Surfactant-Assisted Synthesis, Characterizations, and Catalytic Oxidation Mechanisms of the Mesoporous MnOx−CeO2 and Pd/MnOx−CeO2 Catalysts Used for CO and C3H8 Oxidation

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Tianjin Key Laboratory of Applied Catalysis Science & Engineering, Department of Catalysis Science & Technology, School of Chemical Engineering & Technology, Tianjin University, Tianjin 300072, P. R. China
* Corresponding author. Phone/fax: +86-(0)22-2789-2275. E-mail: [email protected]
Cite this: J. Phys. Chem. C 2010, 114, 1, 468–477
Publication Date (Web):November 30, 2009
Copyright © 2009 American Chemical Society
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A series of mesoporous MnOx−CeO2 binary oxide catalysts with high specific surface areas were prepared by surfactant-assisted precipitation. The CO and C3H8 oxidation reactions were used as model reactions to evaluate their catalytic performance. The techniques of N2 adsorption/desorption, XRD, XPS, TPR, TPO, TPD, and in situ DRIFTS were employed for catalyst characterization. It is found that the activity for CO and C3H8 oxidation of the catalysts exhibits a volcano-type behavior with the increase of Mn content. The catalyst with a Mn/Ce ratio of 4/6, possessing a high specific surface area of 215 m2/g, exhibits the best catalytic activity, which is related not only to its highest reducibility and oxygen-activation ability, as revealed by TPR and TPO, but also to the formation of more active oxygen species on the MnOx−CeO2 interface as identified by TPD. After the addition of a small amount of Pd to the MnOx−CeO2 catalyst, its activity for CO oxidation is greatly enhanced, due to the acceleration of gas-phase oxygen activation and transferring via spillover. However, the activity for C3H8 oxidation is hardly promoted due to the different reaction pathways for CO and C3H8 oxidation. For CO oxidation, the gas-phase oxygen activated by Pd can directly react with the adsorbed CO to form CO2, while, for C3H8 oxidation, which takes place at a much higher temperature than CO oxidation, the C−H bond activation and cleavage may be mainly driven by the active oxygen species on the interface between MnOx and CeO2. The addition of Pd shows little effect on the active interface oxygen species, so no promotion upon C3H8 oxidation is observed.

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  2. Xueqian Wang, Ruonan Sun, Langlang Wang, Yibing Xie, Lei Tao, Yixing Ma, Ping Ning. Coupled Catalytic Oxidation–Reduction and Hydrolysis with Ce1Mn2 Catalysts for HCN and NO Removal. Energy & Fuels 2020, 34 (7) , 8543-8551.
  3. Lei Zhu, Shunlong Pan, Zhiying Liu, Ping Wei, Zhuyun Liu, Peng Yu, Yanhua Xu. Effect of Rare Earth Metal (RE = La, Pr, Nd, Y) Doping on Co–Ce Composite Oxide and Its Application in Catalytic Combustion of Chlorobenzene. Industrial & Engineering Chemistry Research 2020, 59 (13) , 5686-5698.
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  5. Ji Yang, Siyu Hu, Yarong Fang, Son Hoang, Li Li, Weiwei Yang, Zhenfeng Liang, Jian Wu, Jinpeng Hu, Wen Xiao, Chuanqi Pan, Zhu Luo, Jun Ding, Lizhi Zhang, Yanbing Guo. Oxygen Vacancy Promoted O2 Activation over Perovskite Oxide for Low-Temperature CO Oxidation. ACS Catalysis 2019, 9 (11) , 9751-9763.
  6. Guozhu Chen, Yong Wang, Yunwei Wei, Wei Zhao, Daowei Gao, Hongxiao Yang, Cuncheng Li. Successive Interfacial Reaction-Directed Synthesis of [email protected]@CeO2-MnO2 Environmental Catalyst with Sandwich Hollow Structure. ACS Applied Materials & Interfaces 2018, 10 (14) , 11595-11603.
  7. Tangkang Liu, Yanyan Yao, Longqing Wei, Zhangfu Shi, Liying Han, Haoxuan Yuan, Bin Li, Lihui Dong, Fan Wang, and Chuanzhi Sun . Preparation and Evaluation of Copper–Manganese Oxide as a High-Efficiency Catalyst for CO Oxidation and NO Reduction by CO. The Journal of Physical Chemistry C 2017, 121 (23) , 12757-12770.
