A Self-Healing Oxygen-Evolving Catalyst

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Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139
Cite this: J. Am. Chem. Soc. 2009, 131, 11, 3838–3839
Publication Date (Web):February 27, 2009
https://doi.org/10.1021/ja900023k
Copyright © 2009 American Chemical Society
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Abstract

A cobalt−phosphate water-oxidizing catalyst forms from the oxidation of Co2+ to Co3+ in the presence of phosphate. We have employed radioactive 57Co and 32P isotopes to probe the dynamics of this catalyst during water-oxidation catalysis. We show that the catalyst is self-healing and that phosphate is the crucial factor responsible for repair.

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Full experimental details, photographs of electrode arrays, and elemental composition data for Na/K exchange experiments. This information is available free of charge via the Internet at http://pubs.acs.org.

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  25. Jonathan D. Herr and Ryan P. Steele . Ion–Radical Pair Separation in Larger Oxidized Water Clusters, (H2O)+n=6–21. The Journal of Physical Chemistry A 2016, 120 (36) , 7225-7239. https://doi.org/10.1021/acs.jpca.6b07465
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  33. Mauro Schilling, Greta R. Patzke, Jürg Hutter, and Sandra Luber . Computational Investigation and Design of Cobalt Aqua Complexes for Homogeneous Water Oxidation. The Journal of Physical Chemistry C 2016, 120 (15) , 7966-7975. https://doi.org/10.1021/acs.jpcc.6b00712
  34. Andrew M. Ullman, Casey N. Brodsky, Nancy Li, Shao-Liang Zheng, and Daniel G. Nocera . Probing Edge Site Reactivity of Oxidic Cobalt Water Oxidation Catalysts. Journal of the American Chemical Society 2016, 138 (12) , 4229-4236. https://doi.org/10.1021/jacs.6b00762
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  36. James D. Blakemore, Robert H. Crabtree, and Gary W. Brudvig . Molecular Catalysts for Water Oxidation. Chemical Reviews 2015, 115 (23) , 12974-13005. https://doi.org/10.1021/acs.chemrev.5b00122
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  45. YuPing Liu, Si-Xuan Guo, Liang Ding, C. André Ohlin, Alan M. Bond, and Jie Zhang . Lindqvist Polyoxoniobate Ion-Assisted Electrodeposition of Cobalt and Nickel Water Oxidation Catalysts. ACS Applied Materials & Interfaces 2015, 7 (30) , 16632-16644. https://doi.org/10.1021/acsami.5b04219
  46. Ahamed Irshad and Nookala Munichandraiah . High Catalytic Activity of Amorphous Ir-Pi for Oxygen Evolution Reaction. ACS Applied Materials & Interfaces 2015, 7 (29) , 15765-15776. https://doi.org/10.1021/acsami.5b02601
  47. Prashanth W. Menezes, Arindam Indra, Diego González-Flores, Nastaran Ranjbar Sahraie, Ivelina Zaharieva, Michael Schwarze, Peter Strasser, Holger Dau, and Matthias Driess . High-Performance Oxygen Redox Catalysis with Multifunctional Cobalt Oxide Nanochains: Morphology-Dependent Activity. ACS Catalysis 2015, 5 (4) , 2017-2027. https://doi.org/10.1021/cs501724v
  48. Michaela S. Burke, Matthew G. Kast, Lena Trotochaud, Adam M. Smith, and Shannon W. Boettcher . Cobalt–Iron (Oxy)hydroxide Oxygen Evolution Electrocatalysts: The Role of Structure and Composition on Activity, Stability, and Mechanism. Journal of the American Chemical Society 2015, 137 (10) , 3638-3648. https://doi.org/10.1021/jacs.5b00281
