Enhancing Electrocatalytic Activity of Perovskite Oxides by Tuning Cation Deficiency for Oxygen Reduction and Evolution Reactions

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State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing Tech University, No. 5 Xin Mofan Road, Nanjing, Jiangsu 210009, P.R. China
Center for Innovative Fuel Cell and Battery Technologies, School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332-0245, United States
§ State Key Laboratory of Materials-Oriented Chemical Engineering, College of Energy, Nanjing Tech University, No. 5 Xin Mofan Road, Nanjing, Jiangsu 210009, P.R. China
Department of Chemical Engineering, Curtin University, Perth, Western Australia 6845, Australia
Cite this: Chem. Mater. 2016, 28, 6, 1691–1697
Publication Date (Web):February 27, 2016
https://doi.org/10.1021/acs.chemmater.5b04457
Copyright © 2016 American Chemical Society
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Abstract

Development of cost-effective and efficient electrocatalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is of prime importance to emerging renewable energy technologies. Here, we report a simple and effective strategy for enhancing ORR and OER electrocatalytic activity in alkaline solution by introducing A-site cation deficiency in LaFeO3 perovskite; the enhancement effect is more pronounced for the OER than the ORR. Among the A-site cation deficient perovskites studied, La0.95FeO3-δ (L0.95F) demonstrates the highest ORR and OER activity and, hence, the best bifunctionality. The dramatic enhancement is attributed to the creation of surface oxygen vacancies and a small amount of Fe4+ species. This work highlights the importance of tuning cation deficiency in perovskites as an effective strategy for enhancing ORR and OER activity for applications in various oxygen-based energy storage and conversion processes.

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  • Additional XRD, BET, ICP, XPS spectra of Fe, O 1s XPS peak deconvolution results, Mössbauer parameters, and electrochemistry data. (PDF)

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