  8. Jian Zhang, Yidan Cao, Chang-An Wang, and Rui Ran . Design and Preparation of MnO2/CeO2–MnO2 Double-Shelled Binary Oxide Hollow Spheres and Their Application in CO Oxidation. ACS Applied Materials & Interfaces 2016, 8 (13) , 8670-8677.
  9. Jhon Quiroz, Jean-Marc Giraudon, Antonella Gervasini, Christophe Dujardin, Christine Lancelot, Martine Trentesaux, and Jean-François Lamonier . Total Oxidation of Formaldehyde over MnOx-CeO2 Catalysts: The Effect of Acid Treatment. ACS Catalysis 2015, 5 (4) , 2260-2269.
  10. Yanli Wang, Xiaoxiao Li, Liang Zhan, Cui Li, Wenming Qiao, and Licheng Ling . Effect of SO2 on Activated Carbon Honeycomb Supported CeO2–MnOx Catalyst for NO Removal at Low Temperature. Industrial & Engineering Chemistry Research 2015, 54 (8) , 2274-2278.
  11. Nabanita Pal, Eun-Bum Cho, Dukjoon Kim, and Mietek Jaroniec . Mn-Doped Ordered Mesoporous Ceria–Silica Composites and Their Catalytic Properties toward Biofuel Production. The Journal of Physical Chemistry C 2014, 118 (29) , 15892-15901.
  12. Phornphimon Maitarad, Dengsong Zhang, Ruihua Gao, Liyi Shi, Hongrui Li, Lei Huang, Thanyada Rungrotmongkol, and Jianping Zhang . Combination of Experimental and Theoretical Investigations of MnOx/Ce0.9Zr0.1O2 Nanorods for Selective Catalytic Reduction of NO with Ammonia. The Journal of Physical Chemistry C 2013, 117 (19) , 9999-10006.
  13. Tong Zhang Darren Delai Sun . Hierarchical Hybrid K-OMS-2/TiO2 Nanofibrous Membrane for Water Treatment. 2013,,, 267-276.
  14. Yanli Wang, ChuanZhang Ge, Liang Zhan, Cui Li, Wenming Qiao, and Licheng Ling . MnOx–CeO2/Activated Carbon Honeycomb Catalyst for Selective Catalytic Reduction of NO with NH3 at Low Temperatures. Industrial & Engineering Chemistry Research 2012, 51 (36) , 11667-11673.
  15. Shuoyi Feng, Jiadong Liu, Bo Gao. Synergistic mechanism of Cu-Mn-Ce oxides in mesoporous ceramic base catalyst for VOCs microwave catalytic combustion. Chemical Engineering Journal 2022, 429 , 132302.
  16. Yinghao Xue, Wei Teng, Yanyan Chen, Qian Ma, Xiaoqian Chen, Yu Sun, Jianwei Fan, Yuping Qiu, Rongbing Fu. Amorphous Mn-La oxides immobilized on carbon sphere for efficient removal of As(Ⅴ), Cd(Ⅱ), and Pb(Ⅱ): Co-adsorption and roles of Mn species. Chemical Engineering Journal 2022, 429 , 132262.
  17. Alessandra Palella, Lorenzo Spadaro, Roberto Di Chio, Francesco Arena. Effective low-temperature catalytic methane oxidation over MnCeOx catalytic compositions. Catalysis Today 2021, 379 , 240-249.
  18. Moataz Morad, Mohammad A. Karim, Hatem M. Altass, Abd El Rahman S. Khder. Microwave-assisted synthesis of gold nanoparticles supported on Mn 3 O 4 catalyst for low temperature CO oxidation. Environmental Technology 2021, 42 (17) , 2680-2689.
  19. Fei-Xiang Tian, Minghui Zhu, Xianglin Liu, Weifeng Tu, Yi-Fan Han. Dynamic Structure of Highly Disordered Manganese Oxide Catalysts for Low-Temperature CO Oxidation. Journal of Catalysis 2021,
  20. Siyang Nie, Shize Yang, Pengfei Zhang. Mechanochemical Redox: Calcination‐free Synthesis of Ceria‐hybrid Catalyst with Ultra‐High Surface Area. ChemCatChem 2021, 13 (10) , 2434-2443.