  49. Mohammad Mahdi Najafpour, Monika Fekete, Davood Jafarian Sedigh, Eva-Mari Aro, Robert Carpentier, Julian J. Eaton-Rye, Hiroshi Nishihara, Jian-Ren Shen, Suleyman I. Allakhverdiev, and Leone Spiccia . Damage Management in Water-Oxidizing Catalysts: From Photosystem II to Nanosized Metal Oxides. ACS Catalysis 2015, 5 (3) , 1499-1512. https://doi.org/10.1021/cs5015157
  50. Chunmei Ding, Xin Zhou, Jingying Shi, Pengli Yan, Zhiliang Wang, Guiji Liu, and Can Li . Abnormal Effects of Cations (Li+, Na+, and K+) on Photoelectrochemical and Electrocatalytic Water Splitting. The Journal of Physical Chemistry B 2015, 119 (8) , 3560-3566. https://doi.org/10.1021/acs.jpcb.5b00713
  51. Jonathan D. Herr, Justin Talbot, and Ryan P. Steele . Structural Progression in Clusters of Ionized Water, (H2O)n=1–5+. The Journal of Physical Chemistry A 2015, 119 (4) , 752-766. https://doi.org/10.1021/jp509698y
  52. Robert H. Crabtree . Deactivation in Homogeneous Transition Metal Catalysis: Causes, Avoidance, and Cure. Chemical Reviews 2015, 115 (1) , 127-150. https://doi.org/10.1021/cr5004375
  53. Markus D. Kärkäs, Oscar Verho, Eric V. Johnston, and Björn Åkermark . Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation. Chemical Reviews 2014, 114 (24) , 11863-12001. https://doi.org/10.1021/cr400572f
  54. Arindam Indra, Prashanth W. Menezes, Nastaran Ranjbar Sahraie, Arno Bergmann, Chittaranjan Das, Massimo Tallarida, Dieter Schmeißer, Peter Strasser, and Matthias Driess . Unification of Catalytic Water Oxidation and Oxygen Reduction Reactions: Amorphous Beat Crystalline Cobalt Iron Oxides. Journal of the American Chemical Society 2014, 136 (50) , 17530-17536. https://doi.org/10.1021/ja509348t
  55. Xiaohui Deng and Harun Tüysüz . Cobalt-Oxide-Based Materials as Water Oxidation Catalyst: Recent Progress and Challenges. ACS Catalysis 2014, 4 (10) , 3701-3714. https://doi.org/10.1021/cs500713d
  56. Xin Yang, Janitha Walpita, Ekaterina Mirzakulova, Shameema Oottikkal, Christopher M. Hadad, and Ksenija D. Glusac . Mechanistic Studies of Electrode-Assisted Catalytic Oxidation by Flavinium and Acridinium Cations. ACS Catalysis 2014, 4 (8) , 2635-2644. https://doi.org/10.1021/cs5005135
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  58. Yi Liu and Daniel G. Nocera . Spectroscopic Studies of Nanoparticulate Thin Films of a Cobalt-Based Oxygen Evolution Catalyst. The Journal of Physical Chemistry C 2014, 118 (30) , 17060-17066. https://doi.org/10.1021/jp5008347
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  60. Michele Orlandi, Stefano Caramori, Federico Ronconi, Carlo A. Bignozzi, Zakaria El Koura, Nicola Bazzanella, Laura Meda, and Antonio Miotello . Pulsed-Laser Deposition of Nanostructured Iron Oxide Catalysts for Efficient Water Oxidation. ACS Applied Materials & Interfaces 2014, 6 (9) , 6186-6190. https://doi.org/10.1021/am501021e
  61. Michael Huynh, D. Kwabena Bediako, and Daniel G. Nocera . A Functionally Stable Manganese Oxide Oxygen Evolution Catalyst in Acid. Journal of the American Chemical Society 2014, 136 (16) , 6002-6010. https://doi.org/10.1021/ja413147e
  62. Min-Rui Gao, Xuan Cao, Qiang Gao, Yun-Fei Xu, Ya-Rong Zheng, Jun Jiang, and Shu-Hong Yu . Nitrogen-Doped Graphene Supported CoSe2 Nanobelt Composite Catalyst for Efficient Water Oxidation. ACS Nano 2014, 8 (4) , 3970-3978. https://doi.org/10.1021/nn500880v
  63. Jordan J. Stracke and Richard G. Finke . Distinguishing Homogeneous from Heterogeneous Water Oxidation Catalysis when Beginning with Polyoxometalates. ACS Catalysis 2014, 4 (3) , 909-933. https://doi.org/10.1021/cs4011716
