supporting Info (1)»

Abstract

In situ chemical oxidation (ISCO) and in situ thermal remediation (ISTR) are applicable to treatment of groundwater contaminated with chlorinated ethenes. ISCO with persulfate (S2O82-) requires activation, and this can be achieved with the heat from ISTR, so there may be advantages to combining these technologies. To explore this possibility, we determined the kinetics and products of chlorinated ethene oxidation with heat-activated persulfate and compared them to the temperature dependence of other degradation pathways. The kinetics of chlorinated ethene disappearance were pseudo-first-order for 1−2 half-lives, and the resulting rate constantsmeasured from 30 to 70 °Cfit the Arrhenius equation, yielding apparent activation energies of 101 ± 4 kJ mol-1 for tetrachloroethene (PCE), 108 ± 3 kJ mol-1 for trichloroethene (TCE), 144 ± 5 kJ mol-1 for cis-1,2-dichloroethene (cis-DCE), and 141 ± 2 kJ mol-1 for trans-1,2-dichloroethene (trans-DCE). Chlorinated byproducts were observed, but most of the parent material was completely dechlorinated. Arrhenius parameters for hydrolysis and oxidation by persulfate or permanganate were used to calculate rates of chlorinated ethene degradation by these processes over the range of temperatures relevant to ISTR and the range of oxidant concentrations and pH relevant to ISCO.

*

 Corresponding author phone:  (503)748-1023; fax:  (503)748-1273; e-mail:  [email protected]

Supporting Information Available

ARTICLE SECTIONS
Jump To

Two tables (details on experimental conditions and results) and seven figures (further validation of our results). This material is available free of charge via the Internet at http://pubs.acs.org.

Terms & Conditions

Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

Cited By


This article is cited by 479 publications.

  1. Jean Van Buren, Amy A. Cuthbertson, Daniel Ocasio, David L. Sedlak. Ubiquitous Production of Organosulfates during Treatment of Organic Contaminants with Sulfate Radicals. Environmental Science & Technology Letters 2021, 8 (7) , 574-580. https://doi.org/10.1021/acs.estlett.1c00316
  2. Rong Chen, Tianqi Zhang, Juhee Kim, Huan Peng, Miaomiao Ye, Ching-Hua Huang. Interfacial Solar Distillation for Freshwater Production: Fate of Volatile and Semivolatile Organic Contaminants. Environmental Science & Technology 2021, 55 (9) , 6248-6256. https://doi.org/10.1021/acs.est.0c07191
  3. Moshan Chen, Carter A. Rholl, Tianchen He, Aditi Sharma, Kimberly M. Parker. Halogen Radicals Contribute to the Halogenation and Degradation of Chemical Additives Used in Hydraulic Fracturing. Environmental Science & Technology 2021, 55 (3) , 1545-1554. https://doi.org/10.1021/acs.est.0c03685
  4. Yongguang Bu, Hongchao Li, Wenjing Yu, Yifan Pan, Lijun Li, Yanfeng Wang, Liangtao Pu, Jie Ding, Guandao Gao, Bingcai Pan. Peroxydisulfate Activation and Singlet Oxygen Generation by Oxygen Vacancy for Degradation of Contaminants. Environmental Science & Technology 2021, 55 (3) , 2110-2120. https://doi.org/10.1021/acs.est.0c07274
  5. Jingwen Wang, Ying Wan, Jiaqi Ding, Zongping Wang, Jun Ma, Pengchao Xie, Mark R. Wiesner. Thermal Activation of Peracetic Acid in Aquatic Solution: The Mechanism and Application to Degrade Sulfamethoxazole. Environmental Science & Technology 2020, 54 (22) , 14635-14645. https://doi.org/10.1021/acs.est.0c02061
  6. Tao Luo, Ying Peng, Long Chen, Jinjun Li, Feng Wu, Danna Zhou. Metal-Free Electro-Activated Sulfite Process for As(III) Oxidation in Water Using Graphite Electrodes. Environmental Science & Technology 2020, 54 (16) , 10261-10269. https://doi.org/10.1021/acs.est.9b07078
  7. Xueying Yang, Jingsheng Cai, Xiaoning Wang, Yifan Li, Zhangxiong Wu, Winston Duo Wu, Xiao Dong Chen, Jingyu Sun, Sheng-Peng Sun, Zhaohui Wang. A Bimetallic Fe–Mn Oxide-Activated Oxone for In Situ Chemical Oxidation (ISCO) of Trichloroethylene in Groundwater: Efficiency, Sustained Activity, and Mechanism Investigation. Environmental Science & Technology 2020, 54 (6) , 3714-3724. https://doi.org/10.1021/acs.est.0c00151