  21. Olga A. Bulavchenko, Tatyana N. Afonasenko, Alexey R. Osipov, Alena A. Pochtar’, Andrey A. Saraev, Zahar S. Vinokurov, Evgeny Yu. Gerasimov, Sergey V. Tsybulya. The Formation of Mn-Ce Oxide Catalysts for CO Oxidation by Oxalate Route: The Role of Manganese Content. Nanomaterials 2021, 11 (4) , 988.
  22. Shanka Dissanayake, Ninad Vora, Laura Achola, Yanliu Dang, Junkai He, Zachary Tobin, Xingxu Lu, Anne Mirich, Pu-Xian Gao, Steven L. Suib. Synergistic catalysis by Mn promoted ceria for molecular oxygen assisted epoxidation. Applied Catalysis B: Environmental 2021, 282 , 119573.
  23. E. Yu. Liberman, B. S. Kleusov, A. V. Naumkin, I. V. Zagaynov, T. V. Konkova, E. A. Simakina, A. O. Izotova. Thermal Stability and Catalytic Activity of the MnOx–CeO2 and the MnOx–ZrO2–CeO2 Highly Dispersed Materials in the Carbon Monoxide Oxidation Reaction. Inorganic Materials: Applied Research 2021, 12 (2) , 468-476.
  24. Wenjian Xu, Xi Chen, Jing Chen, Hongpeng Jia. Bimetal oxide CuO/Co3O4 derived from Cu ions partly-substituted framework of ZIF-67 for toluene catalytic oxidation. Journal of Hazardous Materials 2021, 403 , 123869.
  25. Ahmed Ismail, Mingyang Li, Muhammad Zahid, Liman Fan, Cheng Zhang, Zhibin Li, Yujun Zhu. Effect of strong interaction between Co and Ce oxides in CoxCe1-xO2-δ oxides on its catalytic oxidation of toluene. Molecular Catalysis 2021, 502 , 111356.
  26. Francesco Arena, Roberto Di Chio, Alessandra Palella, Lorenzo Spadaro, Leone Frusteri, Barbara Fazio, Sara Morandi, Gianmario Martra. Tailoring manganese oxide catalysts for the total oxidation of pollutants in gas and liquid phase. Applied Catalysis A: General 2021, 610 , 117917.
  27. Haidong Shen, Jun Bu, Wenbin Wang, Chen Wu, Yueling Cao, Baoliang Zhang, Qiuyu Zhang, Hepeng Zhang. Insight into Ce Doping Induced Oxygen Vacancies over Ce‐Doped Mno 2 Catalysts for Imine Synthesis. Chinese Journal of Chemistry 2020, 38 (11) , 1353-1359.
  28. Minhui Wu, Huiping Deng, Jun Shi, Zheng Wang. Transition element doped octahedral manganese molecular sieves (Me-OMS-2) as diclofenac adsorbents. Chemosphere 2020, 258 , 127120.
  29. Zhengzheng Yang, Liping Luo, Linxi Tang, Zibo Zhou, Zizhong Zhou, Yunxiang Li. Trimesic acid assisted synthesis of cerium-manganese oxide for catalytic diesel soot elimination: Enhancement of thermal aging resistibility. Fuel 2020, 278 , 118369.
  30. Junwei Feng, Yong Wang, Daowei Gao, Baotao Kang, Shun Li, Chunsheng Li, Guozhu Chen. Ce–Mn coordination polymer derived hierarchical/porous structured CeO 2 –MnO x for enhanced catalytic properties. Nanoscale 2020, 12 (30) , 16381-16388.
  31. Baohuai Zhao, Rui Ran, Liu Yang, Xiaodong Wu, Zhichun Si, Duan Weng. Comparative study of La1–Ce MnO3+ perovskites and Mn–Ce mixed oxides for NO catalytic oxidation. Journal of Rare Earths 2020, 38 (8) , 863-872.
  32. Lei Li, Changyu Zhang, Jinlong Yan, Dong Wang, Yue Peng, Junhua Li, John Crittenden. Distinctive Bimetallic Oxides for Enhanced Catalytic Toluene Combustion: Insights into the Tunable Fabrication of Mn−Ce Hollow Structure. ChemCatChem 2020, 12 (10) , 2872-2879.
  33. Shafqat Ali, Xiaodong Wu, Zareen Zuhra, Yue Ma, Yasir Abbas, Baofang Jin, Rui Ran, Duan Weng. Cu-Mn-Ce mixed oxides catalysts for soot oxidation and their mechanistic chemistry. Applied Surface Science 2020, 512 , 145602.