  64. Chengyu He, Xinglong Wu, and Zhiqiang He . Amorphous Nickel-Based Thin Film As a Janus Electrocatalyst for Water Splitting. The Journal of Physical Chemistry C 2014, 118 (9) , 4578-4584. https://doi.org/10.1021/jp408153b
  65. Leanne G. Bloor, Pedro I. Molina, Mark D. Symes, and Leroy Cronin . Low pH Electrolytic Water Splitting Using Earth-Abundant Metastable Catalysts That Self-Assemble in Situ. Journal of the American Chemical Society 2014, 136 (8) , 3304-3311. https://doi.org/10.1021/ja5003197
  66. James D. Blakemore, Harry B. Gray, Jay R. Winkler, and Astrid M. Müller . Co3O4 Nanoparticle Water-Oxidation Catalysts Made by Pulsed-Laser Ablation in Liquids. ACS Catalysis 2013, 3 (11) , 2497-2500. https://doi.org/10.1021/cs400639b
  67. Andrew M. Ullman and Daniel G. Nocera . Mechanism of Cobalt Self-Exchange Electron Transfer. Journal of the American Chemical Society 2013, 135 (40) , 15053-15061. https://doi.org/10.1021/ja404469y
  68. Joseph DePasquale, Ismael Nieto, Lauren E. Reuther, Corey J. Herbst-Gervasoni, Jared J. Paul, Vadym Mochalin, Matthias Zeller, Christine M. Thomas, Anthony W. Addison, and Elizabeth T. Papish . Iridium Dihydroxybipyridine Complexes Show That Ligand Deprotonation Dramatically Speeds Rates of Catalytic Water Oxidation. Inorganic Chemistry 2013, 52 (16) , 9175-9183. https://doi.org/10.1021/ic302448d
  69. D. Kwabena Bediako, Cyrille Costentin, Evan C. Jones, Daniel G. Nocera, and Jean-Michel Savéant . Proton–Electron Transport and Transfer in Electrocatalytic Films. Application to a Cobalt-Based O2-Evolution Catalyst. Journal of the American Chemical Society 2013, 135 (28) , 10492-10502. https://doi.org/10.1021/ja403656w
  70. Christopher L. Farrow, D. Kwabena Bediako, Yogesh Surendranath, Daniel G. Nocera, and Simon J. L. Billinge . Intermediate-Range Structure of Self-Assembled Cobalt-Based Oxygen-Evolving Catalyst. Journal of the American Chemical Society 2013, 135 (17) , 6403-6406. https://doi.org/10.1021/ja401276f
  71. Ahamed Irshad and Nookala Munichandraiah . EQCM Investigation of Electrochemical Deposition and Stability of Co–Pi Oxygen Evolution Catalyst of Solar Energy Storage. The Journal of Physical Chemistry C 2013, 117 (16) , 8001-8008. https://doi.org/10.1021/jp312752q
  72. Shannon C. Riha, Benjamin M. Klahr, Eric C. Tyo, Sönke Seifert, Stefan Vajda, Michael J. Pellin, Thomas W. Hamann, and Alex B. F. Martinson . Atomic Layer Deposition of a Submonolayer Catalyst for the Enhanced Photoelectrochemical Performance of Water Oxidation with Hematite. ACS Nano 2013, 7 (3) , 2396-2405. https://doi.org/10.1021/nn305639z
  73. D. Kwabena Bediako, Yogesh Surendranath, and Daniel G. Nocera . Mechanistic Studies of the Oxygen Evolution Reaction Mediated by a Nickel–Borate Thin Film Electrocatalyst. Journal of the American Chemical Society 2013, 135 (9) , 3662-3674. https://doi.org/10.1021/ja3126432
  74. Garett G. W. Lee and Shelley D. Minteer . Greener Method to a Manganese Oxygen Reduction Reaction Electrocatalyst: Anion Electrolyte Effects on Electrocatalytic Performance. ACS Sustainable Chemistry & Engineering 2013, 1 (3) , 359-363. https://doi.org/10.1021/sc300162d
  75. Xiao Liang Hu, Simone Piccinin, Alessandro Laio, and Stefano Fabris . Atomistic Structure of Cobalt-Phosphate Nanoparticles for Catalytic Water Oxidation. ACS Nano 2012, 6 (12) , 10497-10504. https://doi.org/10.1021/nn3044325
  76. Seif Yusuf and Feng Jiao . Effect of the Support on the Photocatalytic Water Oxidation Activity of Cobalt Oxide Nanoclusters. ACS Catalysis 2012, 2 (12) , 2753-2760. https://doi.org/10.1021/cs300581k