  8. Klara Rusevova Crincoli, Constance Green, Scott G. Huling. Sulfate Radical Scavenging by Mineral Surfaces in Persulfate-Driven Oxidation Systems: Reaction Rate Constants and Implications. Environmental Science & Technology 2020, 54 (3) , 1955-1962. https://doi.org/10.1021/acs.est.9b06442
  9. Silvio Canonica, Ursula Schönenberger. Inhibitory Effect of Dissolved Organic Matter on the Transformation of Selected Anilines and Sulfonamide Antibiotics Induced by the Sulfate Radical. Environmental Science & Technology 2019, 53 (20) , 11783-11791. https://doi.org/10.1021/acs.est.9b04105
  10. Chaoting Guan, Jin Jiang, Yongming Shen, Suyan Pang, Congwei Luo, Xi Zhao. Carbon Materials Inhibit Formation of Nitrated Aromatic Products in Treatment of Phenolic Compounds by Thermal Activation of Peroxydisulfate in the Presence of Nitrite. Environmental Science & Technology 2019, 53 (15) , 9054-9062. https://doi.org/10.1021/acs.est.9b01354
  11. Limin Hu, Guangshan Zhang, Qiao Wang, Xiaojing Wang, Peng Wang. Effect of Microwave Heating on Persulfate Activation for Rapid Degradation and Mineralization of p-Nitrophenol. ACS Sustainable Chemistry & Engineering 2019, 7 (13) , 11662-11671. https://doi.org/10.1021/acssuschemeng.9b01686
  12. Jonghun Lim, Yang Yang, Michael R. Hoffmann. Activation of Peroxymonosulfate by Oxygen Vacancies-Enriched Cobalt-Doped Black TiO2 Nanotubes for the Removal of Organic Pollutants. Environmental Science & Technology 2019, 53 (12) , 6972-6980. https://doi.org/10.1021/acs.est.9b01449
  13. Yue Li, Roya Baghi, Jan Filip, Syful Islam, Louisa Hope-weeks, Weile Yan. Activation of Peroxydisulfate by Ferrite Materials for Phenol Degradation. ACS Sustainable Chemistry & Engineering 2019, 7 (9) , 8099-8108. https://doi.org/10.1021/acssuschemeng.8b05257
  14. Weizhen Liu, Jiayi Zheng, Xinwen Ou, Xueming Liu, Yao Song, Chen Tian, Wencong Rong, Zhenqing Shi, Zhi Dang, Zhang Lin. Effective Extraction of Cr(VI) from Hazardous Gypsum Sludge via Controlling the Phase Transformation and Chromium Species. Environmental Science & Technology 2018, 52 (22) , 13336-13342. https://doi.org/10.1021/acs.est.8b02213
  15. Shishu Zhu, Xiaochen Huang, Fang Ma, Li Wang, Xiaoguang Duan, Shaobin Wang. Catalytic Removal of Aqueous Contaminants on N-Doped Graphitic Biochars: Inherent Roles of Adsorption and Nonradical Mechanisms. Environmental Science & Technology 2018, 52 (15) , 8649-8658. https://doi.org/10.1021/acs.est.8b01817
  16. Shiqing Zhou, Yanghai Yu, Weiqiu Zhang, Xiaoyang Meng, Jinming Luo, Lin Deng, Zhou Shi, John Crittenden. Oxidation of Microcystin-LR via Activation of Peroxymonosulfate Using Ascorbic Acid: Kinetic Modeling and Toxicity Assessment. Environmental Science & Technology 2018, 52 (7) , 4305-4312. https://doi.org/10.1021/acs.est.7b06560
  17. Jiabin Chen, Cong Fang, Wenjun Xia, Tianyin Huang, and Ching-Hua Huang . Selective Transformation of β-Lactam Antibiotics by Peroxymonosulfate: Reaction Kinetics and Nonradical Mechanism. Environmental Science & Technology 2018, 52 (3) , 1461-1470. https://doi.org/10.1021/acs.est.7b05543
  18. Ahmed I. A. Chowdhury, Jason I. Gerhard, David Reynolds, and Denis M. O’Carroll . Low Permeability Zone Remediation via Oxidant Delivered by Electrokinetics and Activated by Electrical Resistance Heating: Proof of Concept. Environmental Science & Technology 2017, 51 (22) , 13295-13303. https://doi.org/10.1021/acs.est.7b02231
  19. Clara Torrentó, Jordi Palau, Diana Rodríguez-Fernández, Benjamin Heckel, Armin Meyer, Cristina Domènech, Mònica Rosell, Albert Soler, Martin Elsner, and Daniel Hunkeler . Carbon and Chlorine Isotope Fractionation Patterns Associated with Different Engineered Chloroform Transformation Reactions. Environmental Science & Technology 2017, 51 (11) , 6174-6184. https://doi.org/10.1021/acs.est.7b00679
  20. Dawit N. Wordofa, Sharon L. Walker, and Haizhou Liu . Sulfate Radical-Induced Disinfection of Pathogenic Escherichia coli O157:H7 via Iron-Activated Persulfate. Environmental Science & Technology Letters 2017, 4 (4) , 154-160. https://doi.org/10.1021/acs.estlett.7b00035