  34. Lei Li, Changyu Zhang, Feng Chen, Yunting Xiang, Jinlong Yan, Wei Chu. Facile fabrication of hollow structured Cu-Ce binary oxides and their catalytic properties for toluene combustion. Catalysis Today 2020, 359
  35. Minh Tuan Nguyen Dinh, Chinh Chien Nguyen, Tan Linh Truong Vu, Van Thinh Ho, Quang Duc Truong. Tailoring porous structure, reducibility and Mn4+ fraction of ε-MnO2 microcubes for the complete oxidation of toluene. Applied Catalysis A: General 2020, 595 , 117473.
  36. Qiang Lv, Ming Cai, Chang'an Wang, Yang He, Defu Che. Investigation on elemental mercury removal by cerium modified semi-coke. Journal of the Energy Institute 2020, 93 (2) , 666-678.
  37. Larisa Lutsenko, Luidmila Oleksenko, Inna Vasylenko, Olexander Ripko, George Fedorenko, Nelly Maksymovych. Nanosized Oxide Materials: Morphology, Phase Composition and Catalytic Activity in CO Oxidation. 2020,,, 118-121.
  38. Qiang Lv, Chang’an Wang, Yang He, Ming Cai, Defu Che. Elemental Mercury Removal over CeO2/TiO2 Catalyst Prepared by Sol–Gel Method. Applied Sciences 2020, 10 (8) , 2706.
  39. Cecilia C. Díaz, M. Pilar Yeste, Hilario Vidal, José M. Gatica, Luis E. Cadús, María R. Morales. In situ generation of Mn1−xCex system on cordierite monolithic supports for combustion of n-hexane. Effects on activity and stability. Fuel 2020, 262 , 116564.
  40. Jing Wang, Peifen Wang, Qiang Zhao, Jin Shi, Tao Yu, Xiao Du, Xiaogang Hao, Abuliti Abudula, Guoqing Guan. Stable hetero-metal doped Co-based catalysts prepared by electrodeposition method for low temperature combustion of toluene. Carbon Resources Conversion 2020, 3 , 95-103.
  41. Changyu Zhang, Wei Chu, Feng Chen, Lei Li, Ruiyu Jiang, Jinlong Yan. Effects of cerium precursors on surface properties of mesoporous CeMnO catalysts for toluene combustion. Journal of Rare Earths 2020, 38 (1) , 70-75.
  42. Jie Fu, Ning Liu, Lefu Mei, Libing Liao, Dina Deyneko, Jiayang Wang, Yaning Bai, Guocheng Lv. Synthesis of Ce-doped Mn3Gd7−xCex(SiO4)6O1.5 for the enhanced catalytic ozonation of tetracycline. Scientific Reports 2019, 9 (1)
  43. Ya Cheng, Tinglin Huang, Chenyang Liu, Shasha Zhang. Effects of dissolved oxygen on the start-up of manganese oxides filter for catalytic oxidative removal of manganese from groundwater. Chemical Engineering Journal 2019, 371 , 88-95.
  44. Yan Cui, Leilei Xu, Mindong Chen, Chufei Lv, Xinbo Lian, Cai-e Wu, Bo Yang, Zhichao Miao, Fagen Wang, Xun Hu. CO Oxidation over Metal Oxide (La2O3, Fe2O3, PrO2, Sm2O3, and MnO2) Doped CuO-Based Catalysts Supported on Mesoporous Ce0.8Zr0.2O2 with Intensified Low-Temperature Activity. Catalysts 2019, 9 (9) , 724.
  45. Yingjie Zhang, Ping Ning, Xueqian Wang, Langlang Wang, Yixing Ma, Qiang Ma, Yibing Xie. High efficiency of Mn–Ce‐modified TiO 2 catalysts for the low‐temperature oxidation of Hg 0 under a reducing atmosphere. Applied Organometallic Chemistry 2019, 33 (6) , e4866.
  46. Abd El Rahman S. Khder, Hatem M. Altass, Mohamed I. Orif, Sheikha S. Ashour, Layla S. Almazroai. Preparation and characterization of highly active Pd nanoparticles supported Mn3O4 catalyst for low-temperature CO oxidation. Materials Research Bulletin 2019, 113 , 215-222.