  77. Lucas C. C. Ferraz, Waldemir M. Carvalho, Jr., Denise Criado, and Flavio L. Souza . Vertically Oriented Iron Oxide Films Produced by Hydrothermal Process: Effect of Thermal Treatment on the Physical Chemical Properties. ACS Applied Materials & Interfaces 2012, 4 (10) , 5515-5523. https://doi.org/10.1021/am301425e
  78. Seung Woo Lee, Christopher Carlton, Marcel Risch, Yogesh Surendranath, Shuo Chen, Sho Furutsuki, Atsuo Yamada, Daniel G. Nocera, and Yang Shao-Horn . The Nature of Lithium Battery Materials under Oxygen Evolution Reaction Conditions. Journal of the American Chemical Society 2012, 134 (41) , 16959-16962. https://doi.org/10.1021/ja307814j
  79. Benjamin Klahr, Sixto Gimenez, Francisco Fabregat-Santiago, Juan Bisquert, and Thomas W. Hamann . Photoelectrochemical and Impedance Spectroscopic Investigation of Water Oxidation with “Co–Pi”-Coated Hematite Electrodes. Journal of the American Chemical Society 2012, 134 (40) , 16693-16700. https://doi.org/10.1021/ja306427f
  80. Rony S. Khnayzer, Michael W. Mara, Jier Huang, Megan L. Shelby, Lin X. Chen, and Felix N. Castellano . Structure and Activity of Photochemically Deposited “CoPi” Oxygen Evolving Catalyst on Titania. ACS Catalysis 2012, 2 (10) , 2150-2160. https://doi.org/10.1021/cs3005192
  81. Sandeep K. Kondaveeti, Shivaiah Vaddypally, Carol Lam, Daigorou Hirai, Ni Ni, Robert J. Cava, and Michael J. Zdilla . Synthesis, Structure, and Magnetic Studies of Manganese–Oxygen Clusters of Reduced Coordination Number, Featuring an Unchelated, 5-Coordinate Octanuclear Manganese Cluster with Water-Derived Oxo Ligands. Inorganic Chemistry 2012, 51 (19) , 10095-10104. https://doi.org/10.1021/ic202448c
  82. Tomer Zidki, Lihua Zhang, Vladimir Shafirovich, and Sergei V. Lymar . Water Oxidation Catalyzed by Cobalt(II) Adsorbed on Silica Nanoparticles. Journal of the American Chemical Society 2012, 134 (35) , 14275-14278. https://doi.org/10.1021/ja304030y
  83. James Landon, Ethan Demeter, Nilay İnoğlu, Chris Keturakis, Israel E. Wachs, Relja Vasić, Anatoly I. Frenkel, and John R. Kitchin . Spectroscopic Characterization of Mixed Fe–Ni Oxide Electrocatalysts for the Oxygen Evolution Reaction in Alkaline Electrolytes. ACS Catalysis 2012, 2 (8) , 1793-1801. https://doi.org/10.1021/cs3002644
  84. Yabo Wang, Yongsheng Wang, Rongrong Jiang, and Rong Xu . Cobalt Phosphate–ZnO Composite Photocatalysts for Oxygen Evolution from Photocatalytic Water Oxidation. Industrial & Engineering Chemistry Research 2012, 51 (30) , 9945-9951. https://doi.org/10.1021/ie2027469
  85. C. J. Dibble, S. T. Akin, S. Ard, C. P. Fowler, and M. A. Duncan . Photodissociation of Cobalt and Nickel Oxide Cluster Cations. The Journal of Physical Chemistry A 2012, 116 (22) , 5398-5404. https://doi.org/10.1021/jp302560p
  86. Daniel G. Nocera . The Artificial Leaf. Accounts of Chemical Research 2012, 45 (5) , 767-776. https://doi.org/10.1021/ar2003013
  87. Timothy R. Cook, Brian D. McCarthy, Daniel A. Lutterman, and Daniel G. Nocera . Halogen Oxidation and Halogen Photoelimination Chemistry of a Platinum–Rhodium Heterobimetallic Core. Inorganic Chemistry 2012, 51 (9) , 5152-5163. https://doi.org/10.1021/ic300004x
  88. D. Kwabena Bediako, Benedikt Lassalle-Kaiser, Yogesh Surendranath, Junko Yano, Vittal K. Yachandra, and Daniel G. Nocera . Structure–Activity Correlations in a Nickel–Borate Oxygen Evolution Catalyst. Journal of the American Chemical Society 2012, 134 (15) , 6801-6809. https://doi.org/10.1021/ja301018q