  21. Hongshin Lee, Hyoung-il Kim, Seunghyun Weon, Wonyong Choi, Yu Sik Hwang, Jiwon Seo, Changha Lee, and Jae-Hong Kim . Activation of Persulfates by Graphitized Nanodiamonds for Removal of Organic Compounds. Environmental Science & Technology 2016, 50 (18) , 10134-10142. https://doi.org/10.1021/acs.est.6b02079
  22. Wenjie Tian, Huayang Zhang, Xiaoguang Duan, Hongqi Sun, Moses O. Tade, Ha Ming Ang, and Shaobin Wang . Nitrogen- and Sulfur-Codoped Hierarchically Porous Carbon for Adsorptive and Oxidative Removal of Pharmaceutical Contaminants. ACS Applied Materials & Interfaces 2016, 8 (11) , 7184-7193. https://doi.org/10.1021/acsami.6b01748
  23. Yanlin Wu, Angelica Bianco, Marcello Brigante, Wenbo Dong, Pascal de Sainte-Claire, Khalil Hanna, and Gilles Mailhot . Sulfate Radical Photogeneration Using Fe-EDDS: Influence of Critical Parameters and Naturally Occurring Scavengers. Environmental Science & Technology 2015, 49 (24) , 14343-14349. https://doi.org/10.1021/acs.est.5b03316
  24. Xiaobo Wang, Yanlei Qin, Lihua Zhu, and Heqing Tang . Nitrogen-Doped Reduced Graphene Oxide as a Bifunctional Material for Removing Bisphenols: Synergistic Effect between Adsorption and Catalysis. Environmental Science & Technology 2015, 49 (11) , 6855-6864. https://doi.org/10.1021/acs.est.5b01059
  25. Guodong Fang, Cun Liu, Juan Gao, Dionysios D. Dionysiou, and Dongmei Zhou . Manipulation of Persistent Free Radicals in Biochar To Activate Persulfate for Contaminant Degradation. Environmental Science & Technology 2015, 49 (9) , 5645-5653. https://doi.org/10.1021/es5061512
  26. Jordi Palau, Orfan Shouakar-Stash, and Daniel Hunkeler . Carbon and Chlorine Isotope Analysis to Identify Abiotic Degradation Pathways of 1,1,1-Trichloroethane. Environmental Science & Technology 2014, 48 (24) , 14400-14408. https://doi.org/10.1021/es504252z
  27. Yi Zhao, Runlong Hao, Peng Zhang, and Sihan Zhou . Integrative Process for Simultaneous Removal of SO2 and NO Utilizing a Vaporized H2O2/Na2S2O8. Energy & Fuels 2014, 28 (10) , 6502-6510. https://doi.org/10.1021/ef501686j
  28. Haizhou Liu, Thomas A. Bruton, Fiona M. Doyle, and David L. Sedlak . In Situ Chemical Oxidation of Contaminated Groundwater by Persulfate: Decomposition by Fe(III)- and Mn(IV)-Containing Oxides and Aquifer Materials. Environmental Science & Technology 2014, 48 (17) , 10330-10336. https://doi.org/10.1021/es502056d
  29. Hongshin Lee, Ha-Young Yoo, Jihyun Choi, In-Hyun Nam, Sanghyup Lee, Seunghak Lee, Jae-Hong Kim, Changha Lee, and Jaesang Lee . Oxidizing Capacity of Periodate Activated with Iron-Based Bimetallic Nanoparticles. Environmental Science & Technology 2014, 48 (14) , 8086-8093. https://doi.org/10.1021/es5002902
  30. Yi Zhao and Runlong Hao . Macrokinetics of Hg0 Removal by a Vaporized Multicomponent Oxidant. Industrial & Engineering Chemistry Research 2014, 53 (27) , 10899-10905. https://doi.org/10.1021/ie5009376
  31. Tao Zhang, Yin Chen, Yuru Wang, Julien Le Roux, Yang Yang, and Jean-Philippe Croué . Efficient Peroxydisulfate Activation Process Not Relying on Sulfate Radical Generation for Water Pollutant Degradation. Environmental Science & Technology 2014, 48 (10) , 5868-5875. https://doi.org/10.1021/es501218f
  32. Songhu Yuan, Peng Liao, and Akram N. Alshawabkeh . Electrolytic Manipulation of Persulfate Reactivity by Iron Electrodes for Trichloroethylene Degradation in Groundwater. Environmental Science & Technology 2014, 48 (1) , 656-663. https://doi.org/10.1021/es404535q
  33. Jing Zou, Jun Ma, Liwei Chen, Xuchun Li, Yinghong Guan, Pengchao Xie, and Chao Pan . Rapid Acceleration of Ferrous Iron/Peroxymonosulfate Oxidation of Organic Pollutants by Promoting Fe(III)/Fe(II) Cycle with Hydroxylamine. Environmental Science & Technology 2013, 47 (20) , 11685-11691. https://doi.org/10.1021/es4019145