  47. Lei Zhu, Xi Li, Zhiying Liu, Lin Yao, Peng Yu, Ping Wei, Yanhua Xu, Xingmao Jiang. High Catalytic Performance of Mn-Doped Ce-Zr Catalysts for Chlorobenzene Elimination. Nanomaterials 2019, 9 (5) , 675.
  48. N.K. Soliman. Factors affecting CO oxidation reaction over nanosized materials: A review. Journal of Materials Research and Technology 2019, 8 (2) , 2395-2407.
  49. Jing Ouyang, Zai Zhao, Huaming Yang, Junkai He, Steven L. Suib. Surface redox characters and synergetic catalytic properties of macroporous ceria-zirconia solid solutions. Journal of Hazardous Materials 2019, 366 , 54-64.
  50. Francesco Arena, Roberto Di Chio, Claudia Espro, Barbara Fazio, Alessandra Palella, Lorenzo Spadaro. A New Class of MnCeOx Materials for the Catalytic Gas Exhausts Emission Control: A Study of the CO Model Compound Oxidation. Topics in Catalysis 2019, 62 (1-4) , 259-265.
  51. Ling Liu, Jingjing Shi, Ruiyu Wang. Facile construction of [email protected] [email protected] cubes with enhanced catalytic activity toward CO oxidation. Journal of Solid State Chemistry 2019, 269 , 419-427.
  52. Silija Padikkaparambil, Jinoob Perumbilavil Padi, Vinu Vadery, Sankaran Sugunan, Binitha Njarakkattuvalappil Narayanan. Facile Preparation of Noble Metal–Free Cu-Doped CeO2 Oxidation Catalyst Suitable for Engine Exhaust Gas Treatment. Journal of Environmental Engineering 2019, 145 (1) , 04018131.
  53. M.H. Wu, J. Shi, H.P. Deng. Metal doped manganese oxide octahedral molecular sieve catalysts for degradation of diclofenac in the presence of peroxymonosulfate. Arabian Journal of Chemistry 2018, 11 (6) , 924-934.
  54. Yunfei Su, Shanshan Yuan, Dandan Ning, Qingwen Zhang, Weiliang Han, Yi Wang. The Template-Free Synthesis of [email protected] 2 Nanospheres: Facile Strategy, Structure Optimization, and Enhanced Catalytic Activity toward CO Oxidation. European Journal of Inorganic Chemistry 2018, 2018 (25) , 2927-2934.
  55. Dongmei Meng, Qian Xu, Yunlei Jiao, Yun Guo, Yanglong Guo, Li Wang, Guanzhong Lu, Wangcheng Zhan. Spinel structured CoaMnbOx mixed oxide catalyst for the selective catalytic reduction of NOx with NH3. Applied Catalysis B: Environmental 2018, 221 , 652-663.
  56. Baohuai Zhao, Rui Ran, Li Sun, Zesheng Yang, Xiaodong Wu, Duan Weng. A high-surface-area La-Ce-Mn mixed oxide with enhanced activity for CO and C3H8 oxidation. Catalysis Communications 2018, 105 , 26-30.
  57. Jing Chen, Jianyan Wang, Gaosheng Zhang, Qiuyue Wu, Dongtian Wang. Facile fabrication of nanostructured cerium-manganese binary oxide for enhanced arsenite removal from water. Chemical Engineering Journal 2018, 334 , 1518-1526.
  58. Wen Xu, Yusuf G. Adewuyi, Yangxian Liu, Yan Wang. Removal of elemental mercury from flue gas using CuOx and CeO2 modified rice straw chars enhanced by ultrasound. Fuel Processing Technology 2018, 170 , 21-31.
  59. Lei Deng, Yaping Ding, Baoqing Duan, Yingwen Chen, Peiwen Li, Shemin Zhu, Shubao Shen. Catalytic deep combustion characteristics of benzene over cobalt doped Mn-Ce solid solution catalysts at lower temperatures. Molecular Catalysis 2018, 446 , 72-80.
  60. Qing Tang, Jun Du, Bin Xie, Yu Yang, Wenchong Yu, Changyuan Tao. Rare earth metal modified three dimensionally ordered macroporous MnO x -CeO 2 catalyst for diesel soot combustion. Journal of Rare Earths 2018, 36 (1) , 64-71.