  89. Yogesh Surendranath, Daniel A. Lutterman, Yi Liu, and Daniel G. Nocera . Nucleation, Growth, and Repair of a Cobalt-Based Oxygen Evolving Catalyst. Journal of the American Chemical Society 2012, 134 (14) , 6326-6336. https://doi.org/10.1021/ja3000084
  90. Donge Wang, Rengui Li, Jian Zhu, Jingying Shi, Jingfeng Han, Xu Zong, and Can Li . Photocatalytic Water Oxidation on BiVO4 with the Electrocatalyst as an Oxidation Cocatalyst: Essential Relations between Electrocatalyst and Photocatalyst. The Journal of Physical Chemistry C 2012, 116 (8) , 5082-5089. https://doi.org/10.1021/jp210584b
  91. Min-Rui Gao, Yun-Fei Xu, Jun Jiang, Ya-Rong Zheng, and Shu-Hong Yu . Water Oxidation Electrocatalyzed by an Efficient Mn3O4/CoSe2 Nanocomposite. Journal of the American Chemical Society 2012, 134 (6) , 2930-2933. https://doi.org/10.1021/ja211526y
  92. Diane K. Zhong, Sujung Choi, and Daniel R. Gamelin . Near-Complete Suppression of Surface Recombination in Solar Photoelectrolysis by “Co-Pi” Catalyst-Modified W:BiVO4. Journal of the American Chemical Society 2011, 133 (45) , 18370-18377. https://doi.org/10.1021/ja207348x
  93. J. Gregory McAlpin, Troy A. Stich, C. André Ohlin, Yogesh Surendranath, Daniel G. Nocera, William H. Casey, and R. David Britt . Electronic Structure Description of a [Co(III)3Co(IV)O4] Cluster: A Model for the Paramagnetic Intermediate in Cobalt-Catalyzed Water Oxidation. Journal of the American Chemical Society 2011, 133 (39) , 15444-15452. https://doi.org/10.1021/ja202320q
  94. James B. Gerken, J. Gregory McAlpin, Jamie Y. C. Chen, Matthew L. Rigsby, William H. Casey, R. David Britt, and Shannon S. Stahl . Electrochemical Water Oxidation with Cobalt-Based Electrocatalysts from pH 0–14: The Thermodynamic Basis for Catalyst Structure, Stability, and Activity. Journal of the American Chemical Society 2011, 133 (36) , 14431-14442. https://doi.org/10.1021/ja205647m
  95. Lee-Ping Wang and Troy Van Voorhis . Direct-Coupling O2 Bond Forming a Pathway in Cobalt Oxide Water Oxidation Catalysts. The Journal of Physical Chemistry Letters 2011, 2 (17) , 2200-2204. https://doi.org/10.1021/jz201021n
  96. Heechang Ye, Hyun S. Park, and Allen J. Bard . Screening of Electrocatalysts for Photoelectrochemical Water Oxidation on W-Doped BiVO4 Photocatalysts by Scanning Electrochemical Microscopy. The Journal of Physical Chemistry C 2011, 115 (25) , 12464-12470. https://doi.org/10.1021/jp200852c
  97. Dilek K. Dogutan, Robert McGuire, Jr., and Daniel G. Nocera . Electocatalytic Water Oxidation by Cobalt(III) Hangman β-Octafluoro Corroles. Journal of the American Chemical Society 2011, 133 (24) , 9178-9180. https://doi.org/10.1021/ja202138m
  98. Mark D. Symes, Yogesh Surendranath, Daniel A. Lutterman, and Daniel G. Nocera . Bidirectional and Unidirectional PCET in a Molecular Model of a Cobalt-Based Oxygen-Evolving Catalyst. Journal of the American Chemical Society 2011, 133 (14) , 5174-5177. https://doi.org/10.1021/ja110908v
  99. Kenneth J. McDonald and Kyoung-Shin Choi . Photodeposition of Co-Based Oxygen Evolution Catalysts on α-Fe2O3 Photoanodes. Chemistry of Materials 2011, 23 (7) , 1686-1693. https://doi.org/10.1021/cm1020614
  100. Laia Francàs, Xavier Sala, Eduardo Escudero-Adán, Jordi Benet-Buchholz, Lluís Escriche, and Antoni Llobet . Synthesis, Structure, and Reactivity of New Tetranuclear Ru-Hbpp-Based Water-Oxidation Catalysts. Inorganic Chemistry 2011, 50 (7) , 2771-2781. https://doi.org/10.1021/ic101802y
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