  34. Samyoung Ahn, Tawnya D. Peterson, Jason Righter, Danielle M. Miles, and Paul G. Tratnyek . Disinfection of Ballast Water with Iron Activated Persulfate. Environmental Science & Technology 2013, 47 (20) , 11717-11725. https://doi.org/10.1021/es402508k
  35. Tao Zhang, Haibo Zhu, and Jean-Philippe Croué . Production of Sulfate Radical from Peroxymonosulfate Induced by a Magnetically Separable CuFe2O4 Spinel in Water: Efficiency, Stability, and Mechanism. Environmental Science & Technology 2013, 47 (6) , 2784-2791. https://doi.org/10.1021/es304721g
  36. Jing-Yun Fang and Chii Shang . Bromate Formation from Bromide Oxidation by the UV/Persulfate Process. Environmental Science & Technology 2012, 46 (16) , 8976-8983. https://doi.org/10.1021/es300658u
  37. Hans F. Stroo, Andrea Leeson, Jeffrey A. Marqusee, Paul C. Johnson, C. Herb Ward, Michael C. Kavanaugh, Tom C. Sale, Charles J. Newell, Kurt D. Pennell, Carmen A. Lebrón, and Marvin Unger . Chlorinated Ethene Source Remediation: Lessons Learned. Environmental Science & Technology 2012, 46 (12) , 6438-6447. https://doi.org/10.1021/es204714w
  38. Xiaogang Gu, Shuguang Lu, Zhaofu Qiu, Qian Sui, Zhouwei Miao, Kuangfei Lin, Yongdi Liu, and Qishi Luo . Comparison of Photodegradation Performance of 1,1,1-Trichloroethane in Aqueous Solution with the Addition of H2O2 or S2O82– Oxidants. Industrial & Engineering Chemistry Research 2012, 51 (21) , 7196-7204. https://doi.org/10.1021/ie202769d
  39. Cecil K. King’ondu, Naftali N. Opembe, Homer C. Genuino, Hector F. Garces, Eric C. Njagi, Aparna Iyer, Hui Huang, Saminda Dharmarathna, and Steven L. Suib . Nonthermal Synthesis of Three-Dimensional Metal Oxide Structures under Continuous-Flow Conditions and Their Catalytic Applications. The Journal of Physical Chemistry C 2011, 115 (47) , 23273-23282. https://doi.org/10.1021/jp206942u
  40. Ying-Hong Guan, Jun Ma, Xu-Chun Li, Jing-Yun Fang, and Li-Wei Chen . Influence of pH on the Formation of Sulfate and Hydroxyl Radicals in the UV/Peroxymonosulfate System. Environmental Science & Technology 2011, 45 (21) , 9308-9314. https://doi.org/10.1021/es2017363
  41. Xiaogang Gu, Shuguang Lu, Lin Li, Zhaofu Qiu, Qian Sui, Kuangfei Lin, and Qishi Luo . Oxidation of 1,1,1-Trichloroethane Stimulated by Thermally Activated Persulfate. Industrial & Engineering Chemistry Research 2011, 50 (19) , 11029-11036. https://doi.org/10.1021/ie201059x
  42. Paweł Adamczyk, Agnieszka Dybala-Defratyka, and Piotr Paneth . DFT Study of Trichloroethene Reaction with Permanganate in Aqueous Solution. Environmental Science & Technology 2011, 45 (7) , 3006-3011. https://doi.org/10.1021/es103251u
  43. Stephen D. Richardson, Benjamin L. Lebron, Cass T. Miller, and Michael D. Aitken. Recovery of Phenanthrene-Degrading Bacteria after Simulated in Situ Persulfate Oxidation in Contaminated Soil. Environmental Science & Technology 2011, 45 (2) , 719-725. https://doi.org/10.1021/es102420r
  44. Stephen P. Mezyk Kimberly A. Rickman Garrett McKay Charlotte M. Hirsch Xuexiang He Dionysios D. Dionysiou . Remediation of Chemically-Contaminated Waters Using Sulfate Radical Reactions: Kinetic Studies. 2011,,, 247-263. https://doi.org/10.1021/bk-2011-1071.ch012
  45. Jed Costanza, Gretell Otaño, John Callaghan, and Kurt D. Pennell. PCE Oxidation by Sodium Persulfate in the Presence of Solids. Environmental Science & Technology 2010, 44 (24) , 9445-9450. https://doi.org/10.1021/es100997a
  46. Chenju Liang and Hsin-Wey Su. Identification of Sulfate and Hydroxyl Radicals in Thermally Activated Persulfate. Industrial & Engineering Chemistry Research 2009, 48 (11) , 5558-5562. https://doi.org/10.1021/ie9002848
  47. Chenju Liang and, Clifford J. Bruell. Thermally Activated Persulfate Oxidation of Trichloroethylene:  Experimental Investigation of Reaction Orders. Industrial & Engineering Chemistry Research 2008, 47 (9) , 2912-2918. https://doi.org/10.1021/ie070820l
  48. Rifeng Wu, Shanquan Wang. Integration of microbial reductive dehalogenation with persulfate activation and oxidation (Bio-RD-PAO) for complete attenuation of organohalides. Frontiers of Environmental Science & Engineering 2022, 16 (2) https://doi.org/10.1007/s11783-021-1457-8