  61. Xinping Duan, Zhaojun Wen, Yuxin Zhao, Junfu Zhou, Huihuang Fang, Yanning Cao, Lilong Jiang, Linmin Ye, Youzhu Yuan. Intercalation of nanostructured CeO 2 in MgAl 2 O 4 spinel illustrates the critical interaction between metal oxides and oxides. Nanoscale 2018, 10 (7) , 3331-3341.
  62. Yuning Zhu, Chun Du, Zijian Feng, Yongjie Chen, Hang Li, Rong Chen, Meiqing Shen, Bin Shan. Highly dispersed Pd on macroporous SmMn 2 O 5 mullite for low temperature oxidation of CO and C 3 H 8. RSC Advances 2018, 8 (10) , 5459-5467.
  63. Xiao Wang, Wenting Huo, Yongzheng Xu, Yunli Guo, Yuxi Jia. Modified hierarchical birnessite-type manganese oxide nanomaterials for CO catalytic oxidation. New Journal of Chemistry 2018, 42 (16) , 13803-13812.
  64. Francesco Arena, Roberto di Chio, Claudia Espro, Alessandra Palella, Lorenzo Spadaro. A definitive assessment of the CO oxidation pattern of a nanocomposite MnCeO x catalyst. Reaction Chemistry & Engineering 2018, 3 (3) , 293-300.
  65. Francesco Arena, Roberto Di Chio, Layla Filiciotto, Giuseppe Trunfio, Claudia Espro, Alessandra Palella, Antonio Patti, Lorenzo Spadaro. Probing the functionality of nanostructured MnCeOx catalysts in the carbon monoxide oxidation. Applied Catalysis B: Environmental 2017, 218 , 803-809.
  66. S. Adjimi, J.M. García-Vargas, J.A. Díaz, L. Retailleau, S. Gil, M. Pera-Titus, Y. Guo, A. Giroir-Fendler. Highly efficient and stable Ru/K-OMS-2 catalyst for NO oxidation. Applied Catalysis B: Environmental 2017, 219 , 459-466.
  67. Hongjian Zhu, Jing Xu, Yuge Yichuan, Zhongpeng Wang, Yibo Gao, Wei Liu, Henan Yin. Catalytic oxidation of soot on mesoporous ceria-based mixed oxides with cetyltrimethyl ammonium bromide (CTAB)-assisted synthesis. Journal of Colloid and Interface Science 2017, 508 , 1-13.
  68. Yue Zhou, Xin Liu, Qiulin Zhang, Qixian Liu, Zhongxian Song, Ping Ning. Effects of precipitants and surfactants on catalytic activity of Pd/CeO2 for CO oxidation. Research on Chemical Intermediates 2017, 43 (11) , 6187-6205.
  69. Zhiying Pu, Yan Liu, Huan Zhou, Wanzhen Huang, Yifan Zheng, Xiaonian Li. Catalytic combustion of lean methane at low temperature over ZrO2-modified Co3O4 catalysts. Applied Surface Science 2017, 422 , 85-93.
  70. Pan Wang, Jing Yi, Wenye Gu, Peng Luo, Lili Lei. The influence of xMnyCe/γ-Al 2 O 3 on NOx catalysts on the properties of NOx storage and reduction over Pt-Ce-Ba/γ-Al 2 O 3 catalysts. Chemical Engineering Journal 2017, 325 , 700-707.
  71. Francesco Arena, Roberto Di Chio, Barbara Fazio, Claudia Espro, Leone Spiccia, Alessandra Palella, Lorenzo Spadaro. Probing the functionality of nanostructured MnCeO x catalysts in the carbon monoxide oxidation. Applied Catalysis B: Environmental 2017, 210 , 14-22.
  72. Qun Shen, Lingyun Zhang, Nannan Sun, Hui Wang, Liangshu Zhong, Chi He, Wei Wei, Yuhan Sun. Hollow MnOx-CeO 2 mixed oxides as highly efficient catalysts in NO oxidation. Chemical Engineering Journal 2017, 322 , 46-55.
  73. Xiu Lin, Sufang Zhao, Lingling Fu, Yongming Luo, Runliang Zhu, Zhigang Liu. Synthesis of Co-N-C grafted on well-dispersed MnO x -CeO 2 hollow mesoporous sphere with efficient catalytic performance. Molecular Catalysis 2017, 437 , 18-25.
