Self-Healing of Molecular Catalyst and Photosensitizer on Metal–Organic Framework: Robust Molecular System for Photocatalytic H2 Evolution from Water

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Center for Supramolecular Optoelectronic Materials, Department of Materials Science and Engineering, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 151-744, Korea
Cite this: J. Am. Chem. Soc. 2016, 138, 28, 8698–8701
Publication Date (Web):June 29, 2016
https://doi.org/10.1021/jacs.6b04552
Copyright © 2016 American Chemical Society
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Abstract

Inspired by self-repair mechanism of PSII in plants, we report a self-healing system which spontaneously repairs molecular catalyst and photosensitizer during photocatalytic H2 evolution. A bipyridine-embedded UiO-type metal–organic framework (MOF), namely Ptn_Ir_BUiO, which incorporated H2-evolving catalyst and photosensitizer, was synthesized and subject to photocatalytic H2 evolution reaction (HER). Impressively, HER with Pt0.1_Ir_BUiO showed very stable molecular photocatalysis without significant decrease in its activity and colloidal formation for 6.5 days at least; in the homogeneous counterpart, the molecular catalyst became a colloid just after 7.5 h. It was revealed that the arrangement of diimine sites which closely and densely surrounded the H2-evolving catalyst and photosensitizer in the MOF enabled such a highly efficient self-healing.

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