  49. Qiao Wang, Zetao Xu, Yiting Cao, Yuanqing Chen, Xing Du, Yang Yang, Zhihong Wang. Two-dimensional ultrathin perforated Co3O4 nanosheets enhanced PMS-Activated selective oxidation of organic micropollutants in environmental remediation. Chemical Engineering Journal 2022, 427 , 131953. https://doi.org/10.1016/j.cej.2021.131953
  50. Haradhan Kolya, Chun-Won Kang. Oxidation treatment on wood cell walls affects gas permeability and sound absorption capacity. Carbohydrate Polymers 2022, 276 , 118874. https://doi.org/10.1016/j.carbpol.2021.118874
  51. Mohamed Faisal Gasim, Jun-Wei Lim, Siew-Chun Low, Kun-Yi Andrew Lin, Wen-Da Oh. Can biochar and hydrochar be used as sustainable catalyst for persulfate activation?. Chemosphere 2022, 287 , 132458. https://doi.org/10.1016/j.chemosphere.2021.132458
  52. Mengxin Li, Chao Liu, Zhao Zhang, Shihai Cao, Hao Liu, Shigang Shen, Wenjing Wang. Ultrathin Cu-Fe oxide nanosheets boosting persulfate activation to remove organic pollutants with coupling and transformation between radical and nonradical mechanism. Separation and Purification Technology 2022, 281 , 119978. https://doi.org/10.1016/j.seppur.2021.119978
  53. Xixi Wu, Teng Li, Ruizi Wang, Yixuan Zhang, Wenzhe Liu, Liangjie Yuan. One-pot green synthesis of Zero-Valent iron particles supported on N-Doped porous carbon for efficient removal of organic pollutants via Persulfate Activation: Low iron leaching and degradation mechanism. Separation and Purification Technology 2021, 279 , 119768. https://doi.org/10.1016/j.seppur.2021.119768
  54. Hyeonseok Kang, Donghyun Lee, Ki-Myeong Lee, Hak-Hyeon Kim, Hongshin Lee, Min Sik Kim, Changha Lee. Nonradical activation of peroxymonosulfate by hematite for oxidation of organic compounds: A novel mechanism involving high-valent iron species. Chemical Engineering Journal 2021, 426 , 130743. https://doi.org/10.1016/j.cej.2021.130743
  55. Linhai Yang, Xuechang Ren, Yujie Zhang, Zuoyan Chen. Heterogeneous activation of peroxymonosulfate by Cu+-decorated g-C3N4 under sunlight for degradation of organic pollutants. Journal of Environmental Chemical Engineering 2021, 9 (6) , 106596. https://doi.org/10.1016/j.jece.2021.106596
  56. Hang Li, Yan-Ling Yang, Xing Li, Xiao-Yan Fan, Nan Wang. Enhanced degradation mechanism of sulfamethazine by vacuum ultraviolet/persulfate. Journal of Environmental Chemical Engineering 2021, 9 (6) , 106489. https://doi.org/10.1016/j.jece.2021.106489
  57. Pradip Saha, Yicheng Wang, Mahsa Moradi, Robert Brüninghoff, Gholamreza Moussavi, Bastian Mei, Guido Mul, Huub H. M. Rijnaarts, Harry Bruning. Advanced oxidation processes for removal of organics from cooling tower blowdown: Efficiencies and evaluation of chlorinated species. Separation and Purification Technology 2021, 278 , 119537. https://doi.org/10.1016/j.seppur.2021.119537
  58. Chien-Yu Chen, Yi-Chin Cho, Yi-Pin Lin. Activation of peroxydisulfate by carbon nanotube for the degradation of 2,4-dichlorophenol: Contributions of surface-bound radicals and direct electron transfer. Chemosphere 2021, 283 , 131282. https://doi.org/10.1016/j.chemosphere.2021.131282
  59. Yang Deng, Nan Chen, Weiwu Hu, Haishuang Wang, Peijing Kuang, Fangxin Chen, Chuanping Feng. Treatment of old landfill leachate by persulfate enhanced electro-coagulation system: Improving organic matters removal and precipitates settling performance. Chemical Engineering Journal 2021, 424 , 130262. https://doi.org/10.1016/j.cej.2021.130262
  60. Xiaoyan Ma, Liangjie Tang, Jing Deng, Zhanghua Liu, Xueyan Li, Peng Wang, Qingsong Li. Removal of saccharin by UV/persulfate process: Degradation kinetics, mechanism and DBPs formation. Journal of Photochemistry and Photobiology A: Chemistry 2021, 420 , 113482. https://doi.org/10.1016/j.jphotochem.2021.113482
  61. Sarah Sühnholz, Alina Gawel, Frank-Dieter Kopinke, Katrin Mackenzie. Evidence of heterogeneous degradation of PFOA by activated persulfate – FeS as adsorber and activator. Chemical Engineering Journal 2021, 423 , 130102. https://doi.org/10.1016/j.cej.2021.130102