  74. Zhidan Fu, Lisha Liu, Yong Song, Qing Ye, Shuiyuan Cheng, Tianfang Kang, Hongxing Dai. Catalytic oxidation of carbon monoxide, toluene, and ethyl acetate over the xPd/OMS-2 catalysts: Effect of Pd loading. Frontiers of Chemical Science and Engineering 2017, 11 (2) , 185-196.
  75. Chao Wang, Cun Wen, Jochen Lauterbach, Erdem Sasmaz. Superior oxygen transfer ability of Pd/MnOx-CeO2 for enhanced low temperature CO oxidation activity. Applied Catalysis B: Environmental 2017, 206 , 1-8.
  76. Hai-bin LI, Guo-you HUANG, Jian ZHANG, Sheng-hao FU, Teng-gan WANG, Hong-wei LIAO. Photochemical synthesis and enhanced photocatalytic activity of MnO x /BiPO 4 heterojunction. Transactions of Nonferrous Metals Society of China 2017, 27 (5) , 1127-1133.
  77. Qiulin Zhang, Qixian Liu, Ping Ning, Xin Liu, Lisi Xu, Zhongxian Song, Yankang Duan, Tengfei Zhang. Performance and kinetic study on Pd/OMS-2 catalyst for CO catalytic oxidation: effect of preparation method. Research on Chemical Intermediates 2017, 43 (4) , 2017-2032.
  78. Ruiqin Wu, Haobo Wu, Xinbai Jiang, Jinyou Shen, Muhammad Faheem, Xiuyun Sun, Jiansheng Li, Weiqing Han, Lianjun Wang, Xiaodong Liu. The key role of biogenic manganese oxides in enhanced removal of highly recalcitrant 1,2,4-triazole from bio-treated chemical industrial wastewater. Environmental Science and Pollution Research 2017, 24 (11) , 10570-10583.
  79. Agolu Rangaswamy, Perala Venkataswamy, Damma Devaiah, Singuru Ramana, Benjaram M. Reddy. Structural characteristics and catalytic performance of nanostructured Mn-doped CeO 2 solid solutions towards oxidation of benzylamine by molecular O 2. Materials Research Bulletin 2017, 88 , 136-147.
  80. Weidong Zhang, Lijuan Hu, Feng Wu, Jinjun Li. Decreasing Co3O4 Particle Sizes by Ammonia-Etching and Catalytic Oxidation of Propane. Catalysis Letters 2017, 147 (2) , 407-415.
  81. Xiaojiang Yao, Kaili Ma, Weixin Zou, Shenggui He, Jibin An, Fumo Yang, Lin Dong. Influence of preparation methods on the physicochemical properties and catalytic performance of MnO -CeO2 catalysts for NH3-SCR at low temperature. Chinese Journal of Catalysis 2017, 38 (1) , 146-159.
  82. Deboshree Mukherjee, Perala Venkataswamy, Damma Devaiah, Agolu Rangaswamy, Benjaram M. Reddy. Crucial role of titanium dioxide support in soot oxidation catalysis of manganese doped ceria. Catalysis Science & Technology 2017, 7 (14) , 3045-3055.
  83. Wen-Xiang Tang, Pu-Xian Gao. Nanostructured cerium oxide: preparation, characterization, and application in energy and environmental catalysis. MRS Communications 2016, 6 (4) , 311-329.
  84. Dingsheng Chen, Chaoping Cen, Jinxi Feng, Chunyang Yao, Waiqing Li, Shuanghong Tian, Ya Xiong. Co-catalytic effect of Al-Cr pillared montmorillonite as a new SCR catalytic support. Journal of Chemical Technology & Biotechnology 2016, 91 (11) , 2842-2851.
  85. Perala Venkataswamy, Deshetti Jampaiah, Deboshree Mukherjee, C. U. Aniz, Benjaram M. Reddy. Mn-doped Ceria Solid Solutions for CO Oxidation at Lower Temperatures. Catalysis Letters 2016, 146 (10) , 2105-2118.
  86. Liyan Li, Weiliang Han, Jiyi Zhang, Gongxuan Lu, Zhicheng Tang. Controlled pore size of 3D mesoporous Cu-Ce based catalysts and influence of surface textures on the CO catalytic oxidation. Microporous and Mesoporous Materials 2016, 231 , 9-20.
