Facile Synthesis of Mn3O4–Reduced Graphene Oxide Hybrids for Catalytic Decomposition of Aqueous Organics

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School of Chemical Engineering, Hefei University of Technology, Hefei 230009, People’s Republic of China
Anhui Key Laboratory of Controllable Chemical Reaction & Material Chemical Engineering, Hefei 230009, China
§ Department of Chemical Engineering, Curtin University, G.P.O. Box U1987, Perth, WA 6845, Australia
*Tel.: +86 551 2901458 (Y.Y.); +61 8 9266 3776 (S.W.). Fax: +86 551 2901450 (Y.Y.); +61 8 9266 2681 (S.W.). E-mail: [email protected] (Y.Y.); [email protected] (S.W.).
Cite this: Ind. Eng. Chem. Res. 2013, 52, 10, 3637–3645
Publication Date (Web):January 25, 2013
https://doi.org/10.1021/ie303220x
Copyright © 2013 American Chemical Society
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Abstract

Mn3O4–reduced graphene oxide (rGO) hybrids were synthesized, and their catalytic performance in heterogeneous activation of peroxymonosulfate (PMS) to oxidize a target pollutant, Orange II, in aqueous solutions was investigated. The surface morphology and structure of the Mn3O4–rGO hybrids were characterized by field emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectroscopy (EDS), transmission electron microscopy (TEM), powder X-ray diffraction (XRD), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis (TGA). Through an in situ chemical deposition and reduction, Mn3O4–rGO hybrids with Mn3O4 nanoparticles at an average size of 29.2 nm were produced. The catalytic activity in Orange II oxidative decomposition was evaluated in view of the effects of various processes, pH, PMS concentration, Orange II concentration, and temperature. The combination of Mn3O4 nanoparticles with graphene sheets leads to a much higher catalytic activity than that of pure Mn3O4 or rGO. Graphene was found to play an important role in Mn3O4 dispersion and decomposition of Orange II. Typically, 30 mg/L of Orange II could be completely oxidized in 120 min at 25 °C and 0.05 g/L of Mn3O4–rGO hybrids, showing a promising application of the catalyst in the oxidative degradation of aqueous organic pollutants. The efficiency of Orange II decomposition increased with increasing temperature (25–55 °C), pH (4.0–11.0), and PMS dosage (0.25–1.5 g/L), but it decreased with increasing initial Orange II concentration (30–90 mg/L). Mn3O4–rGO hybrids exhibited stable performance without losing activity after four successive runs.

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