  62. Quantao Cui, Wei Zhang, Senyou Chai, Qiting Zuo, Ki-Hyun Kim. The potential of green biochar generated from biogas residue as a heterogeneous persulfate activator and its non-radical degradation pathways: Adsorption and degradation of tetracycline. Environmental Research 2021, 55 , 112335. https://doi.org/10.1016/j.envres.2021.112335
  63. Shumeng Liu, Yucheng Liu, Mingyan Chen, Lingli Li, Wenwen Tu, Zhi Huang. CuFe2O4 modified expanded graphite synthesized by urea-assisted hydrothermal method for tetracycline treatment through persulfate activation: Characterization, mechanism and degradation intermediates. Chemical Engineering Journal 2021, 545 , 133516. https://doi.org/10.1016/j.cej.2021.133516
  64. Cheolyong Kim, Torsten C. Schmidt, Holger V. Lutze. Oxidation of bromide by heat-activated persulfate – Effects of temperature and the organic matter surrogate phenol on kinetics and stoichiometry. Chemical Engineering Journal 2021, 385 , 133533. https://doi.org/10.1016/j.cej.2021.133533
  65. Xiang Liu, Wenxin Hou, Yu Huang, Haiyu Zhao, Zan Song, Yingping Huang. Facile and green synthesis of carbon nanopinnacles for the removal of chlortetracycline: performance, mechanism and biotoxicity. Chemical Engineering Journal 2021, 50 , 133822. https://doi.org/10.1016/j.cej.2021.133822
  66. Jiaxiang Ma, Ying Xu, Feiyun Sun, Xiaodong Chen, Wei Wang. Perspective for removing volatile organic compounds during solar‐driven water evaporation toward water production. EcoMat 2021, 9 https://doi.org/10.1002/eom2.12147
  67. Xiaohui Fan, Heng Lin, Jinjin Zhao, Yican Mao, Jiaxing Zhang, Hui Zhang. Activation of peroxymonosulfate by sewage sludge biochar-based catalyst for efficient removal of bisphenol A: Performance and mechanism. Separation and Purification Technology 2021, 272 , 118909. https://doi.org/10.1016/j.seppur.2021.118909
  68. Yerkanat N. Kanafin, Ardak Makhatova, Vasilios Zarikas, Elizabeth Arkhangelsky, Stavros G. Poulopoulos. Photo-Fenton-Like Treatment of Municipal Wastewater. Catalysts 2021, 11 (10) , 1206. https://doi.org/10.3390/catal11101206
  69. Manoj P. Rayaroth, Charuvila T. Aravindakumar, Noor S. Shah, Grzegorz Boczkaj. Advanced oxidation processes (AOPs) based wastewater treatment - unexpected nitration side reactions - a serious environmental issue: A review. Chemical Engineering Journal 2021, 333 , 133002. https://doi.org/10.1016/j.cej.2021.133002
  70. Marko G. Popadić, Sanja R. Marinović, Tihana M. Mudrinić, Aleksandra D. Milutinović-Nikolić, Predrag T. Banković, Ivana S. Đorđević, Goran V. Janjić. A novel approach in revealing mechanisms and particular step predictors of pH dependent tartrazine catalytic degradation in presence of Oxone®. Chemosphere 2021, 281 , 130806. https://doi.org/10.1016/j.chemosphere.2021.130806
  71. Yafeng Liang, Xuejiao Tang, Qing Zhu, Jianhua Han, Cuiping Wang. A review: Application of tourmaline in environmental fields. Chemosphere 2021, 281 , 130780. https://doi.org/10.1016/j.chemosphere.2021.130780
  72. Tao Luo, Jing Xu, Jinjun Li, Feng Wu, Danna Zhou. Strengthening arsenite oxidation in water using metal-free ultrasonic activation of sulfite. Chemosphere 2021, 281 , 130860. https://doi.org/10.1016/j.chemosphere.2021.130860
  73. Guanyi Chen, Guanyun Wu, Ning Li, Xukai Lu, Jianhui Zhao, Mengting He, Beibei Yan, Hongqiong Zhang, Xiaoguang Duan, Shaobin Wang. Landfill leachate treatment by persulphate related advanced oxidation technologies. Journal of Hazardous Materials 2021, 418 , 126355. https://doi.org/10.1016/j.jhazmat.2021.126355
  74. Ning Min, Jun Yao, Meseret Amde, Cengceng Tang, Langping Wu, Hans Hermann Richnow, Yafei Chen, Yongqiang Cui, Hao Li. Compound specific isotope analysis to characterize degradation mechanisms of p-chloroaniline by persulfate at ambient temperature. Chemical Engineering Journal 2021, 419 , 129526. https://doi.org/10.1016/j.cej.2021.129526