  87. Zhiguo Xie, Xiaoxia Zhou, Huixia Wu, Han Zhao, Yan Liu, Hangrong Chen. One Step Template-Free Synthesis of Mesoporous MnOx/CeO2 Nanocomposite Oxides with Enhanced Low Temperature Catalytic Activity for CO and Hydrocarbon Oxidation. Catalysis Letters 2016, 146 (8) , 1355-1360.
  88. Zhenhe Xu, Yanlong Liu, Fuqiang Ren, Fan Yang, Dongling Ma. Development of functional nanostructures and their applications in catalysis and solar cells. Coordination Chemistry Reviews 2016, 320-321 , 153-180.
  89. Xiao-man Zhang, Ya-Qing Deng, Pengfei Tian, Huan-huan Shang, Jing Xu, Yi-Fan Han. Dynamic active sites over binary oxide catalysts: In situ/operando spectroscopic study of low-temperature CO oxidation over MnOx-CeO2 catalysts. Applied Catalysis B: Environmental 2016, 191 , 179-191.
  90. Rui C. Martins, Vítor Rodrigues, Margarida R. Costa, Luís M. Castro, Rosa M. Quinta-Ferreira. Effect of Calcination Temperature over the Performance of Mn-Ce-O on the Catalytic Ozonation of Olive Mill Wastewater. Ozone: Science & Engineering 2016, 38 (4) , 261-271.
  91. Jiaqi Li, Wenhui Li, Gang Liu, Yuzhou Deng, Jun Yang, Yunfa Chen. Tricobalt tetraoxide-supported palladium catalyst derived from metal organic frameworks for complete benzene oxidation. Catalysis Letters 2016, 146 (7) , 1300-1308.
  92. Yi Xiao, Xiaodong Wu, Shuang Liu, Jie Wan, Min Li, Duan Weng, Changqing Tong. Modification of PdO/CeO2–ZrO2 catalyst by MnO x for water–gas shift reaction: redox property and valence state of Pd. Journal of Materials Science 2016, 51 (11) , 5377-5387.
  93. Singuru Ramana, Bolla Govinda Rao, Perala Venkataswamy, Agolu Rangaswamy, Benjaram M. Reddy. Nanostructured Mn-doped ceria solid solutions for efficient oxidation of vanillyl alcohol. Journal of Molecular Catalysis A: Chemical 2016, 415 , 113-121.
  94. Leandro F. Nascimento, Osvaldo A. Serra. Washcoating of cordierite honeycomb with ceria-copper mixed oxides for catalytic diesel soot combustion. Process Safety and Environmental Protection 2016, 101 , 134-143.
  95. Wei Deng, Qiguang Dai, Yijie Lao, Bingbing Shi, Xingyi Wang. Low temperature catalytic combustion of 1,2-dichlorobenzene over CeO2–TiO2 mixed oxide catalysts. Applied Catalysis B: Environmental 2016, 181 , 848-861.
  96. Lili Zhang, Jinjun Tu, Lai Lyu, Chun Hu. Enhanced catalytic degradation of ciprofloxacin over Ce-doped OMS-2 microspheres. Applied Catalysis B: Environmental 2016, 181 , 561-569.
  97. Nabanita Pal, Eun-Bum Cho, Astam K. Patra, Dukjoon Kim. Ceria-Containing Ordered Mesoporous Silica: Synthesis, Properties, and Applications. ChemCatChem 2016, 8 (2) , 285-303.
  98. Lei Zhong, Qin Zhong, Wei Cai, Shen Zhang, Yang Yu, Man Ou, Fujiao Song. Promotional effect and mechanism study of nonmetal-doped Cr/Ce x Ti 1−x O 2 for NO oxidation: tuning O 2 activation and NO adsorption simultaneously. RSC Advances 2016, 6 (25) , 21056-21066.
  99. Liyan Li, Weiliang Han, Zhicheng Tang, Jiyi Zhang, Gongxuan Lu. Hard-template synthesis of three-dimensional mesoporous Cu–Ce based catalysts with tunable architectures and their application in the CO catalytic oxidation. RSC Advances 2016, 6 (69) , 64247-64257.
  100. Lili Lei, Chuan Sun, Bo Zhang, Wenye Gu. A Simulation Study of Effect of Mn-Ce/ γ -Al 2 O 3 on NO x Storage and Reduction over Pt-Ce-Ba/ γ -Al 2 O 3 Catalysts. Advances in Materials Science and Engineering 2016, 2016 , 1-6.
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