  75. Jiaqi Shi, Tao Long, Yuxuan Zhou, Lei Wang, Cuiping Jiang, Dongguo Pan, Xin Zhu. Efficiency and Quantitative Structure-Activity Relationship of Monoaromatics Oxidation by Quinone-Activated Persulfate. Frontiers in Chemistry 2021, 9 https://doi.org/10.3389/fchem.2021.580643
  76. Alicia Checa-Fernández, Aurora Santos, Arturo Romero, Carmen M. Domínguez. Remediation of real soil polluted with hexachlorocyclohexanes (α-HCH and β-HCH) using combined thermal and alkaline activation of persulfate: Optimization of the operating conditions. Separation and Purification Technology 2021, 270 , 118795. https://doi.org/10.1016/j.seppur.2021.118795
  77. Daniele Silvestri, Kamil Krawczyk, Mirosława Pawlyta, Maciej Krzywiecki, Vinod V.T. Padil, Rafael Torres-Mendieta, Farshid Ghanbari, Ozge Dinc, Miroslav Černík, Dionysios D. Dionysiou, Stanisław Wacławek. Influence of catalyst zeta potential on the activation of persulfate. Chemical Communications 2021, 57 (63) , 7814-7817. https://doi.org/10.1039/D1CC01946E
  78. Muhammad Bilal Asif, William E. Price, Zulqarnain Fida, Arbab Tufail, Ting Ren, Faisal I. Hai. Acid mine drainage and sewage impacted groundwater treatment by membrane distillation: Organic micropollutant and metal removal and membrane fouling. Journal of Environmental Management 2021, 291 , 112708. https://doi.org/10.1016/j.jenvman.2021.112708
  79. Likun Huang, Zhe Li, Guangzhi Wang, Wenli Zhao, Yuanyuan Xu, Dongdong Wang. Experimental study on advanced treatment of landfill leachate by ultraviolet catalytic persulfate. Environmental Technology & Innovation 2021, 23 , 101794. https://doi.org/10.1016/j.eti.2021.101794
  80. Fuwei Sun, Tianhu Chen, Haibo Liu, Xuehua Zou, Peixun Zhai, Ziyang Chu, Daobing Shu, Hanlin Wang, Dong Chen. The pH-dependent degradation of sulfadiazine using natural siderite activating PDS: The role of singlet oxygen. Science of The Total Environment 2021, 784 , 147117. https://doi.org/10.1016/j.scitotenv.2021.147117
  81. Kirill Fedorov, Xun Sun, Grzegorz Boczkaj. Combination of hydrodynamic cavitation and SR-AOPs for simultaneous degradation of BTEX in water. Chemical Engineering Journal 2021, 417 , 128081. https://doi.org/10.1016/j.cej.2020.128081
  82. Carmen M. Dominguez, Alicia Checa-Fernandez, Arturo Romero, Aurora Santos. Degradation of HCHs by thermally activated persulfate in soil system: Effect of temperature and oxidant concentration. Journal of Environmental Chemical Engineering 2021, 9 (4) , 105668. https://doi.org/10.1016/j.jece.2021.105668
  83. Jingyao Huang, Muhammad Danish, Xiaogang Gu, Xihao Jiang, Meesam Ali, Ali Shan, Qian Sui, Shuguang Lyu. Mechanism of carbon tetrachloride reduction in Fe(II) activated percarbonate system in the environment of sodium dodecyl sulfate. Separation and Purification Technology 2021, 266 , 118549. https://doi.org/10.1016/j.seppur.2021.118549
  84. Ardie Septian, Alam Venugopal Narendra Kumar, Annamalai Sivasankar, Jiyeon Choi, Inseong Hwang, Won Sik Shin. Colloidal activated carbon as a highly efficient bifunctional catalyst for phenol degradation. Journal of Hazardous Materials 2021, 414 , 125474. https://doi.org/10.1016/j.jhazmat.2021.125474
  85. Xuemei Li, Xinlong Yan, Xiaoyan Hu, Rui Feng, Min Zhou, Liping Wang. Enhanced adsorption and catalytic peroxymonosulfate activation by metal-free N-doped carbon hollow spheres for water depollution. Journal of Colloid and Interface Science 2021, 591 , 184-192. https://doi.org/10.1016/j.jcis.2021.01.094
  86. Bihui Niu, Min Yu, Changduo Sun, Luhan Wang, Kun Zang, Xiaowen Hu, Lei Zhou, Yian Zheng. Open hollow structured Calotropis gigantea fiber activated persulfate for decomposition of perfluorooctanoic acid at room temperature. Separation and Purification Technology 2021, 264 , 118200. https://doi.org/10.1016/j.seppur.2020.118200
  87. Jianyuan Zhen, Shuoshuo Zhang, Xuming Zhuang, Shakeel Ahmad, Taeho Lee, Hongyu Si, Chengbo Cao, Shou-Qing Ni. Sulfate radicals based heterogeneous peroxymonosulfate system catalyzed by CuO-Fe3O4-Biochar nanocomposite for bisphenol A degradation. Journal of Water Process Engineering 2021, 41 , 102078. https://doi.org/10.1016/j.jwpe.2021.102078
  88. Huanxuan Li, Zongxiang Yang, Shun Lu, Liya Su, Chunhui Wang, Jingang Huang, Jie Zhou, Junhong Tang, Mingzhi Huang. Nano-porous bimetallic CuCo-MOF-74 with coordinatively unsaturated metal sites for peroxymonosulfate activation to eliminate organic pollutants: Performance and mechanism. Chemosphere 2021, 273 , 129643. https://doi.org/10.1016/j.chemosphere.2021.129643
  89. Shiqi Liu, Zichen Zhang, Fei Huang, Yongze Liu, Li Feng, Jin Jiang, Liqiu Zhang, Fei Qi, Chao Liu. Carbonized polyaniline activated peroxymonosulfate (PMS) for phenol degradation: Role of PMS adsorption and singlet oxygen generation. Applied Catalysis B: Environmental 2021, 286 , 119921. https://doi.org/10.1016/j.apcatb.2021.119921
  90. Lin Dai, Jiaxin Xu, Jinbin Lin, Lingbin Wu, Huahua Cai, Jing Zou, Jun Ma. Iodometric spectrophotometric determination of peroxydisulfate in hydroxylamine-involved AOPs: 15 min or 15 s for oxidative coloration?. Chemosphere 2021, 272 , 128577. https://doi.org/10.1016/j.chemosphere.2020.128577
  91. Chen Yu, Jingchun Tang, Ding Li, Yongsheng Chen. Green synthesized nanosilver-biochar photocatalyst for persulfate activation under visible-light illumination. Chemosphere 2021, 350 , 131237. https://doi.org/10.1016/j.chemosphere.2021.131237
  92. Ali Gholami, Fakhreddin Mousavinia. Eco-friendly approach for efficient catalytic degradation of organic dyes through peroxymonosulfate activated with pistachio shell-derived biochar and activated carbon. Environmental Technology 2021, 19 , 1-18. https://doi.org/10.1080/09593330.2021.1922510
  93. Wendong Liu, Changlong Li, Guanqing Ding, Guangbin Duan, Yuanyuan Jiang, Yizhong Lu. Highly efficient hydrogen peroxide electrosynthesis on oxidized carbon nanotubes by thermally activated-persulfate. Journal of Materiomics 2021, 8 https://doi.org/10.1016/j.jmat.2021.04.010
  94. Xingyun Hu, Feng Zhu, Linghao Kong, Xianjia Peng. Sulfate radical-based removal of chloride ion from strongly acidic wastewater: Kinetics and mechanism. Journal of Hazardous Materials 2021, 410 , 124540. https://doi.org/10.1016/j.jhazmat.2020.124540
  95. Wei Song, Ji Li, Caixia Fu, Zhuoyue Wang, Yuxin Zhou, Xiaolei Zhang, Jingxin Yang, Ke Wang, Yinghui Liu, Qi Song. Establishment of sulfate radical advanced oxidation process based on Fe2+/O2/dithionite for organic contaminants degradation. Chemical Engineering Journal 2021, 410 , 128204. https://doi.org/10.1016/j.cej.2020.128204
  96. Sijin Zuo, Xuming Jin, Xinwei Wang, Yunhao Lu, Qi Zhu, Jiangwei Wang, Weiping Liu, Yonghua Du, Juan Wang. Sandwich structure stabilized atomic Fe catalyst for highly efficient Fenton-like reaction at all pH values. Applied Catalysis B: Environmental 2021, 282 , 119551. https://doi.org/10.1016/j.apcatb.2020.119551
  97. Dongmei Ma, Yang Yang, Bingfeng Liu, Guojun Xie, Chuan Chen, Nanqi Ren, Defeng Xing. Zero-valent iron and biochar composite with high specific surface area via K2FeO4 fabrication enhances sulfadiazine removal by persulfate activation. Chemical Engineering Journal 2021, 408 , 127992. https://doi.org/10.1016/j.cej.2020.127992
  98. Xuerui Yang, Xue Cao, Li Zhang, Yanlin Wu, Lei Zhou, Guangli Xiu, Corinne Ferronato, Jean-Marc Chovelon. Sulfate radical-based oxidation of the aminopyralid and picloram herbicides: The role of amino group on pyridine ring. Journal of Hazardous Materials 2021, 405 , 124181. https://doi.org/10.1016/j.jhazmat.2020.124181
  99. Xiaoyan Ma, Zhanghua Liu, Yulong Yang, Lidan Zhu, Jing Deng, Sijia Lu, Xueyan Li, Andrea M. Dietrich. Aqueous degradation of artificial sweeteners saccharin and neotame by metal organic framework material. Science of The Total Environment 2021, 761 , 143181. https://doi.org/10.1016/j.scitotenv.2020.143181
  100. Yaoxin Shen, Bo Jiang, Yi Xing. Recent advances in the application of magnetic Fe3O4 nanomaterials for the removal of emerging contaminants. Environmental Science and Pollution Research 2021, 28 (7) , 7599-7620. https://doi.org/10.1007/s11356-020-11877-8
Load more citations